How small variations in crystal interactions affect macroscopic properties

Journal of the American Chemical Society

Volumn 129, Issue 42, 2007, Pages 12666-12667

  Cotton, F Albert ^a   Herrero, Santiago ^b   Jiménez Aparicio, Reyes ^b   Murillo, Carlos A ^a   Urbanos, Francisco A ^b   Villagrán, Dino ^a   Wang, Xiaoping ^a,c  

^a TEXAS A AND M UNIVERSITY   (United States)

^b UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

^c UNIVERSITY OF NORTH TEXAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DNA; FORMAMIDE DERIVATIVE; HYDROGEN SULFIDE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; RUTHENIUM;

ACCELERATION; ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; DNA HELIX; ELECTRON TRANSPORT; ENANTIOSELECTIVITY; ENERGY; HYDROGEN BOND; MAGNETISM; MOLECULAR INTERACTION; TEMPERATURE DEPENDENCE; X RAY CRYSTALLOGRAPHY;

BIOCHEMISTRY; CHEMISTRY, PHYSICAL; COBALT; CRYSTALLIZATION; CRYSTALLOGRAPHY, X-RAY; DNA; ELECTRONS; GASES; MAGNETICS; MOLECULAR CONFORMATION; RUTHENIUM; TEMPERATURE;

EID: 35548979998     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja075808z     Document Type: Article

References (23)

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20. 2 distance increases as temperature increases. As indicated in the caption to Figure 1 and Figure S1, the donor⋯acceptor distances for the hydrogen bonding interactions for O3⋯O5 and O9⋯O11 remain essentially constant with temperature. However, those for O9⋯O2S change significantly.
21. 2 may also be possible.
22. -1·K.
23. 2 distances DFT calculations, structural work using neutron studies and variable pressure as well as measurements using VT high-field EPR appear to be necessary. These will be done in due time. However, it should be pointed out that our intention in this paper is to call attention as to how small variations in crystal interactions may have large effects in physical properties.