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0000633011
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For a related endo-selective hydrative cyclization, see: Chen, Y.; Ho, D. M.; Lee, C. J. Am. Chem. Soc. 2005, 127, 12184.
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For a pioneering example of the synthesis of a rhodium vinylidene complex, see: (b) Wolf, J.; Werner, H.; Serhadli, O.; Ziegler, M. L. Angew. Chem., Int. Ed. Engl. 1983, 22, 414.
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16
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33845452077
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note
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No reaction occurred at 23 °C, while extensive decomposition of enyne 1 was observed at 60 °C.
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17
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4544236676
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For a review, see
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For a review, see: Glorius, F. Angew. Chem., Int. Ed. 2004, 43, 3364.
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(a) Hayashi, T.; Inoue, K.; Taniguchi, N.; Ogasawara, M. J. Am. Chem. Soc. 2001, 123, 9918.
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22
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33845449273
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note
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(9) The 2-phenyl-1,3-dioxa-2-borinane was chosen instead of phenylboronic acid to avoid proton scrambling.
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23
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33845436938
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note
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The isotopic composition remained constant upon resubjection of 8′ to the same reaction conditions for 2 h. In a separate control experiment employing unlabeled 8, no deuterium incorporation was observed.
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26
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0037042235
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Hayashi, T.; Takahashi, M.; Takaya, Y.; Ogasawara, M. J. Am. Chem. Soc. 2002, 124, 5052.
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