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Volumn 43, Issue 26, 2004, Pages 8373-8378

Paramagnetism at ambient temperature, diamagnetism at low temperature in a Ru26+ core: Structural evidence for zero-field splitting

Author keywords

[No Author keywords available]

Indexed keywords

GUANIDINE DERIVATIVE; LIGAND; RUTHENIUM;

EID: 11144260354     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic048946n     Document Type: Article
Times cited : (34)

References (53)
  • 9
    • 23744465061 scopus 로고    scopus 로고
    • Cotton, F. A., Walton, R. A., Murillo, C. A., Eds.; Springler Verlag: New York, in press
    • Angaridis, P. In Multiple Bonds between Metal Atoms, 3rd ed.; Cotton, F. A., Walton, R. A., Murillo, C. A., Eds.; Springler Verlag: New York, in press.
    • Multiple Bonds between Metal Atoms, 3rd Ed.
    • Angaridis, P.1
  • 26
    • 11144250561 scopus 로고    scopus 로고
    • note
    • Use of a second crystal of 2 was necessary because some decomposition was observed at room temperature while collecting data on the crystal used for the low temperature data collections.
  • 31
    • 11144345253 scopus 로고    scopus 로고
    • note
    • s values of ±1/2 and ±3/2.
  • 37
    • 3042646959 scopus 로고    scopus 로고
    • For a recent review, with 266 references, referring to zero-field splitting in metal complexes, see: Boča, R. Coord. Chem. Rev. 2004, 248, 757.
    • (2004) Coord. Chem. Rev. , vol.248 , pp. 757
    • Boča, R.1
  • 45
    • 0037036809 scopus 로고    scopus 로고
    • Changes in metal-metal distances of about 0.03-0.05 Å are commonly observed by removal of electrons from δ or δ* orbitals, whereas a larger increase, 0.05-0.08 Å, would be expected by populating π* orbitals. See for example: Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Timmons, D. J.; Wilkinson, C. C. J. Am. Chem. Soc. 2002, 124, 9249.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 9249
    • Cotton, F.A.1    Daniels, L.M.2    Murillo, C.A.3    Timmons, D.J.4    Wilkinson, C.C.5
  • 50
    • 11144349362 scopus 로고    scopus 로고
    • note
    • This values are similar to those reported earlier. See ref 13b.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.