Raman evidence for a weakened O - O bond in mononuclear low-spin iron(III)-hydroperoxides [10]

Journal of the American Chemical Society

Volumn 121, Issue 1, 1999, Pages 264-265

  Ho, Raymond Y N ^a   Roelfes, Gerard ^b   Feringa, Ben L ^b   Que Jr , Lawrence ^a  

^a University of Minnesota   (United States)

^b UNIVERSITY OF GRONINGEN   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYST; CHEMICAL BOND; LETTER; MOLECULAR INTERACTION; RAMAN SPECTROMETRY; STRUCTURE ANALYSIS;

EID: 0033550504     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982812p     Document Type: Letter

References (34)

1. Que, L., Jr.; Ho, R. Y. N. Chem. Rev. 1996, 96, 2607-2624.
2. Sono, M.; Roach, M. P.; Coulter, E. D.; Dawson, J. H. Chem. Rev. 1996, 96, 2841-2887.
3. (a) Hecht, S. M. Acc. Chem. Res. 1986, 19, 383-391.
4. (b) Guajardo, R. J.; Hudson, S. E.; Brown, S. J.; Mascharak, P. K. J. Am. Chem. Soc. 1993, 115, 7971-7977.
5. (c) Nam, W.; Ho, R.; Valentine, J. S. J. Am. Chem. Soc. 1991, 113, 7052-7054.
6. Kim, C.; Chen, K.; Kim, J.; Que, L. Jr. J. Am. Chem. Soc. 1997, 119, 5964-5965.
7. Lubben, M.; Meetsma, A.: Wilkinson, E. C.; Feringa, B.; Que, L., Jr. Angew. Chem., Int. Ed. Engl. 1995, 34, 1512-1514.
8. Abbreviations used: BLM = bleomycin, DFT = density functional theory, EDTA = ethylenediaminetetraacetic acid, N4Py = N-(bis(2-pyridyl)-methyl)-N,N-bis(2-pyridylmethyl)amine, OEP = 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine, Py5 = 2,6-bis-(bis(2-pyridyl)methoxymelhane)pyridine, T(2-N-Me)PyP = tetrakis(2-N-methylpyridiniumyl)-porphinato, TPA = tris-(2-pyridylmethyl)amine.
9. de Vries, M. E.; La Crois, R. M.; Roelfes, G.; Kooijman, H.; Spek, A. L.; Hage, R.; Feringa, B. L. J. Chem. Soc., Chem. Commun. 1997, 1549-1550.
10. Sam, J. W.; Tang, X.-J.; Peisach, J. J. Am. Chem. Soc. 1994, 116, 6, 5250-5256.
11. Stubbe, J.; Kozarich, J. W. Chem. Rev. 1987, 87, 1107-1136.
12. Kane, S. A.; Hecht, S. M. Prog. Nucleic Acid Res. Mol. Biol. 1994, 49, 313-352.
13. Cytochrome P-450. Structure, Mechanism and Biochemistry; Ortiz de Montellano, P. R., Ed.; Plenum Press: New York, 1986.
14. 3CN.
15. -1 downshifts observed are within the uncertainty of our instrument.
16. McCandlish, E.: Miksztal, A. R.; Nappa, M.; Sprenger, A. Q.; Valentine, J. S.; Stong, J. D.; Spiro, T. G. J. Am. Chem. Soc. 1980, 102, 4268-4271.
17. Ahmad, S.; McCallum, J. D.; Shiemke, A. K.; Appelman, E. H.; Loehr, T. M.; Sanders-Loehr, J. Inorg. Chem. 1988, 27, 2230-2233.
18. Kurtz, D. M., Jr.; Shriver, D. F.; Klotz, I. M. J. Am. Chem. Soc. 1976, 98, 5033.
19. Shiemke, A. K.; Loehr, T. M.; Sanders-Loehr, J. J. Am. Chem. Soc. 1984, 106, 4951-4956.
20. (a) Murch, B. P.; Bradley, F. C.; Que, L., Jr. J. Am. Chem. Soc. 1986, 108, 5027-5028;
21. (b) Kitajima, N.; Fukui, H.; Moro-oka, Y.; Mizutani, Y.; Kitagawa, T. J. Am. Chem. Soc. 1990, 112, 6402-6403.
22. (c) Brennan, B. A.; Chen. Q.; Juarez-Garcia, C.; True, A. E.; O'Connor, C. J.; Que, L., Jr. Inorg. Chem. 1991, 30, 1937-1943.
23. (d) Kitajima, N.; Tamura, N.; Tanaka, M.; Morooka, Y. Inorg. Chem. 1992, 31, 3342-3343.
24. (e) Dong, Y.; Ménage, S.; Brennan, B. A.; Elgren, T. E.; Jang, H. G.; Pearce, L. L.; Que, L., Jr. J. Am. Chem. Soc. 1993, 115, 1851-1859.
25. (f) Kim, K.; Lippard, S. J. J. Am. Chem. Soc. 1996, 118, 4914-4915.
26. (g) Dong, Y.; Zang, Y.; Kauffmann, K.; Shu, L.; Wilkinson, E. C.; Münck, E.; Que, L., Jr. J. Am. Chem. Soc. 1997, 119, 12683-12684.
27. Zang, Y.; Kim, J.; Dong, Y.; Wilkinson, E. C.; Appelman, E. H.; Que, L., Jr. J. Am. Chem. Soc. 1997, 119, 4197-4205.
28. Roelfes, G.; Chen, K.; Que, L., Jr.; Feringa, B. L., unpublished results.
29. Jonas, R. T.; Stack, T. D. P. J. Am. Chem. Soc. 1997, 119, 8566-8567.
30. Holmes, M. A.; Le Trong, I.; Turley, S.; Sieker, L. C.; Stenkamp, R. E. J. Mol. Biol. 1991, 218, 583-593.
31. (a) Le Carpentier, J. M.; Mitschler, A.; Weiss, R. Acta Crystallogr., Sect. B 1972, 1288-1298.
32. (b) Carmona, D.; Lamata, M. P.; Ferrer, J.; Modrego, J.; Perales, M.; Lahoz, F. J.; Atencio, R.; Oro, L. A. J. Chem. Soc., Chem Commun. 1994, 575-576.
33. (c) Wada, A.; Harata, M.; Hasegawa, K.; Jitsukawa, K.; Masuda, H.; Mukai, M.; Kitagawa, T.; Einaga, H. Angew. Chem., Int. Ed. 1998, 37, 798-799.
34. Harris, D. L.; Loew, G. H. J. Am. Chem. Soc. 1998, 120, 8941-8948.