Fatty acid alkyl esters: Perspectives for production of alternative biofuels

Applied Microbiology and Biotechnology

Volumn 85, Issue 6, 2010, Pages 1713-1733

  Röttig, Annika ^a   Wenning, Leonie ^a   Bröker, Daniel ^a   Steinbüchel, Alexander ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Biodiesel; Biofuels; Fatty acid ethyl ester; Fatty acid methyl ester; Microdiesel; Renewable resources

Indexed keywords

ALTERNATIVE ENERGY; BIOTECHNOLOGICAL PRODUCTION; COMBUSTION CHARACTERISTICS; ENERGY CRISIS; ENERGY DEMANDS; FATTY ACID ALKYL ESTERS; FATTY ACID ETHYL ESTER; FATTY ACID METHYL ESTER; FUEL PROPERTIES; GLOBAL ECONOMIES; GLOBAL PRODUCTION; HIGH COSTS; IMMOBILIZED ENZYME; IN-VIVO; LOW COSTS; MICRODIESEL; OIL SUPPLIES; PETROLEUM DIESEL; PRODUCTION PROCESS; RENEWABLE RESOURCE;

ACIDS; ALKYLATION; BIOETHANOL; BIOLOGICAL SYSTEMS; CRUDE OIL; ENERGY POLICY; ESTERIFICATION; ESTERS; ETHANOL; FATTY ACIDS; FOSSIL FUELS; GENETIC ENGINEERING; SYNTHESIS (CHEMICAL); SYNTHETIC FUELS;

BIODIESEL;

ALCOHOL; BIODIESEL; BIOFUEL; CARBON; CARBON MONOXIDE; FATTY ACID ALKYL ESTER; FATTY ACID DERIVATIVE; FOSSIL FUEL; NITROGEN OXIDE; UNCLASSIFIED DRUG;

BIOFUEL; BIOMASS; BIOTECHNOLOGY; CATALYSIS; CRUDE OIL; ENERGY MARKET; ESTER; FATTY ACID; FOSSIL FUEL; RENEWABLE RESOURCE;

ALCANIVORAX; BIOCATALYST; BIODEGRADABILITY; BIOFUEL PRODUCTION; BIOTECHNOLOGY; BURKHOLDERIA CEPACIA; CANDIDA ANTARCTICA; CANDIDA RUGOSA; CATALYSIS; CHEMICAL BOND; COMBUSTION; CROP; ESCHERICHIA COLI; FERMENTATION; NONHUMAN; OXIDATION; PARTICULATE MATTER; PSEUDOMONAS FLUORESCENS; RHIZOMUCOR; RHIZOPUS; SHORT SURVEY; SYNTHESIS; TEMPERATURE; TRANSESTERIFICATION;

BIOFUELS; BIOTECHNOLOGY; ESTERS; FATTY ACIDS;

EID: 76849088375     PISSN: 01757598     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00253-009-2383-z     Document Type: Short Survey

References (195)

1. RD Abigor PO Uadia TA Foglia MJ Haas KC Jones E Okpefa JU Obibuzor ME Bafor 2000 Lipase-catalysed production of biodiesel fuel from some Nigerian lauric oils Biochem Soc Trans 28 979 981 1:CAS:528:DC%2BD3MXhsVKjsrc%3D
2. M Adamczak UT Bornscheuer W Bednarski 2009 The application of biotechnological methods for the synthesis of biodiesel Eur J Lipid Sci Technol 111 808 813
3. C Akoh SW Chang GC Lee JF Shaw 2007 Enzymatic approach to biodiesel production J Agric Food Chem 55 8995 9005 1:CAS:528:DC%2BD2sXhtFSnsL3K
4. S Al-Zuhair 2007 Production of biodiesel: possibilities and challenges Biofuels, Bioprod Biorefin 1 57 66 1:CAS:528:DC%2BD2sXhtV2nsLrK
5. MCG Albuquerque CL Cavalcante AEB Torres DCS Azevedo EJS Parente 2009 Transesterification of castor oil using ethanol: effect of water removal by adsorption onto Zeolite 3A Energy Fuels 23 1136 1138 1:CAS:528: DC%2BD1MXht1Ogurs%3D
6. K Alhomsi M Selig T Sustic E Katrangi V Weissig M Laposata 2008 Induction of apoptosis and necrosis in human peripheral blood mononuclear cells by fatty acid ethyl esters Alcohol Clin Exp Res 32 534 543 1:CAS:528:DC%2BD1cXkt1Kksbk%3D
7. Y Ali MA Hanna 1994 Alternative diesel fuels from vegetable oils Bioresour Technol 50 153 163 1:CAS:528:DyaK2MXksVGls7Y%3D
8. D Altiparmak A Keskin A Koca M Gürü 2006 Alternative fuel properties of tall oil fatty acid methyl ester-diesel fuel blends Bioresour Technol 98 241 246
9. HM Alvarez A Steinbüchel 2002 Triacylglycerols in prokaryotic microorganisms Appl Microbiol Biotechnol 60 367 376 1:CAS:528: DC%2BD38Xpt1Cjur4%3D
10. MS Antczak A Kubiak T Antczak S Bielecki 2009 Enzymatic biodiesel synthesis-key factors affecting efficiency of the process Renewable Energy 34 1185 1194
11. D Antoni VV Zverlov WH Schwarz 2007 Biofuels from microbes Appl Microbiol Biotechnol 77 23 35 1:CAS:528:DC%2BD2sXhtFGgs7fE
12. RE Armenta M Vinatoru AM Burja JA Kralovec CJ Barrow 2007 Transesterification of fish oil to produce fatty acid ethyl esters using ultrasonic energy J Am Oil Chem Soc 84 1045 1052 1:CAS:528:DC%2BD2sXhtlGmtrrN
13. S Atsumi JC Liao 2008 Metabolic engineering for advanced biofuels production from Escherichia coli Curr Opin Biotechnol 19 414 419 1:CAS:528:DC%2BD1cXht1SntL7O
14. K Ban M Kaieda T Matsumoto A Kondo H Fukuda 2001 Whole cell biocatalyst for biodiesel fuel production utilizing Rhizopus oryzae cells immobilized within biomass support particles Biochem Eng J 8 39 43 1:CAS:528:DC%2BD38XktFWqt7w%3D
15. K Ban S Hama K Nishizuka M Kaieda T Matsumoto A Kondo H Noda H Fukuda 2002 Repeated use of whole-cell biocatalysts immobilized within biomass support particles for biodiesel fuel production J Mol Catal B Enzyme 17 157 165 1:CAS:528:DC%2BD38XktVGjt7c%3D
16. CA Best M Laposata 2003 Fatty acid ethyl esters: toxic non-oxidative metabolites of ethanol and markers of ethanol intake Front Biosci 8 202 217
17. Bommarius AS, Riebel-Bommarius BR (2000) Biocatalysts: fundamentals and applications. John Wiley & Sons, New York 266
18. GB Bradshaw WC Meuly 1944 Preparation of detergents US Patent 2 360 844
19. R Bredemeier R Hulsch JO Metzger L Berthe-Corti 2003 Submersed culture production of extracellular wax esters by the marine bacterium Fundibacter jadensis Mar Biotechnol 5 579 583 1:CAS:528:DC%2BD2cXks1CgsQ%3D%3D
20. Bröker D, Elbahloul Y, Steinbüchel A (2009) Production of lipids for biofuels using bacteria. In: Ratledge C (ed) Monograph on single cell oils, AOCS Press, Urbana: USA, pp 67-90 (in press)
21. JB Brown 1938 The structure and chemical composition of fats and oils J Am Oil Chem Soc 15 102 106 1:CAS:528:DyaA1cXjsVKlsQ%3D%3D
22. M Canakci H Sanli 2008 Biodiesel production from various feedstocks and their effects on the fuel properties J Ind Microbial Biotech 35 431 441 1:CAS:528:DC%2BD1cXks1Gns7o%3D
23. M Canakci J van Gerpen 1999 Biodiesel production via acid catalysis Trans ASAE 42 1203 1210 1:CAS:528:DyaK1MXnvFaltrk%3D
24. JW Chen WT Wu 2003 Regeneration of immobilized Candida antarctica lipase for transesterification J Biosci Bioeng 95 466 469 1:CAS:528: DC%2BD3sXlslajurY%3D
25. Y Chisti 2007 Biodiesel from microalgae Biotechnol Adv 25 294 306 1:CAS:528:DC%2BD2sXjslGksbo%3D
26. DP Chynoweth JM Owens R Legrand 2001 Renewable methane from anaerobic digestion of biomass Renew Energy 22 1 8 1:CAS:528:DC%2BD3cXntFajtrc%3D
27. SJ Clark L Wagner MD Schrock PG Piennaar 1984 Methyl and ethyl soybean esters as renewable fuels for diesel engines J Am Oil Chem Soc 61 1632 1637 1:CAS:528:DyaL2cXlvFGit7g%3D
28. 2O release from agro-biofuel production negates global warming reduction by replacing fossil fuels Atmos Chem Phys 8 389 395 1:CAS:528:DC%2BD1cXjtVyrsL4%3D
29. C Dai J Tao M Zhao B Jiang 2007 Energetic efficiency and environmental, economic, societal benefits of microdiesel from biowastes Energy Explor Exploit 25 210 226
30. D de Oliveira I Do Nascimento Filho M Di Luccio C Faccio C Dalla Rosa JP Bender N Lipke C Amroginski C Dariva JV de Oliveira 2005 Kinetics of enzyme-catalyzed alcoholysis of soybean oil in n-hexane Appl Biochem Biotechnol 121 231 241
31. Del Cardayre S, Cockrem M, Charles M (2009) Systems and methods for the production of fatty esters. International patent WO2009009391. 15 Jan 2009
32. A Demirbas 2003 Chemical and fuel properties of seventeen vegetable oils Energy Sources 25 721 728 1:CAS:528:DC%2BD3sXlt1yks7c%3D
33. MA Diczfalusy I Björkhem C Einarsson CG Hillebrant SEH Alexson 2001 Characterization of enzymes involved in formation of ethyl esters of long-chain fatty acids in humans J Lipid Res 42 1025 1032 1:CAS:528:DC%2BD3MXlt1Kru7c%3D
34. Diesel R (1913) Die Entstehung des Dieselmotors. Verlag Julius Springer, Berlin
35. LM Du Plessis JBM de Villiers WH van der Walt 1985 Stability studies on methyl and ethyl fatty acid esters of sunflowerseed oil J Am Oil Chem Soc 62 748 752
36. W Du Y Xu D Liu J Zeng 2004 Comparative study on lipase-catalyzed transformation of soybean oil for biodiesel production with different acyl acceptors J Mol Catal B Enzyme 30 125 129 1:CAS:528:DC%2BD2cXlsFymtLk%3D
37. W Du DH Liu LL Li LM Dai 2007 Mechanism exploration during lipase-mediated methanolysis of renewable oils for biodiesel production in a tert-butanol system Biotechnol Prog 23 1087 1090 1:CAS:528:DC%2BD2sXovFCltrk%3D (Pubitemid 47587078)
38. W Du W Li T Sun X Chen C Liu 2008 Perspectives for biotechnological production of biodiesel and impacts Appl Microbiol Biotechnol 79 331 337 1:CAS:528:DC%2BD1cXlvF2ku7k%3D
39. Emerging Markets Online (2008) Biodiesel 2020: a global market survey, 2nd edition. http://www.emerging-markets.com/biodiesel/default.asp
40. JM Encinar JF Gonzáles A Rodríguez-Reinares 2007 Ethanolysis of used frying oil. Biodiesel preparation and characterization Fuel Process Technol 88 513 522 1:CAS:528:DC%2BD2sXjs1Cnsro%3D
41. EPA 420-P-02-001, www.epa.gov/oms/models/analysis/biodsl/p02001.pdf
42. European Biodiesel Board (2009) http://www.ebb-eu.org/stats.php
43. EurOpserv'ER (2008) Biogas barometer. In: Systèmes solaires, le journal des energies renouvelables 186: 45-59, http://www.eurobserv-er.org/pdf/ baro186-a.asp. Accessed 17 Nov 2009
44. F Fargione J Hill D Tilman S Polasky P Hawthorne 2008 Land clearing and the biofuel carbon dept Science 319 1235 1238 1:CAS:528:DC%2BD1cXisVSksLs%3D
45. RO Feuge AT Gros 1949 Modification of vegetable oils. VII. Alkali catalyzed interesterification of peanut oil with ethanol J Am Oil Chem Soc 26 97 102 1:CAS:528:DyaH1MXhvV2muw%3D%3D
46. CR Fischer D Klein-Marcuschamer G Stephanopoulos 2008 Selection and optimization of microbial hosts for biofuels production Metab Eng 10 295 304 1:CAS:528:DC%2BD1cXhsVKrt7vE
47. LM Fixter MN Nagi JG McCormack CA Fewson 1986 Structure, distribution and function of wax esters in Acinetobacter calcoaceticus J Gen Microbiol 132 3147 3157 1:CAS:528:DyaL2sXivFOksA%3D%3D
48. L Fjerback KV Christensen B Norddahl 2009 A review of the current state of biodiesel production using enzymatic transesterification Biotechnol Bioeng 102 1298 1315
49. TA Foglia LA Nelson RO Dunn WN Marmer 1997 Low-temperature properties of alkyl esters of tallow and grease J Am Oil Chem Soc 74 951 955 1:CAS:528:DyaK2sXls1Sks7w%3D
50. MW Formo 1954 Ester reactions of fatty materials J Am Oil Chem Soc 31 548 559 1:CAS:528:DyaG2MXmsFGr
51. JL Fortman S Chhabra A Mukhopadhyay H Chou TS Lee E Steen JD Keasling 2008 Biofuel alternatives to ethanol: pumping the microbial well Trends Biotechnol 26 375 381 1:CAS:528:DC%2BD1cXnsF2qtbk%3D
52. Freedman B, Pryde EH (1982) Fatty esters from vegetable oils for use as a diesel fuel. In: Vegetable oil fuels-Proceedings of the international conference on plant and vegetable oils as fuels. Fargo, N. D., 2-4 August, St. Jospeh, Mich. S. 117-122
53. B Freedman EH Pryde TL Mounts 1984 Variables affecting the yields of fatty esters from transesterified vegetable oils J Am Oil Chem Soc 61 1638 1643 1:CAS:528:DyaL2MXmtV2rtQ%3D%3D
54. T Fujii O Kobayashi H Yoshimoto S Furukawa Y Tamai 1997 Effect of aeration and unsaturated fatty acids on expression of the Saccharomyces cerevisiae alcohol acetyltransferase gene Appl Environ Microbiol 63 910 915 1:CAS:528:DyaK2sXhsV2isr8%3D
55. H Fukuda A Kondo H Noda 2001 Biodiesel fuel production by transesterification of oils J Biosci Bioeng 92 405 416 1:CAS:528: DC%2BD38XnvVWitw%3D%3D
56. H Fukuda S Hama S Tamalampudi H Noda 2008 Whole-cell biocatalysts for biodiesel fuel production Trends Biotechnol 26 668 673 1:CAS:528: DC%2BD1cXhtl2qu7rI
57. B Gao E Su J Lin Z Jiang Y Ma D Wie 2009 Development of recombinant Escherichia coli whole-cell biocatalyst expresssing a novel alkaline lipase-coding gene from Proteus sp. for biodiesel production J Biotechnol 139 169 175 1:CAS:528:DC%2BD1MXhsVOgsw%3D%3D
58. German Biogas Association (2009) Aktuelle Branchenzahlen dokumentieren positive Entwicklung für Biogasnutzung. In: press release 10 Nov 2009, http://www.biogas.org/datenbank/file/notmember/presse/09-11-10-PM- Branchenzahlen-AT09.pdf, accessed 17 Nov 2009
59. CE Goering AW Schwab MJ Daugherty EH Pryde AJ Heakin 1982 Fuel properties of eleven vegetable oils Trans ASAE 25 1472 1483 1:CAS:528:DyaL3sXhsVKntL4%3D
60. NP Gorski H Nouraldin DM Dube FI Preffer DM Dombkowski EM Villa KB Lewandrowski RD Weiss C Hufford M Laposata 1996 Reduced fatty acid ethyl ester synthase activity in the white blood cells of alcoholics Alcohol Clin Exp Res 20 268 274 1:STN:280:DyaK283nvFyrsA%3D%3D
61. KA Goss R Alharethi M Laposata 1999 Fatty acid ethyl ester synthesis in the preparation of scotch whiskey Alcohol 17 241 245 1:CAS:528: DyaK1MXislKrtrc%3D
62. MS Graboski RL McCormick 1998 Combustion of fat and vegetable oil derived fuels in diesel engines Prog Energy Comb Sci 24 125 164 1:CAS:528: DyaK1cXjtFeju7w%3D
63. KA Gray L Zhao M Emptage 2006 Bioethanol Curr Opin Chem Biol 10 141 146 1:CAS:528:DC%2BD28XjtFagt7g%3D
64. RA Gubitosi-Klug RW Gross 1996 Fatty acid ethyl esters, non-oxidative metabolites of ethanol, accelerate the kinetics of activation of the human brain delayed rectifier K+channel J Biol Chem 271 519 522
65. MJ Haas 2004 The interplay between feedstock quality and esterification technology in biodiesel production Lipid Technol 16 7 11 1:CAS:528: DC%2BD2cXht1WnsL4%3D
66. Haas MJ, Foglia TA (2005) Alternate feedstocks and technologies for biodiesel production. In: Knothe G, Van Gerpen J, Krahl J (eds) The Biodiesel Handbook. AOCS Press, Champaign, pp 50-69
67. MJ Haas KM Scott 1996 Combined nonenzymatic-enzymatic method for the synthesis of simple alkyl fatty acid esters from soapstock J Am Oil Chem Soc 73 1393 1401 1:CAS:528:DyaK28XntFOiu7k%3D
68. MJ Haas AJ McAloon WC Yee TA Foglia 2005 A process model to estimate biodiesel production costs Bioresour Technol 97 671 678
69. PS Haber JS Wilson MW Apte RC Pirola 1993 Fatty acid ethyl esters increase rat pancreatic lysosomal fragility J Lab Clin Med 121 759 764 1:CAS:528:DyaK2cXksFaiurc%3D
70. M Habulin Z Knez 2001 Activity and stability of lipases from different sources in supercritical carbon dioxide and near-critical propane J Chem Technol Biotechnol 76 1260 1266 1:CAS:528:DC%2BD3MXptVKhtrk%3D
71. S Hama S Tamalampudi T Fukumizu K Miura H Yamaji A Kondo H Fukuda 2006 Lipase localization in Rhizopus oryzae cells immobilized within biomass support particles for use as whole-cell biocatalysts in biodiesel-fuel production J Biosci Bioeng 101 328 333 1:CAS:528:DC%2BD28XmtVahtro%3D
72. S Hama S Tamalampudi Y Suzuki A Yoshida H Fukuda A Kondo 2008 Preparation and comparative characterization of immobilized Aspergillus oryzae expressing Fusarium heterosporum lipase for enzymatic biodiesel production Appl Microbiol Biotechnol 81 637 645 1:CAS:528:DC%2BD1cXhsVCntbrI
73. Q He Y Xu Y Teng D Wang 2008 Biodiesel production catalyzed by whole-cell lipase from Rhizopus chinensis Chin Jour Catal 29 141 146
74. ME Himmel SY Ding DK Johnson WS Adney MR Nimlos JW Brady TD Foust 2007 Biomass recalcitrance: engineering plants and enzymes for biofuels production Science 315 804 807 1:CAS:528:DC%2BD2sXhsVShsrk%3D
75. HE Hoydonckx DE De Vos SA Chavan PA Jacobs 2004 Esterification and transesterification of renewable chemicals Top Catal 27 83 96 1:CAS:528:DC%2BD2cXntlektw%3D%3D
76. Q Hu M Sommerfeld E Jarvis M Ghirardi M Posewitz M Seibert A Darzins 2008 Microalgal triacylglycerols as feedstocks for biodiesel production: perspectives and advances Plant J 54 621 639 1:CAS:528:DC%2BD1cXmvFKgsrs%3D
77. BL Hungund DB Goldstein F Villegas TB Cooper 1988 Formation of fatty acid ethyl esters during chronic ethanol treatment in mice Biochem Pharmacol 37 3001 3004 1:CAS:528:DyaL1cXltVKgtLk%3D
78. LO Ingram T Conway DP Clark GW Sewell JF Preston 1987 Genetic engineering of ethanol production in Escherichia coli Appl Environ Microbiol 53 2420 2425 1:CAS:528:DyaL2sXmtFaqsLc%3D
79. KR Jegannathan S Abang D Poncelet ES Chan P Ravindra 2008 Production of biodiesel using immobilized lipase-a critical review Crit Rev Biotechnol 28 253 264 1:CAS:528:DC%2BD1cXhsVGqt7fL
80. G Jin TJ Bierma CG Hamaker R Rhykerd LA Loftus 2008 Producing biodiesel using whole-cell biocatalysts in separate hydrolysis and methanolysis reactions J Environ Sci Health A Tox Hazard Subst Environ Eng 43 589 595 1:CAS:528:DC%2BD1cXktlSkt7c%3D
81. G Jin TJ Bierma CG Hamaker R Mucha V Schola J Stewart C Wade 2009 Use of a whole-cell biocatalyst to produce biodiesel in a water-containing system J Environ Sci Health A Tox Hazard Subst Environ Eng 44 21 28 1:CAS:528: DC%2BD1cXhsV2rs7jF
82. HC Joshi J Toler T Walker 2008 Optimization of cottonseed oil ethanolysis to produce biodiesel high in gossypol content J Am Oil Chem Soc 85 357 363 1:CAS:528:DC%2BD1cXkt1altbo%3D
83. JS Junior AP Mariano DF Angelis 2009 Biodegradation of biodiesel/diesel blends by Candida viswanathii Afr J Biotechnol 8 2774 2778
84. M Kaieda T Samukawa T Matsumoto K Ban A Kondo Y Shimada H Noda F Nomoto K Ohtsuka E Izumoto H Fukuda 1999 Biodiesel fuel production from plant oil catalyzed by Rhizopus oryzae lipase in a water-containing system without an organic solvent J Biosci Bioeng 88 627 631 1:CAS:528:DC%2BD3cXhslyhuw%3D%3D
85. M Kaieda T Samukawa A Kondo H Fukuda 2001 Effect of methanol and water contents on production of biodiesel fuel from plant oil catalyzed by various lipases in a solvent-free system J Biosci Bioeng 91 12 15 1:CAS:528: DC%2BD3MXhvFSmtrk%3D
86. R Kalscheuer A Steinbüchel 2003 A novel bifunctional wax ester synthase/acyl-CoA:diacylglycerol acyltransferase mediates wax ester and triacylglycerol biosynthesis in Acinetobacter calcoaceticus ADP1 J Biol Chem 278 8075 8082 1:CAS:528:DC%2BD3sXhsF2iurc%3D (Pubitemid 36800547)
87. R Kalscheuer S Uthoff H Luftmann A Steinbüchel 2003 In vitro and in vivo biosynthesis of wax diesters by an unspecific bifunctional wax ester synthase/acyl-CoA:diacylglycerol acyltransferase from Acinetobacter calcoaceticus ADP1 Eur J Lipid Sci Technol 105 578 584 1:CAS:528: DC%2BD3sXosVKmsrw%3D (Pubitemid 37363263)
88. R Kalscheuer T Stölting A Steinbüchel 2006 Microdiesel: Escherichia coli engineered for fuel production Microbiology 152 2529 2536 1:CAS:528:DC%2BD28XhtVart7vM
89. R Kalscheuer T Stöveken A Steinbüchel 2007 Engineered microorganisms for sustainable production of diesel fuel and other oleochemicals from renewable plant biomass Int Sugar J 109 16 19 1:CAS:528: DC%2BD2sXhvFKntbs%3D
90. BS Kaphalia RR Fritz GA Ansari 1997 Purification and characterization of rat liver microsomal fatty acid ethyl and 2-chloroethyl ester synthase and their relationship with carboxylesterase (pI 6.1) Chem Res Toxicol 10 211 218 1:CAS:528:DyaK2sXhtFejtr8%3D
91. JP Kapur SD Bhasin KC Mathur 1982 Oilseeds for food and industrial applications Chem Age India 33 475 482
92. A Keskin M Gürü D Altiparmak 2006 Biodiesel production from tall oil with synthesized Mn and Ni based additives: effects of the additives on fuel consumption and emissions Fuel 86 1139 1143
93. N Khan MA Warith GA Luk 2007 Comparison of acute toxicity of biodiesel, biodiesel blends, and diesel on aquatic organisms J Air Waste Manage Assoc 57 286 296 1:CAS:528:DC%2BD2sXjvFShu7o%3D
94. SJ Kim SM Jung YP Park K Park 2007 Lipase catalyzed transesterification of soybean oil using ethyl acetate, an alternative acyl acceptor Biotechnol Bioprocess Eng 12 441 445 1:CAS:528:DC%2BD2sXhtVehtrnL
95. G Knothe 2001 Historical perspectives on vegetable oil-based diesel fuels Ind Oils 12 1103 1107
96. G Knothe 2005 Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters Fuel Process Technol 86 1059 1070 1:CAS:528: DC%2BD2MXjvVCkt7g%3D
97. Koo-Oshima S, Hahn N, Van Gerpen J (1998) Comprehensive health and environmental effects of biodiesel as an alternative fuel. Proceedings of the Fall meeting of the Society for Risk Analysis, Paris, France
98. Korus RA, Hoffman DS, Bam N, Peterson CL, Drown DC (1993) Transesterification process to manufacture ethyl ester of rape oil. In: Proceedings of the First Biomass Conference of the Americas: Energy, Environment, Agriculture and Industry, Burlington, VT, 30 Aug-2 Sep, 2:815-826
99. K Krisnangkura R Simamaharnnop 1992 Continuous transmethylation of palm oil in an organic solvent J Am Oil Chem Soc 72 427 432
100. M Kusano Y Sakai N Kato H Yoshimoto Y Tamai 1999 A novel hemiacetal dehydrogenase activity involved in ethyl acetate synthesis in Candida utilis J Biosci Bioeng 87 690 692 1:CAS:528:DyaK1MXltFCls74%3D
101. A Lapinskiené P Martinkus V Rebzdaite 2006 Eco-toxicological studies of diesel and biodiesel fuels in aerated soil Environ Pollut 142 432 437
102. EA Laposata LG Lange 1986 Presence of nonoxidative ethanol metabolism in human organs commonly damaged by ethanol abuse Science 231 497 499 1:CAS:528:DyaL28XhtVCitLw%3D
103. PV Lara EY Park 2004 Potential application of waste activated bleaching earth on the production of fatty acid alkyl esters using Candida cylindracea lipase in organic solvent system Enzyme Microb Technol 34 270 277 1:CAS:528:DC%2BD2cXhtFWntL0%3D
104. SY Lee MA Hubbe S Saka 2006 Biodiesel from wood pulping BioResources 1 150 171
105. SY Lee JH Park SH Jang LK Nielsen J Kim KS Jung 2008 Fermentative butanol production by Clostridia Biotechnol Bioeng 101 209 228 1:CAS:528: DC%2BD1cXhtFChtbvK
106. LL Li W Du DH Liu L Wang ZB Li 2006 Lipase-catalyzed transesterification of rapeseed oils for biodiesel production with a novel organic solvent as the reaction medium J Mol Catal B Enzym 43 58 62 1:CAS:528:DC%2BD28Xht1SgsbvN
107. W Li W Du D Liu 2007 Optimization of whole cell-catalyzed methanolysis of soybean oil for biodiesel production using response surface methodology J Mol Catal B Enzyme 45 122 127 1:CAS:528:DC%2BD2sXislKhtrY%3D
108. W Li W Du D Liu 2007 Rhizopus oryzae IFO 4697 whole cell catalyzed methanolysis of crude and acidified rapeseed oils for biodiesel production in tert-butanol system Proc Biochem 42 1481 1485 1:CAS:528:DC%2BD2sXhtFGrsbfK
109. Licht FO (2008) 2008 world fuel ethanol production, estimates. Renewable Fuels Association, RFA http://www.ethanolrfa.org/industry/statistics/
110. M Lilly FF Bauer MG Lambrechts JH Swiegers D Cozzolino IS Pretorius 2006 The effect of increased yeast alcohol acetyltransferase and esterase activity on the flavour profiles of wine and distillates Yeast 23 641 659 1:CAS:528:DC%2BD28XosFGju7Y%3D
111. SQ Liu R Holland VL Crow 2004 Esters and their biosynthesis in fermented dairy products: a review Int Dairy J 14 923 945 1:CAS:528:DC%2BD2cXmvFylu7c%3D
112. E Lotero Y Liu DE Lopez K Suwannakarn DA Bruce JG Goodwin Jr 2005 Synthesis of biodiesel via acid catalysis Ind Eng Chem Res 44 5353 5363 1:CAS:528:DC%2BD2MXmsVWitA%3D%3D
113. X Lu H Vora C Khosla 2008 Overproduction of free fatty acids in E. coli: implications for biodiesel production Metab Eng 10 333 339 1:CAS:528: DC%2BD1cXhsVKrt7jO
114. F Ma MA Hanna 1999 Biodiesel production: a review Bioresour Technol 70 1 15 1:CAS:528:DyaK1MXjtlGhtb8%3D
115. F Ma LD Clements MA Hanna 1998 The effects of catalyst, free fatty acids and water on transesterification of beef tallow Trans ASAE 41 1261 1264 1:CAS:528:DyaK1cXnt1Wgsro%3D
116. V Makareviciene P Janulis 2003 Environmental effect of rapeseed oil ethyl ester Renew Energy 28 2395 2403 1:CAS:528:DC%2BD3sXltl2hur0%3D
117. R Malhotra 2007 Road to emerging alternatives-biofuels and hydrogen Journal of the Petrotech Society 4 34 40
118. AP Mariano RC Tomasella LM Oliveira J Contiero DF Angelis 2008 Biodegradability of diesel and biodiesel blends Afr J Biotechnol 7 1323 1328
119. Marshall WF (1993) Biodiesel, commercialization of a renewable fuel. IIT Research Institute, National Institute for Petroleum and Energy Research, Bartlesville, OK (report for the US Department of Energy, Energy Efficiency and Renewable Fuels, Washington, DC)
120. AB Mason JP Dufour 2000 Alcohol acetyltransferases and the significance of ester synthesis in yeast Yeast 16 1287 1298 1:CAS:528:DC%2BD3cXnvVGhsLg%3D
121. T Matsumoto S Takahashi M Kaieda M Ueda A Tanaka H Fukuda A Kondo 2001 Yeast whole-cell biocatalyst constructed by intracellular overproduction of Rhizopus oryzae lipase is applicable to biodiesel fuel production Appl Microbiol Biotechnol 57 515 520 1:CAS:528:DC%2BD3MXptVantL0%3D
122. T Matsumoto H Fukuda M Ueda A Tanaka A Kondo 2002 Construction of yeast strains with high cell surface lipase activity by using novel display systems based on the Flo1p flocculation functional domain Appl Environ Microbiol 68 4517 4522 1:CAS:528:DC%2BD38XmvVCjs7g%3D
123. RL McCormick MS Graboski TL Alleman AM Herring K Shaine Tyson 2001 Impact of biodiesel source material and chemical structure on emissions of criteria pollutants from a heavy-duty engine Environ Sci Technol 35 1742 1747 1:CAS:528:DC%2BD3MXit1Cks7o%3D
124. LC Meher C Vidya Sagar SN Naik 2004 Technical aspects of biodiesel production by transesterification-a review Renewable Sustainable Energy Rev 10 248 268
125. P Metzger C Largeau 2005 Botryococcus braunii: a rich source for hydrocarbons and related ether lipids Appl Microbiol Biotechnol 66 486 496 1:CAS:528:DC%2BD2MXkslek
126. M Mittelbach 1990 Lipase catalyzed alcoholysis of sunflower oil J Am Oil Chem Soc 67 168 170 1:CAS:528:DyaK3cXitlCitL0%3D
127. M Mittelbach P Tritthart 1988 Diesel fuel derived from vegetable oils. II. Emission tests using methyl esters of used frying oil J Am Oil Chem Soc 65 1185 1187 1:CAS:528:DyaL1cXkvFGru7k%3D
128. A Mrozik K Hupert-Kocurek B Nowak S Labuzek 2008 Microbial lipases and their significance in the protection of the environment Post Mikrobiol 47 43 50 1:CAS:528:DC%2BD1cXptVyksb4%3D
129. T Nakashima S Kyotani E Izumoto H Fukuda 1990 Cell aggregation as a trigger for enhancement of intracellular lipase production by a Rhizopus species J Ferment Bioeng 70 83 89
130. K Narasimharao A Lee K Wilson 2007 Catalysts in production of biodiesel: a review J Biobased Mater Bioenergy 1 19 30
131. National Biodiesel Board (2009) http://www.biodiesel.org/
132. AD Neale RK Scopes JM Kelly REH Wettenhall 1986 The two alcohol dehydrogenases of Zymomonas mobilis Eur J Biochem 154 119 124 1:CAS:528:DyaL28XosVWrsQ%3D%3D
133. LA Nelson TA Foglia WN Marmer 1996 Lipase-catalyzed production of biodiesel J Am Oil Chem Soc 73 1191 1195 1:CAS:528:DyaK28XlslGisr4%3D
134. PM Nielsen J Brask L Fjerbaek 2008 Enzymatic biodiesel production: technical and economical considerations Eur J Lipid Sci Technol 110 662 700
135. H Noureddini X Gao RS Philkana 2005 Immobilized Pseudomonas cepacia lipase for biodiesel fuel production from soybean oil Bioresour Technol 96 769 777 1:CAS:528:DC%2BD2cXhtVOqs7nK
136. 2 J Supercrit Fluids 19 141 148 1:CAS:528: DC%2BD3MXhtFyrsro%3D
137. AC Oliveira MF Rosa 2006 Enzymatic transesterification of sunflower oil in an aqueous-oil-biphasic system J Am Oil Chem Soc 83 21 25 1:CAS:528:DC%2BD28XhsFahtrc%3D
138. MO Park 2005 New pathway for long-chain n-alkane synthesis via 1-alcohol in Vibrio furnissii M1 J Bacteriol 187 1426 1429 1:CAS:528:DC%2BD2MXhs1Kksb0%3D
139. YC Park CE Horton Shaffer GN Bennett 2009 Microbial formation of esters Appl Microbiol Biotechnol 10.1007/s00253-009-2170-x
140. JC Pasqualino D Montané J Salvadó 2006 Synergic effects of biodiesel in the biodegradability of fossil-derived fuels Biomass Bioenergy 30 874 879 1:CAS:528:DC%2BD28XhtVSis7jN
141. Peterson CL, Möller G (2005) Biodiesel fuels: biodegradability, biological, and chemical oxygen demand, and toxicity. In: Knothe G, Van Gerpen J, Krahl J (eds) The Biodiesel Handbook. AOCS Press, Champaign, pp 143-158
142. Peterson CL, Reece DL (1994) Emissions tests with an on-road vehicle fueled with methyl and ethyl esters of rapeseed oil. ASAE Paper No. 946532. ASAE International Winter Meeting, Atlanta, Georgia. 13-16 Dec
143. Peterson CL, Reece DL, Cruz R, Thompson J (1992) A comparison of ethyl and methyl esters of vegetable oils as diesel fuel substitutes in liquid fuels from renewable resource. Proceedings of Alternative Energy Conference. ASAE, St. Joseph, MI 49085-9659
144. Peterson CL, Hammond B, Reece D, Thompson J, Beck S (1995) Performance and durability testing of diesel engines using ethyl and methyl ester fuels. Department of Biological and Agricultural Engineering. University of Idaho, Moscow, Idaho 83844-2060. National Biodiesel Board, 1 Jan 1995-31 Dec 1995
145. D Pimentel T Patzek G Cecil 2007 Ethanol production: energy, economic, and environmental losses Rev Environ Contam Toxicol 189 25 41 1:CAS:528:DC%2BD2sXht1agtbs%3D
146. D Pimentel A Marklein MA Toth M Karpoff GS Paul R McCormack J Kyriazis T Krueger 2008 Biofuel impacts on world food supply: use of fossil fuel, land and water resources Energies 1 41 78
147. Pitter P, Chudoba J (1990) Biodegradability of organic substances in the aquatic environment. CRC Press, Inc., Boca Raton
148. MA Refaai PN Nguyen TS Steffensen RJ Evans JE Cluette-Brown M Laposata 2002 Liver and adipose tissue fatty acid ethyl esters obtained at autopsy are postmortem markers for premortem ethanol intake Clin Chem 48 77 83 1:CAS:528:DC%2BD38XhsFartA%3D%3D
149. H Riveros-Rosas A Julian-Sanchez E Pina 1997 Enzymology of ethanol and acetaldehyde metabolism in mammals Arch Med Res 28 453 471 1:CAS:528: DyaK1cXitlGnsQ%3D%3D
150. RC Rodrigues G Volpato K Wada MAZ Ayub 2008 Enzymatic synthesis of biodiesel from transesterification reactions of vegetable oils and short chain alcohols J Am Oil Chem Soc 85 925 930 1:CAS:528:DC%2BD1cXhtFSmsLzN
151. D Royon M Daz G Ellenrieder S Locatelli 2007 Enzymatic production of biodiesel from cotton seed oil using t-butanol as a solvent Bioresour Technol 98 648 653 1:CAS:528:DC%2BD28Xps1Wks78%3D
152. MA Rude A Schirmer 2009 New microbial fuels: a biotech perspective Curr Opin Microbiol 12 274 281 1:CAS:528:DC%2BD1MXnt1ersLk%3D
153. SMG Saerens KJ Verstrepen SDM Van Laere ARD Voet P Van Dijck FR Delvaux JM Thevelein 2006 The Saccharomyces cerevisiae EHT1 and EEB1 genes encode novel enzymes with medium-chain fatty acid ethyl ester synthesis and hydrolysis capacity J Biol Chem 281 4446 4456 1:CAS:528:DC%2BD28XhtlKrsr8%3D
154. SMG Saerens F Delvaux KJ Verstrepen P Van Dijck JM Thevelein FR Delvaux 2008 Parameters affecting ethyl ester production by Saccharomyces cerevisiae during fermentation Appl Environ Microbiol 74 454 461 1:CAS:528: DC%2BD1cXktVymsr4%3D
155. M Saghir J Werner M Laposata 1997 Rapid in vivo hydrolysis of fatty acid ethyl esters, toxic nonoxidative ethanol metabolites Am J Physiol 273 184 190
156. Salem RO, Laposata M (2005) Alcohol and fatty acid ethyl esters. In: Preedy VR, Watson R (eds.) Comprehensive handbook of alcohol related pathology, Vol. 3. Elsevier Ltd
157. B Selmi D Thomas 1998 Immobilized lipase-catalyzed ethanolysis of sunflower oil in a solvent-free medium J Am Oil Chem Soc 75 691 695 1:CAS:528:DyaK1cXksFKnsLw%3D
158. S Shafiee E Topal 2009 When will fossil fuel reserves be diminished? Energy Policy 37 181 189
159. Y Shimada Y Watanabe T Samukawa A Sugihara H Noda H Fukuda Y Tominaga 1999 Conversion of vegetable oil to biodiesel using immobilized Candida antarctica lipase J Am Oil Chem Soc 76 789 793 1:CAS:528:DyaK1MXkvV2hsbs%3D
160. Y Shimada Y Watanabe A Sugihara Y Tominaga 2002 Enzymatic alcoholysis for biodiesel fuel production and application of the reaction to oil processing J Mol Catal B Enzyme 17 133 142 1:CAS:528:DC%2BD38XktVGjt7w%3D
161. Sorrell S, Speirs J, Bentley R, Brandt A, Miller R (2009) Global oil depletion. An assessment of the evidence for a near-term peak in global oil production. UK Energy Research Centre. ISBN 1-903144-0-35; http://www.ukerc.ac. uk/support/tiki-index.php?page=Global+Oil+Depletion
162. MM Soumanou UT Bornscheuer 2003 Improvement in lipase-catalyzed synthesis of fatty acid methyl esters from sunflower oil Enzyme Microb Technol 33 97 103 1:CAS:528:DC%2BD3sXkvVKju7g%3D
163. A Srivastava R Prasad 2000 Trigylcerides-based diesel fuels Renewable Sustainable Energy Rev 4 111 133 1:CAS:528:DC%2BD3cXisVCks7o%3D
164. F Staat E Vallet 1994 Vegetable oil methyl ester as a diesel substitute Chem Ind 21 863 865
165. T Stöveken R Kalscheuer U Malkus R Reichelt A Steinbüchel 2005 The wax ester synthase/acyl-CoA:diacylglycerol acyltransferase from Acinetobacter sp. strain ADP1: characterization of a novel type of acyltransferases J Bacteriol 187 1369 1376 (Pubitemid 40299461)
166. M Stratford PA Anslow 1996 Comparison of the inhibitory action on Saccharomyces cerevisiae of weak-acid preservatives, uncouplers and medium-chain fatty acids FEMS Microbiol Lett 142 53 58 1:CAS:528:DyaK28XkslGhsbc%3D
167. Z Szczepiorkowski GR Dickersin M Laposata 1995 Fatty acid ethyl esters decrease human hepatoblastoma cell proliferation and protein synthesis Gastroenterology 108 515 521 1:CAS:528:DyaK2MXkvVSntb8%3D
168. D Tilman J Hill C Lehman 2006 Carbon-negative biofuels from low-input high-diversity grassland biomass Science 314 1598 1600 1:CAS:528: DC%2BD28Xht1OntL7E
169. T Treloar LJ Madden JS Winter JL Smith J Jersey 1996 Fatty acid ethyl ester synthesis by human liver microsomes Biochim Biophys Acta 1299 160 166
170. T Tsujita H Okuda 1994 The synthesis of fatty acid ethyl ester by carboxylester lipase Eur J Biochem 224 57 62 1:CAS:528:DyaK2cXlsFWqu7c%3D
171. S Ulgiati 2001 A comprehensive energy and economic assessment of biofuels: when "green" is not enough Crit Rev Plant Sci 20 71 106
172. S Uthoff T Stöveken N Weber K Vosmann E Klein R Kalscheuer A
173. S Uthoff D Bröker A Steinbüchel 2009 Current state and perspective of producing biodiesel-like compounds by biotechnology Microb Biotechnol 2 551 565
174. S Van Laere S Saerens K Verstrepen P Van Dijck J Thevelein F Delvaux 2008 Flavour formation in fungi: characterisation of K1Atf, the Kluyveromyces lactis orthologue of the Saccharomyces cerevisiae alcohol acetyltransferases Atf1 and Atf2 Appl Microbiol Biotechnol 78 783 792
175. PT Vasudevan M Briggs 2008 Biodiesel production-current state of the art and challenges J Ind Microbiol Biotech 35 421 430 1:CAS:528:DC%2BD1cXks1GnsrY%3D
176. KJ Verstrepen SDM Van Laere BMP Vanderhaegen G Derdelinchkx JP Dufour IS Pretorius J Winderickx JM Thevelein FR Delvaux 2003 Expression levels of the yeast alcohol acetyltransferase genes ATF1, Lg-ATF1, and ATF2 control the formation of a broad range of volatile esters Appl Environ Microbiol 69 5228 5237 1:CAS:528:DC%2BD3sXntlSjtbw%3D
177. L Wang W Du DH Liu LL Li NM Dai 2006 Lipase-catalyzed biodiesel production from soybean oil deodorizer distillate with absorbent present in tert-butanol system J Mol Catal B Enzyme 43 29 32 1:CAS:528:DC%2BD28Xht1SgsbrN
178. D Wang Y Xu Y Teng 2007 Synthetic activity enhancement of membrane bound lipase from Rhizopus chinensis by pretreatment with isooctane Bioprocess Biosyst Eng 30 147 155
179. Y Watanabe Y Shimada Y Sugihara H Noda H Fukuda Y Tominaga 2000 Continuous production of biodiesel fuel from vegetable oil using immobilized Candida antarctica lipase J Am Oil Chem Soc 77 355 360 1:CAS:528: DC%2BD3cXislGqtrg%3D (Pubitemid 30850920)
180. Y Watanabe Y Shimada A Sugihara Y Tominaga 2001 Enzymatic conversion of waste edible oil to biodiesel fuel in a fixed-bed bioreactor J Am Oil Chem Soc 78 703 707 1:CAS:528:DC%2BD3MXmt12htrg%3D
181. J Werner M Laposata C Fernandez-Del Castillo M Saghir R Iozzo KB Lewandrowski AL Warshaw 1997 Pancreatic injury in rats induced by fatty acid ethyl esters, a nonoxidative metabolite of alcohol Gastroenterology 113 286 294 1:CAS:528:DyaK2sXks1Ojt70%3D
182. World Energy Outlook 2008. International Energy Agency. http://www.worldenergyoutlook.org/2008.asp
183. P Wu Y Yang JA Colucci EA Grulke 2007 Effect of ultrasonication on droplet size in biodiesel mixtures J Am Oil Chem Soc 84 877 884 1:CAS:528:DC%2BD2sXhtV2qsbjM
184. VT Wyatt MA Hess RO Dunn TA Foglia MJ Haas WN Marmer 2005 Fuel properties and nitrogen oxide emission levels of biodiesel produced from animal fats J Am Oil Chem Soc 82 585 591 1:CAS:528:DC%2BD2MXhtVersbvP
185. Y Xu W Du D Liu 2003 A novel enzymatic route for biodiesel production from renewable oils in a solvent-free medium Biotechnol Lett 25 1239 1241 1:CAS:528:DC%2BD3sXmtVenurc%3D
186. S Yadvika TR Sreekrishnan S Kohli V Rana 2004 Enhancement of biogas production from solid substrates using different techniques-a review Bioresour Technol 95 1 10 1:CAS:528:DC%2BD2cXkvFyksr4%3D
187. MM Yakimov PN Golyshin S Lang ERB Moore WR Abraham H Lünsdorf KN Timmis 1998 Alcanivorax borkumensis gen. nov., sp. nov., a new, hydrocarbon-degrading and surfactant-producing marine bacterium Int J Syst Bacteriol 48 339 348 1:CAS:528:DyaK1cXkt1ajtrc%3D
188. K Yunoki Y Yasui S Hirose M Ohnishi 2005 Fatty acids in must prepared from eleven grapes grown in Japan: comparison with wine and effect on fatty acid ethyl ester formation Lipids 40 361 367 1:CAS:528:DC%2BD2MXkvF2qurc%3D
189. K Yunoki S Hirose M Ohnishi 2007 Ethyl esterification of long-chain unsaturated fatty acids derived from grape must by yeast during alcoholic fermentation Biosci Biotechnol Biochem 71 3105 3310 1:CAS:528: DC%2BD1cXktVKjtg%3D%3D
190. Zah R, Böni H, Gauch M, Hischier R, Lehmann M, Wäger P (2007) Life cycle assessment of energy products: environmental assessment of biofuels-executive summary. EMPA for the Federal Office for Energy, the Federal Office for the Environment, and the Federal Office for Agriculture, Bern
191. G Zajac W Piekarski P Krzaczek 2008 Comparison of an effect of FAME and FAEE addition to diesel fuel on energetic parameters of an engine Teka Kom Motoryz Energ Rol 8a 217 223
192. X Zhang CL Peterson D Reece R Haws G Moller 1998 Biodegradability of biodiesel in the aquatic environment Trans ASAE 41 1423 1430 1:CAS:528:DyaK1cXnt1Wgs74%3D
193. X Zhao B El-Zahab R Brosnahan J Perry P Wang 2007 An organic soluble lipase for water-free synthesis of biodiesel Appl Biochem Biotechnol 143 236 243 1:CAS:528:DC%2BD2sXhsVCmtrrI
194. W Zhou SK Konar DGB Boocock 2003 Ethyl ester from the single-phase base-catalyzed ethanolysis of vegetable oils J Am Oil Chem Soc 80 367 371 1:CAS:528:DC%2BD3sXjslGmurk%3D
195. Zoebelein H (2001) Dictionary of renewable resources. Wiley-VCH Verlag GmbH, Weinheim, p 299