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The absolute configurations of the chlorinated oxo esters 9b,df and the brominated products 15b and 15f were determined to be (JR) by comparison of the values of the optical, rotations with those reported in the literature. The absolute configurations of the fluorinated products 16d and 16e were determined to be (S) by comparison with literature data. The absolute configurations of other halogenated products were assigned by analogy.
-
The absolute configurations of the chlorinated oxo esters 9b,df and the brominated products 15b and 15f were determined to be (JR) by comparison of the values of the optical, rotations with those reported in the literature. The absolute configurations of the fluorinated products 16d and 16e were determined to be (S) by comparison with literature data. The absolute configurations of other halogenated products were assigned by analogy.
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