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Volumn 22, Issue 1, 2010, Pages 117-129

Competing mechanisms in atomic layer deposition of Er2 O 3 versus la2O3 from cyclopentadienyl precursors

Author keywords

[No Author keywords available]

Indexed keywords

ALD GROWTH; COMPETING MECHANISMS; CONTROLLED GROWTH; CYCLOPENTADIENYL PRECURSOR; CYCLOPENTADIENYLS; FIRST-PRINCIPLES; GROWTH REACTIONS; HEXAGONAL PHASE; HYDROGEN TRANSFER; KEY REACTIONS; METAL PRECURSOR; NANOSCALE THIN FILMS; OXIDE SURFACE; PERIODIC DENSITY FUNCTIONAL THEORY; PRECURSOR MOLECULES; RARE EARTH OXIDE; RARE-EARTH METAL OXIDE; REACTIVE ADSORPTION; TECHNOLOGY APPLICATION;

EID: 74949135904     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm902469c     Document Type: Article
Times cited : (30)

References (52)
  • 4
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    • Topics in Appled Physics series; Franciulli, M., Giovanna, S., Eds.; Springer: New York
    • Rare Earth Oxide Thin Films: Growth, Characterisation and Applications, Topics in Appled Physics series; Franciulli, M., Giovanna, S., Eds.; Springer: New York, 2007; p 106.
    • (2007) Rare Earth Oxide Thin Films: Growth, Characterisation and Applications , pp. 106
  • 20
    • 74949102780 scopus 로고    scopus 로고
    • PhD Thesis, Helsinki University of Technology, Finland
    • J. Niinisẗ, PhD Thesis, Helsinki University of Technology, Finland, 2004
    • (2004)
    • Niinisẗ, J.1
  • 40
    • 0003516749 scopus 로고    scopus 로고
    • 4th ed.; Oxford University Press: New York
    • Atkins, P. W. Physical Chemistry, 4th ed.; Oxford University Press: New York, 2004.
    • (2004) Physical Chemistry
    • Atkins, P.W.1
  • 45
    • 74949135326 scopus 로고    scopus 로고
    • We have also checked how relaxing the constraints on the proton impacts on the reaction and we find that if the proton is completely free to relax, it will return to the surface, unless it is already bonded to Cp. With the z-direction perpendicular to the surface, constraining along z gives results similar to fully constraining the proton, while constraining along x and y gives results similar to having no constraints on the proton
    • We have also checked how relaxing the constraints on the proton impacts on the reaction and we find that if the proton is completely free to relax, it will return to the surface, unless it is already bonded to Cp. With the z-direction perpendicular to the surface, constraining along z gives results similar to fully constraining the proton, while constraining along x and y gives results similar to having no constraints on the proton.
  • 47
    • 0001314440 scopus 로고
    • Ada Crystallogr. 1970, B26, 1046 .
    • (1970) Ada Crystallogr. , vol.B26 , pp. 1046
  • 52
    • 74949118153 scopus 로고    scopus 로고
    • The thickness increment per cycle depends on the molar increment per cycle and on the density of the film
    • The thickness increment per cycle depends on the molar increment per cycle and on the density of the film.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.