Catalytic enantioselective fluorination of α-cyano acetates catalyzed by chiral palladium complexes

Tetrahedron Letters

Volumn 46, Issue 17, 2005, Pages 3115-3117

  Kim, Hye Ran ^a   Kim, Dae Young ^a  

^a Soonchunhyang University   (South Korea)

Author keywords

Asymmetric reactions; Chiral palladium complexes; Fluorination

Indexed keywords

ACETIC ACID DERIVATIVE; BENZENE DERIVATIVE; FLUORENE; PALLADIUM COMPLEX;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHIRALITY; ENANTIOSELECTIVITY; FLUORINATION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY;

EID: 15944374329     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.02.164     Document Type: Article

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27. 4, filtered, concentrated, and purified by flash chromatography (silica gel, ethyl acetate-hexane = 1:15) to afford the α-cyano α-fluoro acetate
28. No reaction was observed in MeOH using N-fluoropyridinium triflate