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Insightful and illuminating description of the stabilizing and destabilizing mechanisms of solid particles at interfaces in comparison with those of small-molecule surfactants and proteins.
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Horozov T.S., and Binks B.P. Particle-stabilized emulsions: a bilayer or a bridging monolayer?. Angew Chem Int Ed 45 (2006) 773-776. The issue of the favoured arrangement of particles in the gap between adjacent stable droplets is explicitly addressed.
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Influences of particle size and interparticle interactions on the interfacial stabilizing structure are considered from a comparative experimental perspective. Depending on pH and ionic strength, an emulsion may contain large droplets densely covered by particles or small droplets sparsely covered.
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A mixture of oil + water + nanoparticles (magnetite spheres, 11 nm) self-assembles spontaneously into a stable O/W emulsion with monodisperse droplets (30-150 nm). Apart from its opaque appearance, the particle-stabilized emulsion appears similar in properties to those of a conventional transparent surfactant-based microemulsion.
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Study of O/W emulsions containing positively charged alumina-coated silica particles + sodium docyl sulfate. The most stable systems with respect to coalescence were gel-like in consistency, with particle flocs at the oil-water interface.
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From an analysis of experimental data on triglyceride O/W emulsions stabilized by silica nanoparticles + monoglyceride, a two-stage synergistic mechanism is inferred involving the stabilizing role of monoglyceride during emulsification and that of the particles during long-term emulsion storage.
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