Diphenylphosphanylsulfoximines as ligands in iridium-catalyzed asymmetric imine hydrogenations

Angewandte Chemie - International Edition

Volumn 44, Issue 46, 2005, Pages 7564-7567

  Moessner, Christian ^a   Bolm, Carsten ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Amines; Asymmetric catalysis; Hydrogenation; Imines; Sulfoximines

Indexed keywords

CATALYSIS; HYDROGENATION; MOLECULAR STRUCTURE; REACTION KINETICS;

ASYMMETRICAL CATALYSIS; IMINES; SULFOXIMINES;

AMINES;

IMINE; IRIDIUM; LIGAND; ORGANOMETALLIC COMPOUND;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; HYDROGENATION; STEREOISOMERISM; SYNTHESIS;

CATALYSIS; HYDROGENATION; IMINES; IRIDIUM; LIGANDS; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM;

EID: 28244467432     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200502482     Document Type: Article

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58. 2 pressure for full conversion after 4 h to obtain 8a with 95 % ee.
59. For details, see the Supporting Information.