Intramolecular hydroalkoxylation/cyclization of alkynyl alcohols mediated by lanthanide catalysts. Scope and reaction mechanism

Journal of the American Chemical Society

Volumn 131, Issue 1, 2009, Pages 263-276

  Seo, Sungyong ^a   Yu, Xianghua ^a   Marks, Tobin J ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNYL; CONVENTIONAL TRANSITIONS; ENOL ETHERS; FIRST-ORDER; FUNCTIONALIZED SUBSTRATES; KINETIC ISOTOPE EFFECTS; LANTHANIDE; MECHANISTIC DATA; ORGANIC COMPLEX; PRECATALYSTS; PROTONOLYSIS; RATE LAWS; REACTION MECHANISM; REGIO-SELECTIVE; TRANSITION STATE; TURNOVER FREQUENCY;

CATALYSIS; CYCLIZATION; ETHERS; ISOTOPES; LUTETIUM; ORGANIC COMPOUNDS; TRANSITION METALS;

CATALYSTS;

ALCOHOL; ALKYNYL GROUP; EXOCYCLIC DOUBLE BOND; LANTHANIDE; LANTHANIDE[N(SIME3)2]3; UNCLASSIFIED DRUG; ALCOHOL DERIVATIVE; ALKENE; ALKYNE; ETHER DERIVATIVE; ORGANOMETALLIC COMPOUND;

ARTICLE; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CYCLIZATION; ISOTOPE ANALYSIS; REACTION ANALYSIS; STEREOCHEMISTRY; ALKYLATION; CATALYSIS; CHEMISTRY; KINETICS; OXIDATION REDUCTION REACTION; STEREOISOMERISM; SYNTHESIS; THERMODYNAMICS;

ALCOHOLS; ALKENES; ALKYLATION; ALKYNES; CATALYSIS; CYCLIZATION; ETHERS, CYCLIC; KINETICS; LANTHANOID SERIES ELEMENTS; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; STEREOISOMERISM; THERMODYNAMICS;

EID: 62649160608     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8072462     Document Type: Article

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