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Direct observations based on confocal microscopy provide unambiguous evidence for the dominant role of the interconnected depletion-flocculated network of oil droplets in the mechanism by which hydrocolloid thickener like xanthan control creaming phenomena of concentrated oil-in-water emulsions.
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Moschakis T., Murray B.S., and Dickinson E. Particle tracking using confocal microscope to probe the microrheology in a phase-separating emulsion containing nonadsorbing polysaccharide. Langmuir 22 (2006) 4710-4719. Direct observations based on confocal microscopy provide unambiguous evidence for the dominant role of the interconnected depletion-flocculated network of oil droplets in the mechanism by which hydrocolloid thickener like xanthan control creaming phenomena of concentrated oil-in-water emulsions.
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Blijdenstein T.B.J., van der Linden E., van Vliet T., and van Aken G.A. Scaling behavior of delayed demixing, rheology, and microstructure of emulsions flocculated by depletion and bridging. Langmuir 20 (2004) 11321-11328
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O/W emulsions fabricated through the membrane technique were used as a precursor to produce whipped dairy creams.
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Bouaouina H., Labbafi M., Desrumeaux A., Vial C., Insel E., Durosset P., and Bérot S. Influence of emulsification step on whipped dairy food properties. Sci Aliments 25 (2005) 353-366. O/W emulsions fabricated through the membrane technique were used as a precursor to produce whipped dairy creams.
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Bouaouina, H.1
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Preparation characteristics of monodisperse oil-in water emulsions with large particles stabilized by proteins in straight-through emulsification
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Highly monodisperse O/W emulsions stabilized by various proteins were produced using the microchannel emulsification technique. This technique is promising within the prospect of preparing materials with well defined and reproducible properties provided the production rates are augmented.
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Saito M., Yin L.-Y., Kobayashi I., and Nakajima M. Preparation characteristics of monodisperse oil-in water emulsions with large particles stabilized by proteins in straight-through emulsification. Food Hydrocoll 19 (2005) 745-751. Highly monodisperse O/W emulsions stabilized by various proteins were produced using the microchannel emulsification technique. This technique is promising within the prospect of preparing materials with well defined and reproducible properties provided the production rates are augmented.
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Saito, M.1
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Moschakis T., Murray B.S., and Dickinson E. Microstructural evolution of viscoelastic emulsions stabilised by sodium caseinate and xanthan gum. J Colloid Interface Sci 284 (2005) 714-728
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De Kruif C.G., and Tuinier R. Polysaccharide protein interactions. Food Hydrocoll 15 (2001) 555-563
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Stephen A.M. (Ed), Marcel Decker Inc, New York
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Dickinson E. Emulsion stabilization by polysaccharides and protein-polysaccharide complexes. In: Stephen A.M. (Ed). Food polysaccharides and their applications (1995), Marcel Decker Inc, New York 501-515
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Dickinson, E.1
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33845291452
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Influence of hydrocolloids on phase separation and emulsion properties of whey protein isolate
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A detailed study about the influence of ionic and neutral hydrocolloid gums on phase separation, surface activity and emulsion stability of whey protein isolates.
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Ercelebi E.A., and Ibanoglu E. Influence of hydrocolloids on phase separation and emulsion properties of whey protein isolate. J Food Eng 80 (2007) 454-459. A detailed study about the influence of ionic and neutral hydrocolloid gums on phase separation, surface activity and emulsion stability of whey protein isolates.
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Ercelebi, E.A.1
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33947183535
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Influence of pH and biopolymer ratio on whey protein-pectin interactions in aqueous solutions and in O/W emulsions
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It is demonstrated that pectin has a stabilizing effect on whey protein-stabilized emulsions both below and above the protein's isoelectric point, provided that electrostatic protein precipitation is avoided.
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Neirynck N., van der Meeren P., Lukaszewicz-Lausecker M., Cocquyt J., Verbeken D., and Dewettinck K. Influence of pH and biopolymer ratio on whey protein-pectin interactions in aqueous solutions and in O/W emulsions. Colloids Surf A 298 (2007) 99-107. It is demonstrated that pectin has a stabilizing effect on whey protein-stabilized emulsions both below and above the protein's isoelectric point, provided that electrostatic protein precipitation is avoided.
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Neirynck, N.1
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19
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In situ study of flocculation of whey protein-stabilized emulsions caused by addition of high methoxyl pectin
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Bridging and depletion flocculation of whey protein-stabilized emulsions was investigated using two promising non-destructive spectroscopic techniques, ultrasonic spectroscopy and diffusion wave spectroscopy.
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Gancz K., Alexander M., and Corredig M. In situ study of flocculation of whey protein-stabilized emulsions caused by addition of high methoxyl pectin. Food Hydrocoll 20 (2006) 293-298. Bridging and depletion flocculation of whey protein-stabilized emulsions was investigated using two promising non-destructive spectroscopic techniques, ultrasonic spectroscopy and diffusion wave spectroscopy.
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Gancz, K.1
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20
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It is shown that casein addition can inhibit phase separation of β-lactoglobulin-stabilized emulsions for more than 1 year. The enhanced stability may be increased further by thermal processing. The extra stabilizing effect of heating in the presence of caseins opens the possibility of improving the shelf life of products like whipped toppings.
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Parkinson E.L., and Dickinson E. Synergetic stabilization of heat-treated emulsions containing mixtures of milk proteins. Int Dairy J 17 (2007) 95-103. It is shown that casein addition can inhibit phase separation of β-lactoglobulin-stabilized emulsions for more than 1 year. The enhanced stability may be increased further by thermal processing. The extra stabilizing effect of heating in the presence of caseins opens the possibility of improving the shelf life of products like whipped toppings.
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Int Dairy J
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Parkinson, E.L.1
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33646940699
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A simple route to avoid thermally-induced droplet aggregation in emulsions stabilized by soy protein isolates is proposed. It consists of incubating soy protein isolates-dextran mixtures in water at 60 °C for time periods up to 30 min prior to emulsification. The stabilizing effect is explained in terms of polysaccharide-protein hybrid formation, which then adsorbed at the emulsion droplet surfaces thus preventing droplet aggregation.
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Diftis N., and Kiosseoglou V. Stability against heat-induced aggregation of emulsions prepared with a dry-heated soy protein isolate-dextran mixture. Food Hydrocoll 20 (2006) 787-792. A simple route to avoid thermally-induced droplet aggregation in emulsions stabilized by soy protein isolates is proposed. It consists of incubating soy protein isolates-dextran mixtures in water at 60 °C for time periods up to 30 min prior to emulsification. The stabilizing effect is explained in terms of polysaccharide-protein hybrid formation, which then adsorbed at the emulsion droplet surfaces thus preventing droplet aggregation.
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Food Hydrocoll
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Diftis, N.1
Kiosseoglou, V.2
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Princen H.M., and Kiss A.D. Rheology of foams and highly concentrated emulsions: III. Static shear modulus. J Colloid Interface Sci 112 (1986) 427-437
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Becher P. (Ed), Marcel Dekker, New York [Ch.6]
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Dimitrova T., and Leal Calderon F. Bulk, elasticity of concentrated protein-stabilized emulsions. Langmuir 17 (2001) 3235-3244
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Rheological properties of concentrated emulsions stabilized by globular protein in the presence of non-ionic surfactant
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An interesting study about the viscoelastic properties of concentrated oil-in-water emulsions as a function of the surfactant/protein molar ratio in the aqueous phase. The elasticity drastically falls above some threshold value of the molar ratio because of the gradual displacement of the protein by the surfactant.
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Derkatch, S.R.1
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Fechner A., Knoth A., Scherze I., and Muschiolik G. Stability and release properties of double-emulsions stabilized by caseinate-dextran conjugates. Food Hydrocoll 21 (2007) 943-952
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Fechner, A.1
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33747783293
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Protection of Lactobacillus acidophilus from the low pH of a model gastric juice by incorporation in a W/O/W emulsion
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A water-in-oil-in-water emulsion (W/O/W) was used to protect bacteria against the bactericidal effect of the gastric fluids. Lactic acid bacteria were included in the internal water phase, which was protected by the oil phase against the low pH in the external water phase. This strategy is interesting within the prospect of improving the beneficial effects of viable probiotics.
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Shima M., Morita Y., Yamashita M., and Adachi S. Protection of Lactobacillus acidophilus from the low pH of a model gastric juice by incorporation in a W/O/W emulsion. Food Hydrocoll 20 (2006) 1164-1169. A water-in-oil-in-water emulsion (W/O/W) was used to protect bacteria against the bactericidal effect of the gastric fluids. Lactic acid bacteria were included in the internal water phase, which was protected by the oil phase against the low pH in the external water phase. This strategy is interesting within the prospect of improving the beneficial effects of viable probiotics.
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Food Hydrocoll
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Shima, M.1
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Garti N., Aserin A., and Cohen Y. Mechanistic considerations on the release of electrolytes from multiple emulsions stabilized by BSA and non-ionic surfactants. J Control Release 29 (1994) 41-51
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Sela Y., Magdassi Y., and Garti N. Release of markers from the inner water phase of W/O/W emulsions stabilized by silicone based polymeric surfactants. J Control Release 33 (1995) 1-12
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Biopolymeric complexes of protein and polysaccharide are used to stabilize W/O/W double emulsions. It is likely that such complexes adsorb onto the oil globules, forming thick and efficient barriers against release of the species initially encapsulated in the internal water droplets.
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Benichou A., Aserin A., and Garti N. W/O/W double emulsions stabilized with WPI-polysaccharide complexes. Colloids Surf A 294 (2007) 20-32. Biopolymeric complexes of protein and polysaccharide are used to stabilize W/O/W double emulsions. It is likely that such complexes adsorb onto the oil globules, forming thick and efficient barriers against release of the species initially encapsulated in the internal water droplets.
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Benichou A., Aserin A., and Garti N. O/W/O double emulsions stabilized with WPI-polysaccharide conjugates. Colloids Surf A 297 (2007) 211-220
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37
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Preparation of multiple emulsions based on thermodynamic incompatibility of heat-denaturated whey protein and pectin solutions
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This study shows that various types of multiple emulsions can be prepared by mixing an O/W emulsion, with a mixed biopolymer solution that separates into two phases. In particular, O/W/W emulsions are produced. Such systems may have novel applications in the food industry, such as production of reduced fat products, controlled release of non polar components from oil droplets.
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Kim H.-J., Decker E.A., and McClements D.J. Preparation of multiple emulsions based on thermodynamic incompatibility of heat-denaturated whey protein and pectin solutions. Food Hydrocoll 20 (2006) 586-595. This study shows that various types of multiple emulsions can be prepared by mixing an O/W emulsion, with a mixed biopolymer solution that separates into two phases. In particular, O/W/W emulsions are produced. Such systems may have novel applications in the food industry, such as production of reduced fat products, controlled release of non polar components from oil droplets.
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Food Hydrocoll
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, pp. 586-595
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Kim, H.-J.1
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38
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It is demonstrated that the totally or partially crystallized state of the oil in W/O/W emulsions may slow down the rate of release of encapsulated hydrophilic compounds.
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Weiss J., Scherze I., and Muschiolik G.. Polysaccharide gel with multiple emulsions. Food Hydrocoll 19 (2005) 605-615. It is demonstrated that the totally or partially crystallized state of the oil in W/O/W emulsions may slow down the rate of release of encapsulated hydrophilic compounds.
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Davies E., Dickinson E., and Bee R. Shear stability of sodium caseinate emulsions containing monoglyceride and triglyceride crystals. Food Hydrocoll 14 (2000) 145-153
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van Aken G.A. Aeration of emulsions by whipping. Colloids Surf A 190 (2001) 333-354
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33646791534
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This paper describes the effect of shear on the stability of emulsions made of non-Brownian semi-crystalline droplets. The authors demonstrate the existence of an irreversible transition where the droplets aggregate at relatively low volume fractions. The work reveals the importance of hydrodynamic forces in reducing the energy barrier that prevents droplets from aggregation.
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Guery J., Bertrand E., Rouzeau C., Levitz P., Weitz D.A., and Bibette J. Irreversible shear-activated aggregation in non-Brownian suspensions. Phys Rev Lett 96 (2006) 198301. This paper describes the effect of shear on the stability of emulsions made of non-Brownian semi-crystalline droplets. The authors demonstrate the existence of an irreversible transition where the droplets aggregate at relatively low volume fractions. The work reveals the importance of hydrodynamic forces in reducing the energy barrier that prevents droplets from aggregation.
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Phys Rev Lett
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42
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33646351279
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Selection of surfactants for stable paraffin-in-water dispersions, undergoing solid-liquid transition of the dispersed particles
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It is demonstrated that gelation may be induced by a jamming transition (flow hindering) induced by droplet anisotropy upon crystallisation.
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Golemanov K., Tcholakova S., Denkov N.D., and Gurko T. Selection of surfactants for stable paraffin-in-water dispersions, undergoing solid-liquid transition of the dispersed particles. Langmuir 22 (2006) 3560-3569. It is demonstrated that gelation may be induced by a jamming transition (flow hindering) induced by droplet anisotropy upon crystallisation.
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Destabilization of O/W emulsions containing fat crystals by temperature cycling
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Boode K., Bisperink C., and Walstra P. Destabilization of O/W emulsions containing fat crystals by temperature cycling. Colloids Surf A 61 (1991) 55-74
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(1991)
Colloids Surf A
, vol.61
, pp. 55-74
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Boode, K.1
Bisperink, C.2
Walstra, P.3
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45
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12344293425
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Effect of denaturation on temperature cycling stability of heated acidified protein-stabilized O/W emulsion gels
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This paper addresses how protein type and state affect the temperature cycling stability of acidified protein-stabilized O/W emulsions.
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Kiokias S., and Bot A. Effect of denaturation on temperature cycling stability of heated acidified protein-stabilized O/W emulsion gels. Food Hydrocoll 19 (2005) 493-501. This paper addresses how protein type and state affect the temperature cycling stability of acidified protein-stabilized O/W emulsions.
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(2005)
Food Hydrocoll
, vol.19
, pp. 493-501
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Kiokias, S.1
Bot, A.2
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46
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25844508508
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Temperature cycling stability of pre-heated acidified whey protein-stabilized O/W emulsion gels in relation to the internal surface area of the emulsion
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Kiokias S., and Bot A. Temperature cycling stability of pre-heated acidified whey protein-stabilized O/W emulsion gels in relation to the internal surface area of the emulsion. Food Hydrocoll 20 (2006) 245-252
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(2006)
Food Hydrocoll
, vol.20
, pp. 245-252
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Kiokias, S.1
Bot, A.2
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47
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33947144131
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Effect of processing on droplet cluster structure in emulsion gels
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The paper presents the potentiality of a non-invasive technique, spin-echo small angle neutron-scattering to probe the structure of emulsion droplet aggregates.
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Bot A., Duval F.P., and Bouwman W.G. Effect of processing on droplet cluster structure in emulsion gels. Food Hydrocoll 21 (2007) 844-854. The paper presents the potentiality of a non-invasive technique, spin-echo small angle neutron-scattering to probe the structure of emulsion droplet aggregates.
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(2007)
Food Hydrocoll
, vol.21
, pp. 844-854
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Bot, A.1
Duval, F.P.2
Bouwman, W.G.3
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48
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33750287105
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Bicontinuous emulsion gels induced by partial coalescence: kinetics and mechanism
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An interesting study about the microscopic mechanism at the origin of partial coalescence. The experimental data support the idea that coalescence requires the contact between solid and liquid patches in the thin liquid films separating two partially crystallized droplets.
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Thivilliers F., Drelon N., Schmitt V., and Leal-Calderon V. Bicontinuous emulsion gels induced by partial coalescence: kinetics and mechanism. Europhys Lett 76 (2006) 332-338. An interesting study about the microscopic mechanism at the origin of partial coalescence. The experimental data support the idea that coalescence requires the contact between solid and liquid patches in the thin liquid films separating two partially crystallized droplets.
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(2006)
Europhys Lett
, vol.76
, pp. 332-338
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Thivilliers, F.1
Drelon, N.2
Schmitt, V.3
Leal-Calderon, V.4
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49
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34248367262
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Gelling of oil-in-water emulsions comprising crystallized droplets
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Giermanska J., Schmitt V., Drelon N., Thivilliers F., and Leal-Calderon F. Gelling of oil-in-water emulsions comprising crystallized droplets. Langmuir 23 (2007) 4792-4799
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(2007)
Langmuir
, vol.23
, pp. 4792-4799
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Giermanska, J.1
Schmitt, V.2
Drelon, N.3
Thivilliers, F.4
Leal-Calderon, F.5
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50
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33748329640
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Influence of temperature cycling ("tempering") on the mechanical properties of whipped dairy creams
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Drelon N., Gravier E., Boisserie L., Omari A., and Leal-Calderon F. Influence of temperature cycling ("tempering") on the mechanical properties of whipped dairy creams. Int Dairy J 16 (2006) 1454-1463
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(2006)
Int Dairy J
, vol.16
, pp. 1454-1463
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Drelon, N.1
Gravier, E.2
Boisserie, L.3
Omari, A.4
Leal-Calderon, F.5
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51
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33744511723
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Consolidation of foams deriving from emulsions by temperature cycling ("tempering")
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Drelon N., Gravier E., Boisserie L., Omari A., and Leal-Calderon F. Consolidation of foams deriving from emulsions by temperature cycling ("tempering"). Colloids Surf A 282-283 (2006) 360-368
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(2006)
Colloids Surf A
, vol.282-283
, pp. 360-368
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Drelon, N.1
Gravier, E.2
Boisserie, L.3
Omari, A.4
Leal-Calderon, F.5
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52
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12344282739
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Factors affecting fat droplet aggregation in whipped frozen protein-stabilized emulsions
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Relkin P., and Sourdet S. Factors affecting fat droplet aggregation in whipped frozen protein-stabilized emulsions. Food Hydrocoll 19 (2005) 503-511
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(2005)
Food Hydrocoll
, vol.19
, pp. 503-511
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Relkin, P.1
Sourdet, S.2
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53
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33746223561
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Effects of whey protein aggregation on fat globule microstructure in whipped frozen emulsions
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This paper provides a useful trick to improve the textural properties of whipped frozen products. It is demonstrated that in aerated products, partial replacement of native whey proteins by pre-denatured whey proteins or casein modifies the microstructure, promoting a smaller and more uniform air bubble size distribution and a higher degree of connectivity between the fat globules.
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Relkin P., Sourdet S., Smith A.K., Goff H.D., and Cuvelier G. Effects of whey protein aggregation on fat globule microstructure in whipped frozen emulsions. Food Hydrocoll 20 (2006) 1050-1056. This paper provides a useful trick to improve the textural properties of whipped frozen products. It is demonstrated that in aerated products, partial replacement of native whey proteins by pre-denatured whey proteins or casein modifies the microstructure, promoting a smaller and more uniform air bubble size distribution and a higher degree of connectivity between the fat globules.
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(2006)
Food Hydrocoll
, vol.20
, pp. 1050-1056
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Relkin, P.1
Sourdet, S.2
Smith, A.K.3
Goff, H.D.4
Cuvelier, G.5
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54
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32244436127
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Discussion session on food emulsions and foams
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Kokini J., and van Aken G. Discussion session on food emulsions and foams. Food Hydrocoll 20 (2006) 438-445
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(2006)
Food Hydrocoll
, vol.20
, pp. 438-445
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Kokini, J.1
van Aken, G.2
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