Proof of large positive zero-field splitting in a Ru2 5+ paddlewheel

Journal of the American Chemical Society

Volumn 127, Issue 36, 2005, Pages 12691-12696

  Chen, Wei Zhong ^a   Cotton, F Albert ^b   Dalal, Naresh S ^c   Murillo, Carlos A ^b   Ramsey, Chris M ^c   Ren, Tong ^a   Wang, Xiaoping ^b  

^a Department of Biology   (United States)

^b TEXAS A AND M UNIVERSITY   (United States)

^c FLORIDA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANISOTROPY; GROUND STATE; MAGNETIC SUSCEPTIBILITY; MAGNETIZATION; PARAMAGNETIC RESONANCE; SINGLE CRYSTALS;

MAGNETIC CHARACTERIZATION; MAGNETOCRYSTALLINE ANISOTROPY; PADDLEWHEEL; ZEEMAN LEVELS;

RUTHENIUM COMPOUNDS;

RUTHENIUM COMPLEX;

ARTICLE; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; MAGNETIC FIELD; POWDER; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; RUTHENIUM;

EID: 24744442120     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja053615a     Document Type: Article

References (33)

1. Stephenson, T. A.; Wilkinson, G. J. Inorg. Nucl. Chem. 1966, 28, 2285.
2. Bennett, M. J.; Caulton, K. G.; Cotton, F. A. Inorg. Chem. 1969, 8, 1.
3. Cotton, F. A.; Pedersen, E. Inorg. Chem. 1975, 14, 388.
4. Telser, J.; Drago, R. S. Inorg. Chem. 1984, 23, 3114.
5. Norman, J. G., Jr.; Renzoni, G. E.; Case, D. A. J. Am. Chem. Soc. 1979, 101, 5256.
6. Clark, D. L.; Green, J. C.; Redfern, C. M.; Quelch, G. E.; Hillier, I. H.; Guest, M. F. Chem. Phys. Lett. 1989, 154, 326.
7. Cotton, F. A.; Miskowski, V. M.; Zhong, B. J. Am. Chem. Soc. 1989, 111, 6177.
8. Angaridis, P. In Multiple Bonds Between Metal Atoms, 3rd ed.; Cotton, F. A., Murillo, C. A., Walton, R. A., Eds.; Springer Science and Business Media, Inc.: New York, 2005.
9. Cotton, F. A.; Matusz, M. J. Am. Chem Soc. 1988, 110, 5761.
10. Cotton, F. A.; Murillo, C. A.; Reibenspies, J. H.; Villagrán, D.; Wang, X.; Wilkinson, C. C. Inorg. Chem. 2004, 43, 8373.
11. Angaridis, P.; Cotton, F. A.; Murillo, C. A.; Villagrán, D.; Wang, X. J. Am. Chem. Soc. 2005, 127, 5008.
12. Miyasaka, H.; Clérac, R.; Campos-Fernández, C. S.; Dunbar, K. R. Inorg. Chem. 2001, 40, 1663.
13. Angaridis, P.; Berry, J. F.; Cotton, F. A.; Murillo, C. A.; Wang, X. J. Am. Chem. Soc. 2003, 125, 10327.
14. Angaridis, P.; Berry, J. F.; Cotton, F. A.; Lei, P.; Lin, C.; Murillo, C. A.; Villagrán, D. Inorg. Chem. Commun. 2004, 7, 9.
15. (a) Cukiernik, F. D.; Luneau, D.; Marchon, J.-C.; Maldivi, P. Inorg. Chem. 1998, 37, 3698.
16. (b) Cayton, R. H.; Chisholm, M. H.; Darrington, F. D. Angew. Chem., Int. Ed. Engl. 1990, 29, 1481.
17. Angaridis, P.; Cotton, F. A.; Murillo, C. A.; Villagrán, D.; Wang, X. Inorg. Chem. 2004, 43, 8290.
18. Vos, T. E.; Liao, Y.; Shum, W. W.; Her, J.-H.; Stephens, P. W.; Reiff, W. M.; Miller, J. S. J. Am. Chem. Soc. 2004, 126, 11630.
19. Vos, T. E.; Miller, J. S. Angew. Chem., Int. Ed. 2005, 44, 2416.
20. See for example: (a) Jiménez-Aparicio, R.; Urbanos, F. A.; Arrieta, J. M. Inorg. Chem. 2001, 40, 613.
21. (b) Barral, M. C.; González-Prieto, R.; Jiménez-Aparicio, R.; Priego, M. R.; Torres, M. R.; Urbanos, F. A. Eur. J. Inorg. Chem. 2003, 2339.
22. (c) Barrai, M. C.; Jiménez-Aparicio, R.; Pérez-Quintanilla, D.; Priego, J. L.; Royer, E. C.; Torres, M. R.; Urbanos, F. A. Inorg. Chem. 2000, 39, 65.
23. Kahn, O. Molecular Magnetism; VCH: New York, 1993.
24. Lin, C. Ph.D. Dissertation. Florida Institute of Technology, 1997.
25. Sheldrick, G. M. SHELXTL V6. 12; Bruker AXS Inc.: Madison, WI, 2001.
26. Cotton, F. A.; Ren, T. Inorg. Chem. 1995, 34, 3190.
27. EPR spectral simulations were performed using Bruker's XSophe software package employing matrix diagonalization techniques.
28. Weltner, W., Jr. Magnetic Atoms and Molecules; Van Nostrand-Reinhold: New York, 1983.
29. Weil, J. A.; Bolton, J. R.; Wertz, J. E. Electron Paramagnetic Resonance: Elementary Theory and Practical Applications; John Wiley & Sons: New York, 1994.
30. Abragam, A.; Bleaney, B. Electron Paramagnetic Resonance of Transition Ions; Clarendon Press: Oxford, 1970.
31. Pilbrow, J. R. Transition Ion Electron Paramagnetic Resonance; Clarendon Press: Oxford, 1990.
32. Shum, W. W.; Liao, Y.; Miller, J. S. J. Phys. Chem. A 2004, 108, 7460.
33. Carlin, R. L. Magnetochemistry; Springer-Verlag: Berlin, 1986.