C-H bonds as ubiquitous functionality: A general approach to complex arylated pyrazoles via sequential regioselective C-arylation and N-alkylation enabled by SEM-group transposition

Journal of the American Chemical Society

Volumn 131, Issue 8, 2009, Pages 3042-3048

  Goikhman, Roman ^a   Jacques, Teresa L ^a   Sames, Dalibor ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ARENE RINGS; ARYLATIONS; C-H BOND; CATALYTIC SYSTEM; GENERAL APPROACH; HETEROARENES; N-ALKYLATION; NEW APPROACHES; ONE STEP; PROTECTING GROUP; PROTEIN LIGANDS; PYRAZOLES; REGIO-SELECTIVE; REGIOCONTROL; SEM; SUZUKI COUPLINGS; SYNTHETIC METHODS;

ALKYLATION; AMINES; AROMATIC COMPOUNDS; COMPLEXATION; HYDROCARBONS; PALLADIUM;

SYNTHESIS (CHEMICAL);

AMINE; CARBON; HYDROGEN; NITROGEN; PALLADIUM; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; PYRAZOLE DERIVATIVE; BENZENE DERIVATIVE;

ALKYLATION; ARTICLE; ARYLATION; BROMINATION; CATALYSIS; CHEMICAL BOND; COMPLEX FORMATION; DEPROTECTION REACTION; SCANNING ELECTRON MICROSCOPY; SUZUKI REACTION; SYNTHESIS; CHEMISTRY; ISOMERISM;

ALKYLATION; BENZENE DERIVATIVES; ISOMERISM; PYRAZOLES;

EID: 67749101415     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8096114     Document Type: Article

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