Optimization of cottonseed oil ethanolysis to produce biodiesel high in Gossypol content

JAOCS, Journal of the American Oil Chemists' Society

Volumn 85, Issue 4, 2008, Pages 357-363

  Joshi, Hem Chandra ^a   Toler, Joe ^a   Walker, Terry ^a  

^a CLEMSON UNIVERSITY   (United States)

Author keywords

Alkaline catalyst; Antioxidant; Biodiesel; Cottonseed oil; Ethanolysis; Optimization; Transesterification

Indexed keywords

CATALYST ACTIVITY; ETHANOL; FATTY ACIDS; MOLAR MASS; OPTIMIZATION; OXIDATION; POTASSIUM HYDROXIDE; TRANSESTERIFICATION;

ETHANOLYSIS; FATTY ACID ETHYL ESTERS (FAEE); OXIDATIVE STABILITY;

BIODIESEL;

GOSSYPIUM HIRSUTUM; MICROPUS;

EID: 40449105324     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-008-1200-7     Document Type: Article

References (22)

1. O'Brien RD (2004) Fats and oils processing. In: Fats and oils: formulating and processing for application. CRC Press, Boca Raton, pp 16-18
2. Foglia TA, Nelson LA, Dunn RO, Marmer WN (1997) Low-temperature properties of alkyl esters of tallow and grease. J Am Oil Chem Soc 74:951-955
3. Knothe G (2005) Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters. Fuel Proc Technol 86:1059-1070
4. ASTM D 6751-07b (2007) Standard specification for biodiesel fuel blend stock (B100) for middle distillate fuels, American Society for Testing and Materials, West Conshohocken, PA
5. EN 14214-2003 (2003) Automotive fuels-fatty acid methyl esters (FAME) for diesel engines-requirement methods, European Committee for Standardization, Brussels, Belgium
6. Schuchardt U, Sercheli R, Vargas RM (1998) Transesterification of vegetable oils: a review. J Braz Chem Soc 9:199-210
7. Simoni MPM, Meneghetti MR, Wolf CR, Silva EC, Lima GES, Coimbra MA, Soletti JI, Carvalho SHV (2006) Ethanolysis of castor and cottonseed oil: a systematic study using classical catalysts. J Am Oil Chem Soc 83:819-822
8. AOCS official method ce 1-62 (1989) Fatty acid composition by gas chromatography. In: Official methods and recommended practices of the American Oil Chemist's Society, AOCS Press, Champaign
9. Hron RJ, Kuk MS, Abraham G (1990) Determination of free and total gossypol by high performance liquid chromatography. J Am Oil Chem Soc 67:182-187
10. Bikou E, Louloudi A, Papayannakos N (1999) The effect of water on the transesterification kinetics of cottonseed oil with ethanol. Chem Eng Technol 22:70-75
11. Lima da Silva N, Maciel MRW, Batistella CB, Filho RM (2006) Optimization of biodiesel production from castor oil. App Biochem Biotechnol 130:405-414
12. Christie WW (1982) A simple procedure for rapid transmethylation of glycerolipids and cholesteryl esters. J Lipid Res 23:1072-1075
13. Gaita R (2006) A reversed phase HPLC method using evaporative light scattering detection (ELSD) for monitoring the reaction and quality of biodiesel fuels, Grace Davison discovery sciences: the application notebook, industrial 51. http://www.discoverysciences.com/WorkArea/downloadasset.aspx?id=5022
14. Reddy M, Narasinga Rao MS (1987) Effect of chemical modification on the binding of gossypol by gossypin (11S protein) and congossypin (7S protein) of cottonseed. J Bioscience 12:203-209
15. AOCS official method cd 12b-92 (1999) Oil stability index (OSI). In: Official methods and recommended practices of the American Oil Chemist's Society, AOCS Press, Champaign
16. Freedman B, Pryde EH, Mounts TL (1984) Variables affecting the yields of fatty esters from transesterified vegetable oils. J Am Oil Chem Soc 61:1638-1643
17. Vicente G, Coteron A, Martinez M, Araci J (1997) Application of the factorial design of experiments and response surface methodology to optimize biodiesel production. Ind Crop Prod 8:29-35
18. Mason RL, Gunst RF, Hess JL (1989) Designs and analyses for fitting response surfaces. In: Statistic design and analysis of experiments: with applications to engineering and science, 2nd edn. Wiley, New York, pp 568-606
19. Benjamin IU, David OP, Kefas HM, Onche EO (2007) Determination of optimal catalyst concentration for maximum biodiesel yield from tigernut (Cyperus esculentus) oil. Leonardo J Sci 10:131-136
20. Zhou W, Boocock DGB (2006) Phase distribution of alcohol, glycerol, and catalyst in the transesterification of triglycerides. J Am Oil Chem Soc 83:1047-1050
21. Zhou W, Boocock DGB (2006) Phase behavior of the base-catalyzed transesterification of soybean oil. J Am Oil Chem Soc 83:1041-1045
22. Leung DYC, Guo Y (2006) Transesterification of neat and used frying oil: optimization for biodiesel production. Fuel Proc Technol 87:883-890