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Volumn 4, Issue 4, 2000, Pages 270-274

Vanadium-catalysed oxidative bromination using dilute mineral acids and hydrogen peroxide: An option for recycling waste acid streams

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EID: 0034392702     PISSN: 10836160     EISSN: None     Source Type: Journal    
DOI: 10.1021/op000020l     Document Type: Article
Times cited : (77)

References (38)
  • 3
    • 0012848581 scopus 로고    scopus 로고
    • Applications of hydrogen peroxide and derivatives
    • Clark, J. H., Ed.; Royal Society of Chemistry: Cambridge
    • (c) For a recent monograph see Jones, C. W. Applications of Hydrogen Peroxide and Derivatives; In RSC Clean Technology Monographs; Clark, J. H., Ed.; Royal Society of Chemistry: Cambridge, 1999; pp 59-61.
    • (1999) RSC Clean Technology Monographs , pp. 59-61
    • Jones, C.W.1
  • 13
    • 0032739635 scopus 로고    scopus 로고
    • (c) Martinez-Perez, J. A.; Pickel, M. A.; Caroff, E.; Woggon, W.-D. Synlett 1999, 1875-1878. However, implementation of enzymatic processes has serious drawbacks, not least because such reactions are carried out in very dilute solutions, and thus require enormous reaction tanks, meaning high capital costs in a market where the current technology is well-established and retains size advantage. Several VBPO mimics have been reported, but it is unlikely that in the near future they would lead to an enzymatic oxybromination process, which would have to compete on a very narrow profit margin.
    • (1999) Synlett , pp. 1875-1878
    • Martinez-Perez, J.A.1    Pickel, M.A.2    Caroff, E.3    Woggon, W.-D.4
  • 14
    • 1842298685 scopus 로고    scopus 로고
    • (a) Jerzy. G.; Slawomir, Z. Synth. Commun. 1997, 27, 3291-3299. Generally, for oxychlorination a large excess of HCl is required, see:
    • (1997) Synth. Commun. , vol.27 , pp. 3291-3299
    • Jerzy, G.1    Slawomir, Z.2
  • 17
    • 0027114576 scopus 로고
    • For a discussion, see Sheldon, R. A. Chem. Ind. 1992, 903-906; CHEMTECH 1994, 38-47.
    • (1992) Chem. Ind. , pp. 903-906
    • Sheldon, R.A.1
  • 18
    • 0003433102 scopus 로고
    • For a discussion, see Sheldon, R. A. Chem. Ind. 1992, 903-906; CHEMTECH 1994, 38-47.
    • (1994) CHEMTECH , pp. 38-47
  • 19
    • 0001127051 scopus 로고
    • Bhattacharjee, M. Polyhedron 1992, 11, 2817-2818. See also ref 6b, and Bhattacharjee, M.; Chaudhuri, M. K.; Islam, N. S.; Paul, P. C. Inorg. Chim. Acta 1990, 169, 97-100.
    • (1992) Polyhedron , vol.11 , pp. 2817-2818
    • Bhattacharjee, M.1
  • 22
    • 0003601534 scopus 로고
    • Merck & Co., Inc.: Rahway
    • 2] at 25 °C, The Merck Index; Merck & Co., Inc.: Rahway, 1989; pp 323; 211.
    • (1989) The Merck Index , pp. 323
  • 24
    • 85037761571 scopus 로고    scopus 로고
    • 2
    • 2.
  • 26
    • 0040334387 scopus 로고
    • However, in all cases (even when using KBr/AcOH in the absence of catalyst), enough bromine was generated to cause coloration of the samples. cf. Maass, O.; Hiebert, P. G. J. Am. Chem. Soc. 1924, 46, 290-308.
    • (1924) J. Am. Chem. Soc. , vol.46 , pp. 290-308
    • Maass, O.1    Hiebert, P.G.2
  • 27
    • 85037765843 scopus 로고    scopus 로고
    • The slow reaction observed with perchloric acid is probably a result of its low solubility in the reaction medium. Significant amounts of solid perchlorates were observed even when the amount of water was doubled
    • The slow reaction observed with perchloric acid is probably a result of its low solubility in the reaction medium. Significant amounts of solid perchlorates were observed even when the amount of water was doubled.
  • 28
    • 85037749972 scopus 로고    scopus 로고
    • 4, and HBr would all dissociate completely under the aqueous conditions employed. Thus, the differences shown in Figure 1 may reflect possible participation of the inorganic anions in the catalytic decomposition process
    • 4, and HBr would all dissociate completely under the aqueous conditions employed. Thus, the differences shown in Figure 1 may reflect possible participation of the inorganic anions in the catalytic decomposition process.
  • 34
  • 35
    • 0001925594 scopus 로고    scopus 로고
    • Sheldon, R. A. Chem. Ind. 1997, 12-15; J. Chem. Technol. Biotechnol. 1997, 68, 3181-388.
    • (1997) Chem. Ind. , pp. 12-15
    • Sheldon, R.A.1
  • 36
    • 0040334389 scopus 로고    scopus 로고
    • Sheldon, R. A. Chem. Ind. 1997, 12-15; J. Chem. Technol. Biotechnol. 1997, 68, 3181-388.
    • (1997) J. Chem. Technol. Biotechnol. , vol.68 , pp. 3181-3388


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