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Volumn 21, Issue 1-3, 2002, Pages 79-88

Fundamental principles of selective heterogeneous oxidation catalysis

Author keywords

Acrolein; Acrylonitrile; Ammoxidation; Antimonates; Host structure; Lattice oxygen; Metal oxygen bond; Molybdates; Multifunctionality; Oxidation; Phase cooperation; Redox; Site isolation

Indexed keywords


EID: 0037515579     PISSN: 10225528     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1020556131984     Document Type: Article
Times cited : (425)

References (56)
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    • (1998) Oral presentations: IPCAT 1
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    • R.K. Grasseili, Oral presentations: IPCAT 1, Cape Town, South Africa (1998); 4th Eur. Congr. on Catalysis, Rimini, Italy (1999); Morley Award Address, Cleveland, OH (1999); Irsee Symposium, Germany (1999).
    • (1999) 4th Eur. Congr. on Catalysis
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    • (1999)
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    • R.K. Grasseili, Oral presentations: IPCAT 1, Cape Town, South Africa (1998); 4th Eur. Congr. on Catalysis, Rimini, Italy (1999); Morley Award Address, Cleveland, OH (1999); Irsee Symposium, Germany (1999).
    • (1999) Irsee Symposium
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    • 2 system, in 1955 the first useful propylene oxidation catalyst was developed. The system works either in a cyclic oxidant process mode but also as a genuine redox catalyst. The first attempt to use it in a cyclic oxidant mode was abandoned after pilot planting it, because about 200 kg of the solid catalyst had to be circulated to produce 1 kg of acrolein. The expense was too high. Fortunately, the same system operates successfully as a redox catalyst and was first commercialized for the production of acrolein from propylene in 1957 (Degussa licensee), and subsequently commercialized internally in 1959 for the production of acrylonitrile from propylene in 1959 (licensed world wide).
    • Grasselli, R.K.1
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    • R.K. Grasselli and H.F. Hardman, US Patent 3 642 930 (1972); 4 503 001 (1985).
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    • R.K. Grasselli, Featured Lecture, 4th World Congress on Oxidation Catalysis, Berlin, 18 September 2001; R.K. Grasselli, J.D. Burrington, D.J. Buttrey, P. DeSanto, C.G. Lugmair, A.F. Volpe, Jr., and T. Weingand, Topics in Catalysis, in press; P. De Santo, D.J. Buttrey, R.K. Grasselli, C.G. Lugmair, A.F. Volpe, Jr., B.H. Toby and T. Vogt, Topics in Catalysis, in press.
    • (2001) Featured Lecture, 4th World Congress on Oxidation Catalysis
    • Grasselli, R.K.1
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    • A.T. Guttmann, R.K. Grasselli, J.F. Brazdil and D.D. Suresh, US Patent 4 746 641 (1988); A.Anderson, S.L.T. Anderson, G. Centi, R.K. Grasselli, M. Sanati and F. Trifiro. Proceedings of the loth International Congress on Catalysis, eds. L. Guczi et al. (Akademiai Kiado, Budapest, 1992) p. A 691; R.K. Grasselli, Catal. Today 49 (1999) 141.
    • Guttmann, A.T.1    Grasselli, R.K.2    Brazdil, J.F.3    Suresh, D.D.4
  • 56
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    • A.T. Guttmann, R.K. Grasselli, J.F. Brazdil and D.D. Suresh, US Patent 4 746 641 (1988); A.Anderson, S.L.T. Anderson, G. Centi, R.K. Grasselli, M. Sanati and F. Trifiro. Proceedings of the loth International Congress on Catalysis, eds. L. Guczi et al. (Akademiai Kiado, Budapest, 1992) p. A 691; R.K. Grasselli, Catal. Today 49 (1999) 141.
    • (1999) Catal. Today , vol.49 , pp. 141
    • Grasselli, R.K.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.