Homoleptic lanthanide alkyl and amide precatalysts efficiently mediate intramolecular hydrophosphination/cyclization. Observations on scope and mechanism

Organometallics

Volumn 22, Issue 23, 2003, Pages 4630-4632

  Kawaoka, Amber M ^a   Douglass, Michael R ^a   Marks, Tobin J ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLIZATION; INTRAMOLECULAR HYDROPHOSPHINATION; LANTHANOCENES; PHOSPHINOALKENES; PHOSPHINOALKYNES;

ACIDITY; BENZENE; CATALYSIS; CATALYSTS; CHEMICAL BONDS; COMPLEXATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

ORGANOMETALLICS;

EID: 0344584865     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030439a     Document Type: Article

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47. 8
48. 3. the diastereomeric product mixture was heated at 60 °C for 3 days in both the presence and absence of catalyst. There was no discernible change in the ratio of product diastereomers.