Fully Localized Mixed-Valence Oxidation Products of Molecules Containing Two Linked Dimolybdenum Units: An Effective Structural Criterion

Journal of the American Chemical Society

Volumn 125, Issue 42, 2003, Pages 12945-12952

  Cotton, F Albert ^a   Dalal, Naresh S ^b   Liu, Chun Y ^a   Murillo, Carlos A ^a   North, J Micah ^b   Wang, Xiaoping ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b FLORIDA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTALLOGRAPHY; ELECTRONS; FERROMAGNETISM; MOLECULAR STRUCTURE; MOLYBDENUM COMPOUNDS; NEGATIVE IONS; OXIDATION; PARAMAGNETIC RESONANCE;

MONO-CHARGED CATIONS;

MOLECULES;

ANION; MOLYBDENUM COMPLEX;

ARTICLE; CHEMICAL BOND; COMPLEX FORMATION; CRYSTALLOGRAPHY; ELECTRON SPIN RESONANCE; MAGNETISM; OXIDATION; PHOTOSYSTEM II; REDUCTION;

EID: 0142029084     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036920+     Document Type: Article

References (59)

1. See, for example: (a) Prassides, K. Ed. Mixed Valency Systems: Applications in Chemistry, Physics and Biology; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1991.
2. (b) Kitagawa, H.; Onodera, N.; Sonoyama, T.; Yamamoto, M.; Fukawa, T.; Mitani, T.; Seto, M.; Maeda, Y. J. Am. Chem. Soc. 1999, 121, 10068.
3. (c) Dinda, R.; Sengupta, P.; Ghosh, S.; Mak, T. C. W. Inorg. Chem. 2002, 41, 1684.
4. (d) Hagadorn, J. R.; Que, L., Jr.; Tolman, W. B. J. Am. Chem. Soc. 1999, 121, 9760.
5. (e) Nelsen, S. F. Chem.-Eur. J. 2000, 6, 581.
6. (a) Pecoraro, V. L.; Hsieh, W.-Y. In Manganese and its Role in Biological Processes; Sigel, A., Siegel, H., Eds.; Marcel Dekker: New York, 2000; Vol. 37.
7. (b) Alexiou, M.; Dendrinou-Sumara, C.; Karagianni, A.; Biswas, S.; Zaleski, C. M.; Kampf, J.; Yoder, D.; Penner-Hahn, J. E.; Pecoraro, V. L.; Kessissoglou, D. P. Inorg. Chem. 2003, 42, 2185.
8. (a) Cammack, R. In Advances in Inorganic Chemistry: Iron Sulfur Proteins; Cammack, R., Sykes, A. G., Eds.; Academic Press: San Diego, CA, 1992; Vol. 38, pp 281-322.
9. (b) Holm, R. H.; Kennepohl, P.; Solomon, E. I. Chem. Rev. 1996, 96, 2239.
10. (c) Stephens, P. J.; Jollie, D. R.; Warshel, A. Chem. Rev. 1996, 96, 2491.
11. (a) Robinson, H.; Ang, M. C.; Gao, Y.-G.; Hay, M. T.; Lu, Y.; Wang, A. H.-J. Biochemistry 1999, 38, 5677.
12. (b) Wilmmans, M.; Lappalainen, P.; Kelly, M.; Sauer-Eriksson, E.; Saraste, M. Proc. Natl. Acad. Sci. U.S.A. 1995, 92, 11955.
13. (a) Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
14. (b) Richardson, D. E.; Taube, H. Coord. Chem. Rev. 1984, 60, 107.
15. (a) Demadis, K. D.; Hartshom, C. M.; Meyer, T. J. Chem. Rev. 2001, 101, 2655.
16. (b) Brunschwig, B. S.; Creutz, C.; Sutin, N. Chem. Soc. Rev. 2002, 31, 168.
17. (c) Kaim, W.; Klein, A.; Glöckle, M. Acc. Chem. Res. 2000, 33, 755.
18. (a) Creutz, C.; Taube, H. J. Am. Chem. Soc. 1969, 91, 3988.
19. (b) Creutz, C.; Taube, H. J. Am. Chem. Soc. 1973, 95, 1086.
20. (c) Brunschwig, B. S.; Creutz, C.; Sutin, N. Chem. Soc. Rev. 2002, 31, 168.
21. (a) Fürholz, U.; Bürgi, H.-B.; Wagner, F. E.; Stebler, A.; Ammeter, J. H.; Krausz, E.; Clark, R. J. H.; Stead, M. J.; Ludi, A. J. Am. Chem. Soc. 1984, 106, 121.
22. (b) Fürholz, U.; Joss, S.; Bürgi, H.-B.; Ludi, A. Inorg. Chem. 1985, 24, 943.
23. (a) Cotton, F. A.; Donahue, J. P.; Lin, C.; Murillo, C. A. Inorg. Chem. 2001, 40, 1234.
24. (b) Cotton, F. A.; Donahue, J. P.; Murillo, C. A. Inorg. Chem. 2001, 40, 2229.
25. (c) Cotton, F. A.; Daniels, L. M.; Donahue, J. P.; Liu, C. Y.; Murillo, C. A. Inorg. Chem. 2002, 41, 1354.
26. (d) Cotton, F. A.; Donahue, J. P.; Murillo, C. A. J. Am. Chem. Soc. 2003, 125, 5436.
27. (e) Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Pérez, L. M. J. Am. Chem. Soc. 2003, 125, 5486.
28. (f) Cotton, F. A.; Lin, C.; Murillo, C. A. Acc. Chem. Res. 2001, 34, 759.
29. Richardson, D. E.; Taube, H. Inorg. Chem. 1981, 20, 1278.
30. -12 s. See: Schering, T.; Kaim, W.; Olabe, J. A.; Parise, A. R.; Fiedler, J. Inorg. Chim. Acta 2000, 300-302, 125.
31. See, for example: (a) Cotton, F. A.; Hillard, E. A.; Murillo, C. A. Inorg. Chem. 2002, 41, 1639.
32. (b) Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Wilkinson, C. C. J. Am. Chem. Soc. 2002, 124, 9249.
33. (c) Cotton, F. A.; Daniels, L. M.; Liu, C. Y.; Murillo, C. A.; Schultz, A. J.; Wang, X. Inorg. Chem. 2002, 41, 4232.
34. (d) Cotton, F. A.; Huang, P.; Murillo, C. A.; Timmons, D. J. Inorg. Chem. Commun. 2002, 5, 501.
35. (e) Cotton, F. A.; Huang, P.; Murillo, C. A.; Wang, X. Inorg. Chem. Commun. 2003, 6, 121.
36. (f) Cotton, F. A.; Gruhn, N. E.; Gu, J.; Huang, P.; Lichtenberger, D. L. ; Murillo, C. A.; Van Dorn, L. O.; Wilkinson, C. C. Science 2002, 298, 1971.
37. Cotton, F. A.; Liu, C. Y.; Murillo, C. A.; Wang, X. Inorg. Chem. 2003, 42, 4619.
38. -.
39. Efforts are currently in progress to study the electronic spectra in the near-infrared region.
40. SMART. Data Collection Software. Version 5.618; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 2000.
41. SAINT. Data Reduction Software. Version 6.28A; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 2001.
42. Sheldrick, G. M. SHELXTL. Version 6.10; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 2000.
43. Using reaction conditions similar to those for the preparation of 5, we did not isolate a doubly oxidized Co analogue.
44. 9 for this compound implies it is delocalized. Thus, the data are consistent with those presented here. See: Cotton, F. A.; Liu, C. Y.; Murillo, C. A.; Wang, X. Chem. Commun. 2003, 2190.
45. (a) Hush, N. S. Prog. Inorg. Chem. 1967, 8, 391.
46. (b) Sutin, N. Prog. Inorg. Chem. 1983, 30, 441.
47. (c) Brunschwig, B. S.; Sutin, N. Coord. Chem. Rev. 1999, 187, 233.
48. Robin, M.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247.
49. Barrière, F.; Camire, N.; Geiger, W. E.; Mueller-Westerhoff, U. T.; Sanders, R. J. Am. Chem. Soc. 2002, 124, 7262.
50. Bunker. B. C.; Drago, R. S.; Hendrickson, D. N.; Richman, R. M.; Kessell, S. L. J. Am. Chem. Soc. 1978, 100, 3805.
51. Cotton, F. A.; Pedersen, E. Inorg. Chem. 1975, 14, 399.
52. Cotton, F. A.; Daniels, L. M.; Hillard, E. A.; Murillo, C. A. Inorg. Chem. 2002, 41, 1639.
53. ⊥ component can be measured at the top of the peak and has a value of ∼5.57, similar to that of the precursor 2.
54. 2+ unit.
55. See, for example: (a) Rast, S.; Borel, A.; Helm, L.; Belorizky, E.; Fries, P. H.; Merbach, A. E. J. Am. Chem. Soc. 2001, 123, 2637.
56. (b) Setifi, F.; Golhen, S.; Ouahab, L.; Miyazaki, A.; Okabe, K.; Enoki, T.; Toita, T.; Yamada, J. Inorg. Chem. 2002, 41, 3786.
57. Takeda, K.; Awaga, K. Phys. Rev. B 1997, 56, 14560.
58. Stebler, A.; Ammeter, J. H.; Fürholtz, U.; Ludi, A. Inorg. Chem. 1984, 23, 2764.
59. Cotton, F. A.; Liu, C. Y.; Murillo, C. A.; Villagrán, D.; Wang, X. J. Am. Chem. Soc. 2003, 125, in press.