Polyoxovanadometalate-catalyzed selective epoxidation of alkenes with hydrogen peroxide

Angewandte Chemie - International Edition

Volumn 44, Issue 32, 2005, Pages 5136-5141

  Nakagawa, Yoshinao ^a   Kamata, Keigo ^b   Kotani, Miyuki ^b   Yamaguchi, Kazuya ^a,b   Mizuno, Noritaka ^a,b  

^a UNIVERSITY OF TOKYO   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

Alkenes; Epoxidation; Hydrogen peroxide; Polyoxometalates; Vanadium

Indexed keywords

CATALYSIS; CATALYST SELECTIVITY; CATALYSTS; HYDROGEN PEROXIDE; OXIDATION; VANADIUM;

DIASTEREOSELECTIVITY; EPOXIDATION; POLYOXOMETALATES; REGIOSELECTIVITY;

OLEFINS;

ALKENE; EPOXIDE; HYDROGEN PEROXIDE; ORGANOMETALLIC COMPOUND; VANADIUM;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION REDUCTION REACTION; SYNTHESIS;

ALKENES; CATALYSIS; EPOXY COMPOUNDS; HYDROGEN PEROXIDE; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; VANADIUM;

EID: 23944434404     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200500491     Document Type: Article

References (40)

1. T. Hirao, Coord. Chem. Rev. 2003, 237, 1.
2. T. Hirao, Chem. Rev. 1997, 97, 2707.
3. A. E. Shilov, G. B. Shul'pin, Chem. Rev. 1997, 97, 2879.
4. Thematic issue on vanadium-based catalysts for the selective oxidation of hydrocarbons and their derivatives: Appl. Catal. A 1997, 157, 1-425.
5. H. Sigel, A. Sigel, Vanadium and Its Role in Life, Marcel Dekker, New York, 1995.
6. F. Jiang, O. P. Anderson, S. M. Miller, J. Chen, M. Mahroof-Tahir, D. C. Crans, Inorg. Chem. 1998, 37, 5439.
7. A. Butler, M. J. Clague, G. E. Meister, Chem. Rev. 1994, 94, 625.
8. A. G. J. Ligtenbarg, R. Hage, B. L. Feringa, Coord. Chem. Rev. 2003, 237, 89.
9. U. Schuchardt, M. C. Guerreiro, G. B. Shul'pin, Russ. Chem. Bull. 1998, 107, 247.
10. O. Bortolini, F. Di Furia, P. Scrimin, G. Modena, J. Mol. Catal. 1980, 7, 59.
11. E. J. Eisenbraun, A. R. Bader, J. W. Polacheck, E. Reif, J. Org. Chem. 1963, 28, 2057.
12. R. Neumann, M. Levin-Elad, Appl. Catal. A 1995, 122, 85.
13. D. Wei, W. Chuei, G. L. Haller, Catal. Today 1999, 51, 501.
14. G. Bellussi, M. S. Rigutto, Stud. Surf. Sci. Catal. 1994, 85, 177.
15. A. M. Khenkin, L. Weiner, Y. Wang, R. Neumann, J. Am. Chem. Soc. 2001, 123, 8531.
16. R. D. Gall, M. Faraj, C. L. Hill, Inorg. Chem. 1994, 33, 5015.
17. B. S. Lane, K. Burgess, Chem. Rev. 2003, 103, 2457.
18. G. Grigoropoulou, J. H. Clark, J. A. Elings, Green Chem. 2003, 5, 1.
19. R. Noyori, M. Aoki, K. Sato, Chem. Commun. 2003, 1977.
20. I. W. C. E. Arenas, R. A. Sheldon, Top. Catal. 2002, 19, 133.
21. M. T. Pope in Comprehensive Coordination Chemistry II, Vol. 4 (Eds.: J. A. McCleverty, T. J. Meyer), Elsevier, Amsterdam, 2003, p. 635-678.
22. C. L. Hill in Comprehensive Coordination Chemistry II, Vol. 4 (Eds.: J. A. McCleverty, T. J. Meyer), Elsevier, Amsterdam, 2003, p. 679-759.
23. I. V. Kozhevnikov, Catalysis by Polyoxometalates, Wiley, Chichester, UK, 2002.
24. I. V. Kozhevnikov, Chem. Rev. 1998, 98, 171.
25. N. Mizuno, M. Misono, Chem. Rev. 1998, 98, 199.
26. R. Neumann, Prog. Inorg. Chem. 1998, 47, 317.
27. T. Okuhara, N. Mizuno, M. Misono, Adv. Catal. 1996, 41, 113.
28. C. L. Hill, C. M. Prosser-McCartha, Coord. Chem. Rev. 1995, 143, 407.
29. See Table S10 in the Supporting Information.
30. K. Kamata, Y. Nakagawa, K. Yamaguchi, N. Mizuno, J. Catal. 2004, 224, 224.
31. K. Kamata, K. Yonehara, Y. Sumida, K. Yamaguchi, S. Hikichi, N. Mizuno, Science 2003, 300, 964.
32. Y. Nakagawa, K. Uehara, N. Mizuno, Inorg. Chem. 2005, 44, 14.
33. 183W NMR spectra should show five lines (intensity ratio 1:1:1:1:1), five lines (1:1:1:1:1), ten lines (1:1:1:1:1:1:1:1:1:1), and three lines (2:2:1), respectively.
34. V. Nardello, J. Marko, G. Vermeersch, J. M. Aubry, Inorg. Chem. 1995, 34, 4950.
35. M. Akita, S. Hikichi, Bull. Chem. Soc. Jpn. 2002, 75, 1657.
36. J. Canny, R. Thouvenot, A. Tézé, G. Hervé, M. Leparulo-Loftus, M. T. Pope, Inorg. Chem. 1991, 30, 976.
37. A. Tézé, G. Hervé, Inorg. Synth. 1990, 27, 85.
38. A. Tézé, J. Canny, L. Gurdan, R. Thouvenot, G. Hervé, Inorg. Chem. 1996, 25, 1001.
39. N. Mizuno, C. Nozaki, I. Kiyoto, M. Misono, J. Am. Chem. Soc. 1998, 120, 9267.
40. A. I. Vogel, A Textbook of Quantitative Inorganic Analysis Including Elementary Instrumental Analysis, Longman, New York, 1978.