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Volumn 14, Issue 27, 2008, Pages 8383-8397

Intermolecular alkene and alkyne hydroacylation with β-S-substituted aldehydes: Mechanistic insight into the role of a hemilabile P-O-P ligand

Author keywords

Decarbonylation; Heterogeneous catalysis; Hydroacylation; Phosphane complexes; Rhodium

Indexed keywords

ACETYLENE; ALDEHYDES; CATALYSTS; HYDROCARBONS; OLEFINS; ORGANIC COMPOUNDS; RHODIUM;

EID: 53849136630     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200800738     Document Type: Article
Times cited : (98)

References (116)
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    • This catalyst has been formulated as existing mainly as monomeric [Rh(acetone)2(dppe, ClO4] in dilute acetone solutions, the closely associated ion-pair [Rh(ClO4)(dppe, in CD 2Cl2 solutions and the arene bridged dimer [Rhdppe, 2[ClO4]2 in nitromethane. The active catalyst is strongly argued to be a monomeric substrate adduct, and rales of catalysis for the hydroacylation of 4-pentenal are similar for all three solvents, which suggests a common active species
    • 2 in nitromethane. The active catalyst is strongly argued to be a monomeric substrate adduct, and rales of catalysis for the hydroacylation of 4-pentenal are similar for all three solvents, which suggests a common active species.
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    • In our initial communication reference [19, we did not report the minor isomer 8c[CbCl6] present in 5% relative concentration at 289 K
    • 6] present in 5% relative concentration at 289 K.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.