Oxidative reactivity difference among the metal oxo and metal hydroxo moieties: pH dependent hydrogen abstraction by a manganese(IV) complex having two hydroxide ligands

Journal of the American Chemical Society

Volumn 130, Issue 48, 2008, Pages 16245-16253

  Yin, Guochuan ^a   Danby, Andrew M ^a   Kitko, David ^b   Carter, John D ^b   Scheper, William M ^b   Busch, Daryle H ^a  

^a UNIVERSITY OF KANSAS   (United States)

^b PROCTER AND GAMBLE COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSTRACTING; CATALYSTS; CHEMICAL OXYGEN DEMAND; CLARIFICATION; ENZYMES; FUNCTIONAL GROUPS; HYDROGEN; LIGANDS; MANGANESE; METAL IONS; METALS; METHANE; NONMETALS; OXIDATION; PROTEINS; RATE CONSTANTS; REDOX REACTIONS; STRUCTURAL METALS;

ACTIVATION PARAMETERS; DETECTABLE REACTIONS; DIHYDROANTHRACENE; DIPHENYL METHANES; DOMINANT SPECIES; ELECTRON TRANSFERS; EXPERIMENTAL TESTS; H BONDS; HYDROGEN ABSTRACTIONS; HYDROXIDE LIGANDS; IDENTICAL STRUCTURES; KINETIC MEASUREMENTS; OXIDATION CATALYSTS; OXIDATION STATES; OXIDATIVE REACTIVITIES; OXIDIZING POWERS; PH DEPENDENTS; REASONABLE RATES; REDOX ACTIVE METAL IONS; REDOX ENZYMES; REDOX REACTIVITIES; REDUCTION PRODUCTS; TEMPERATURE RANGES;

MANGANESE COMPOUNDS;

HYDROGEN; HYDROXIDE; LIGAND; MANGANESE DERIVATIVE; METAL DERIVATIVE; METHANE;

ARTICLE; CATALYST; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; DISSOCIATION; ELECTRON TRANSPORT; MEASUREMENT; OXIDATION; OXIDATION REDUCTION REACTION; PH; REDUCTION; SYNTHESIS; TEMPERATURE; THERMODYNAMICS;

EID: 57149083074     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja804305x     Document Type: Article

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