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Volumn 48, Issue 36, 2007, Pages 6339-6342

Novel biomimetic iron-catalysts for environmentally benign epoxidations of olefins

Author keywords

Epoxidation; Hydrogen peroxide; Imidazole; Iron

Indexed keywords

ALKENE; HYDROGEN PEROXIDE; IMIDAZOLE DERIVATIVE; IRON;

EID: 34547657722     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.07.006     Document Type: Article
Times cited : (50)

References (58)
  • 1
    • 84891568337 scopus 로고    scopus 로고
    • For a list of common oxidants, their active oxygen contents and waste products, see:, Wiley-VCH, Weinheim p 22
    • For a list of common oxidants, their active oxygen contents and waste products, see:. Bäckvall J.-E. Modern Oxidation Methods (2004), Wiley-VCH, Weinheim p 22
    • (2004) Modern Oxidation Methods
    • Bäckvall, J.-E.1
  • 3
    • 33750437751 scopus 로고    scopus 로고
    • For recent examples of transition metal catalyzed epoxidations using hydrogen peroxide see:
    • For recent examples of transition metal catalyzed epoxidations using hydrogen peroxide see:. Colladon M., Scarso A., Sgarbossa P., Michelin R.A., and Strukul G. J. Am. Chem. Soc. 128 (2006) 14006-14007
    • (2006) J. Am. Chem. Soc. , vol.128 , pp. 14006-14007
    • Colladon, M.1    Scarso, A.2    Sgarbossa, P.3    Michelin, R.A.4    Strukul, G.5
  • 12
  • 52
    • 0036717847 scopus 로고    scopus 로고
    • A few defined complexes of iron and simple imidazole derivatives are known in coordination chemistry. See:
    • A few defined complexes of iron and simple imidazole derivatives are known in coordination chemistry. See:. Cotton S.A., Franckevicius V., and Fawcett F. Polyhedron 21 (2002) 2055-2061
    • (2002) Polyhedron , vol.21 , pp. 2055-2061
    • Cotton, S.A.1    Franckevicius, V.2    Fawcett, F.3
  • 56
    • 34547655485 scopus 로고    scopus 로고
    • note
    • 2 (30%) from Merck was used as received. The peroxide content varied from 33% to 40% as determined by titration.
  • 57
    • 34547683224 scopus 로고    scopus 로고
    • note
    • Side-products are rearrangement products of the corresponding epoxide.
  • 58
    • 34547657257 scopus 로고    scopus 로고
    • note
    • Most of the substrates and epoxides for GC-FID calibration are commercially available. The others were synthesized according to literature methods and determined by NMR and GC-MS. In addition, authentic samples of the commercial products were analyzed by GC-MS and GC-FID.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.