Mechanism of oxidations with H2O2 catalyzed by vanadate anion or oxovanadium(V) triethanolaminate (vanadatrane) in combination with pyrazine-2-carboxylic acid (PCA): Kinetic and DFT studies

Journal of Catalysis

Volumn 267, Issue 2, 2009, Pages 140-157

  Kirillova, Marina V ^a   Kuznetsov, Maxim L ^a   Romakh, Vladimir B ^b   Shul'pina, Lidia S ^c   Fraústo da Silva, João J R ^a   Pombeiro, Armando J L ^a   Shul'pin, Georgiy B ^d  

^a INSTITUTO SUPERIOR TÉCNICO   (Portugal)

^b UNIVERSITY OF WESTERN ONTARIO   (Canada)

^c A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^d SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

Author keywords

Alkane oxidation; Cyclohexane; Homogeneous catalysis; Hydrogen peroxide; Hydroxyl radical; Vanadium complexes

Indexed keywords

ALKANE OXIDATION; C-H BOND; CATALYTIC CYCLES; CATALYTIC SYSTEM; CYCLOHEXYL; DFT METHOD; DFT STUDY; FREE RADICAL GENERATION; HOMOGENEOUS CATALYSIS; HYDROPEROXIDES; HYDROXYL RADICAL; INTERMEDIATE SPECIE; ISO-PROPANOLS; LOW TEMPERATURES; MECHANISM OF OXIDATION; NMR DATA; O-H BOND; OXOVANADIUM; PYRAZINE-2-CARBOXYLIC ACID; RATE LIMITING; REACTION MECHANISM; SPECTROSCOPIC STUDIES; TRANSITION STATE; VANADIUM COMPLEXES;

ACETONE; CARBOXYLIC ACIDS; CATALYSIS; CYCLOHEXANE; DYES; FREE RADICALS; HYDROGEN; HYDROGEN PEROXIDE; LIGANDS; ORGANIC ACIDS; OXIDATION; PARAFFINS; PROBABILITY DENSITY FUNCTION; REACTION KINETICS; SPECTROSCOPIC ANALYSIS; VANADIUM ALLOYS;

VANADIUM COMPOUNDS;

EID: 70349629075     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2009.08.006     Document Type: Article

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