Erratum: EPR spectroscopy that the unpaired electron in an Os 27+ species is in a δ* metal-based molecular orbital (Inorg. Chem. (2009) 49: 1 (319-324) DOI: 10.1021/ic902087e);Proof by EPR spectroscopy that the unpaired electron in an Os 27+ species is in a δ metal-based molecular orbital

Inorganic Chemistry

Volumn 49, Issue 1, 2010, Pages 319-324

  Dalal, Naresh S ^b   Cotton, F Albert ^c   Chiarella, Gina M ^a   Murlllo, Carlos A ^a   Wang, Zhenxing ^b   Young, Mark D ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b FLORIDA STATE UNIVERSITY   (United States)

^c NONE

Author keywords

[No Author keywords available]

Indexed keywords

EID: 73349110446     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic500117b     Document Type: Erratum

References (67)

1. Cotton, F. A.; Curtis, N. F.; Harris, C. B.; Johnson, B. F. G.; Lippard, S. J.; Mague, J. T.; Robinson, W. R.; Wood, J. S. Science 1964, 145, 1305.
2. Multiple Bonds between Metal Atoms; Cotton, F. A., Murillo, C. A., Walton, R. A., Eds.; Springer Science and Business Media, Inc.: New York, 2005.
3. (a) Cotton, F. A.; Hillard, E. A.; Murillo, C. A. J. Am. Chem. Soc. 2003, 125, 2026.
4. (b) Cotton, F. A.; Hillard, E. A.; Murillo, C. A.; Wang, X. Inorg. Chem. 2003, 42, 6063.
5. (a) Cotton, F. A.; Daniels, L. M.; Falvello, L. R.; Matonic, J. H.; Murillo, C. A. Inorg. Chim. Acta 1997, 256, 269.
6. (b) Cotton, F. A.; Feng, X.; Murillo, C. A. Inorg. Chim. Acta 1997, 256, 303.
7. (a) Cotton, F. A.; Daniels, L. M.; Maloney, D. J.; Matonic, J. H.; Murillo, C. A. Inorg. Chim. Acta 1997, 256, 283.
8. (b) Cotton, F. A.; Li, Z.; Murillo, C. A.; Poplaukhin, P. V.; Reibenspies, J. H. J. Cluster Sci. 2008, 19, 89.
9. Coles, M. P. Chem. Commun. 2009, 3659.
10. (a) Cotton, F. A.; Durivage, J. C.; Gruhn, N. E.; Lichtenberger, D. L.; Murillo, C. A.; Van Dorn, L. O.; Wilkinson, C. C. J. Chem. Phys. B 2006, 110, 19793.
11. (b) Cotton, F. A.; Murillo, C. A.; Wang, X.; Wilkinson, C. C. Dalton Trans. 2007, 3943.
12. Cotton, F. A.; Huang, P.; Murillo, C. A.; Wang, X. Inorg. Chem. Commun. 2003, 6, 121.
13. Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Timmons, D. J.; Wilkinson, C. C. J. Am. Chem. Soc. 2002, 124, 9249.
14. Cotton, F. A.; Gruhn, N. E.; Gu, J.; Huang, P.; Lichtenberger, D. L.; Murillo, C. A.; Van Dorn, L. O.; Wilkinson, C. C. Science 2002, 298, 1971.
15. Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry, 6th ed.; John Wiley & Sons, Inc.: New York, 1999.
16. Cotton, F. A.; Donahue, J. P.; Gruhn, N. E.; Lichtenberger, D. L.; Murillo, C. A.; Timmons, D. J.; Van Dorn, L. O.; Villagrán, D.; Wang, X. Inorg. Chem. 2006, 45, 201.
17. See for example: (a) Foley, S. R.; Yap, G. P. A.; Richeson, D. S. Polyhedron 2002, 21, 619.
18. (b) Soria, D. B.; Grundy, J.; Coles, M. P.; Hitchcock, P. B. J. Organomet. Chem. 2005, 690, 2315.
19. (c) Coles, M. P.; Hitchcock, P. B. Organometallics 2003, 22, 5201.
20. (d) Coles, M. P.; Hitchcock, P. B. Dalton Trans. 2001, 1169.
21. (e) Coles, M. P.; Hitchcock, P. B. Inorg. Chim. Acta 2004, 357, 4330.
22. (f) Oakley, S. H.; Coles, M. P.; Hitchcock, P, B. Inorg. Chem. 2004, 43, 7564.
23. (g) Coles, M. P.; Hitchcock, P. B Eur. J. Inorg. Chem. 2004, 2662.
24. (h) Irwin, M. D.; Abdou, H. E.; Mohamed, A. A.; Fackler, J. P., Jr. Chem. Commun. 2003, 2882.
25. (i) Feil, F.; Harder, S. Eur. J. Inorg. Chem. 2005, 4438.
26. (j) Wilder, C. B.; Reitfort, L. L.; Abboud, K. A.; McElwee-White, L. Inorg. Chem. 2006, 45, 263.
27. (k) Rische, D.; Baunemann, A.; Winter, M.; Fischer, R. A. Inorg. Chem. 2006, 45, 269.
28. (l) Edelmann, F. T. Chem. Soc. Rev. 2009, 2253.
29. Cotton, F. A.; Murillo, C. A.; Wang, X.; Wilkinson, C. C. Inorg. Chim. Acta 2003, 351, 191.
30. Cotton, F. A.; Dalai, N. S.; Huang, P.; Murillo, C. A.; Stowe, A. C.; Wang, X. Inorg. Chem. 2003, 42, 670.
31. (a) Novak, I.; Wei, X.; Chin, W. S. J. Phys. Chem. A 2001, 105, 1783.
32. (b) Lee, T. H.; Rabalais, J. W.; J., W. J. Electron Spectrosc. Relat. Phenom. 1977, 11, 123.
33. For a review of diosmium compounds, see: Multiple Bonds between Metal Atoms, Ren, T., Cotton, F. A., Murillo, C. A., Walton, R. A., Eds. Springer Science and Business Media, Inc.: New York, 2005, Chapter 10, p. 431.
34. z) range from 2.002 to 2.009. See: Un, S.; Gerez, C.; Elleingand, E.; Fontecave, M. J. Am. Chem. Soc. 2001, 123, 3048.
35. (b) Similarly for the phenoxyl radical the spread of these values is 2.0022 to 2.0067. See: Benisvy, L.; Bittl, R.; Bothe, E.; Gamer, C. D.;McMaster, J.; Ross, S.; Teuloff, C.; Neese, F. Angew. Chem., Int. Ed. 2005, 44, 5314.
36. For additional examples of systems of biological interest, see: (a) Kay, C. W.; Bittl, R.; Bacher, A.; Richter, G.; Weber, S.J. Am. Chem. Soc. 2005, 127, 10780.
37. (b) Anderson, K. K.; Schmidt, P. P.; Katterle, B.; Stand, K. R.; Palmer, A. E.; Lee, S.-K.; Solomon, E. I.; Gräslund, A.; Barra, A.-L. J. Biol. Inorg. Chem. 2003, 8, 235.
38. (c) Un, S.; Gerez, C.; Elleingand, E.; Fontecave, M. J. Am. Chem. Soc. 2001, 123, 3048.
39. Clérac, R.; Cotton, F. A.; Daniels, L. M.; Donahue, J. P.; Murillo, C. A.; Timmons, D. J. Inorg. Chem. 2000, 39, 2581.
40. (a) Cotton, F. A.; Murillo, C. A.; Reibenspies, J. H.; Villagrán, D.; Wang, X.; Wilkinson, C. C. Inorg. Chem. 2004, 43, 8373.
41. (b) Chen, W.-Z.; Cotton, F. A.; Dalal, N. S.; Murillo, C. A.; Ramsey, C. M.; Ren, T.; Wandg, X. J. Am. Chem. Soc. 2005, 127, 12691.
42. (c) Cotton, F. A.; Herrero, S.; Jiménez-Aparicio, R.; Murillo, C. A.; Urbanos, F. A.; Villagrán, D.; Wang, X. J. Am. Chem. Soc. 2007, 129, 12666.
43. Weil, J. Bolton, J. Electron Paramagnetic Resonance: Elementary Theory and Practical Applications, 2nd ed., Chapter 10; Wiley: New York, 2007.
44. The simulation was done with Andrzej Ozarowski's program SPIN. For more information contact Dr. Andrzej Ozarowski at the National High Magnetic Field Laboratory in Tallahassee, Florida (ozarowsk@magnet.fsu. edu).
45. See for example: (a) Ye, S.; Sarkar, B; Duboc, C.; Fiedler, J.; Kaim, W. Inorg. Chem. 2005, 44, 2843.
46. (b) Salmonsen, R. B.; Abelleira, A.; Clarke, M. J. Inorg. Chem. 1984, 23, 387.
47. (c) Patra, S.; Sarkar, B.; Mobin, S. M.; Kaim, W.; Lahiri, G. K. Inorg. Chem. 2003, 42, 6469.
48. 3 obtained on a single crystal at 100 K that has g = 3.30, 1.65, and 0.36. See: Rieger, P. H. Coord. Chem. Rev. 1994, 135-136, 203, and references therein.
49. This method provides only an approximation because the Os-Os bonds are not aligned precisely with the crystallographic axis.
50. See for example: (a) Miskowski, V.; Gray, H. B. Top. Cur. Chem. 1997, 191, 41.
51. (b) Barral, M. C.; Jiménez-Aparicio, R.; Pérez-Quintanilla, D.; Priego, J. L.; Royer, E. C; Torres, M. R.; Urbanos, F. A. Inorg. Chem. 2000, 39, 65.
52. (c) Angaritis, P.; Cotton, F. A.; Murillo, C. A.; Villagrán, D.; Wang, X. J. Am. Chem. Soc. 2005, 127, 5008.
53. (a) Telser, J.; Drago, R. S. Inorg. Chem. 1984, 23, 3114.
54. (b) Drago, R. S.; Cosmano, R.; Telser, J. Inorg. Chem. 1984, 23, 3120.
55. (c) Chen, W.-Z.; Cotton, F. A.; Dalal, N. S.; Murillo, C. A.; Ramsey, C. M.; Ren, T.; Wang, X. J. Am. Chem. Soc. 2005, 127, 12691.
56. See for example: (a) Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Huang, P.; Villagrán, D. Z. Anorg. Allg. Chem. 2005, 631, 2606.
57. (b) Cotton, F. A.; Hillard, E. A.; Murillo, C. A. Inorg. Chem. 2002, 41, 1639.
58. (c) Cotton, F. A.; Dalal, N. S.; Liu, C. Y.; Murillo, C. A.; North, J. M.; Wang, X. J. Am. Chem. Soc. 2003, 125, 12945.
59. It should be noted that an unpaired electron in a MO would involve substantial ligand character and, thus, would be expected to display less g anisotropy than that of an electron in an Os-based δ* orbital.
60. Cotton, F. A; Dalal, N. S.; Huang, P.; Ibragimov, S. A.; Murillo, C. A.; Piccoli, P. M. B.; Ramsey, C. M.; Schultz, A. J.; Wang, X.; Zhao, Q. Inorg. Chem. 2007, 46, 1718.
61. 2δ* electronic configuration.
62. Cotton, F. A.; Gu, J.; Murillo, C. A.; Timmons, D. J. J. Chem. Soc., Dalton Trans. 1999, 3741.
63. SMART for Windows NT, version 5.618; Bruker Advanced X-ray Solutions, Inc.: Madison, WI, 2001.
64. SAINT. Data Reduction Software, version 6.36A; Bruker Advanced X-ray Solutions, Inc.: Madison, WI, 2002.
65. SADABS. Area Detector Absorption and other Corrections Software, version 2.03; Bruker Advanced X-ray Solutions, Inc.: Madison, WI, 2002.
66. Sheldrick, G. M. SHELX-97 Programs for Crystal Structure Analysis, Institüt für Anorganische Chemie der Universität: Göttingen, Germany, 1998.
67. Sheldrick, G. M. SHELXTL, version 6.10; Bruker Advanced X-ray Solutions, Inc.: Madison, WI, 2000.