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Volumn 38, Issue 21, 1999, Pages 3231-3235

A robust, environmentally benign catalyst for highly selective hydroformylation

Author keywords

Hydroformylations; Immobilization; Rhodium; Sol gel processes

Indexed keywords

ALDEHYDE; ALKENE; RHODIUM;

EID: 0033517803     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19991102)38:21<3231::AID-ANIE3231>3.0.CO;2-B     Document Type: Article
Times cited : (125)

References (24)
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    • (1997) Angew. Chem. , vol.109 , pp. 1074-1095
    • Herrmann, W.A.1    Cornils, B.2
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    • W. A. Herrmann, B. Cornils, Angew. Chem. 1997, 109, 1074-1095; Angew. Chem. Int. Ed. Engl. 1997, 36, 1048-1067.
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 1048-1067
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    • M. T. Reetz, A. Zonta, J. Simpelkamp, Angew. Chem. 1995, 107, 373; Angew. Chem. Int. Ed. Engl. 1995, 34, 301-302.
    • (1995) Angew. Chem. Int. Ed. Engl. , vol.34 , pp. 301-302
  • 16
    • 0345350780 scopus 로고    scopus 로고
    • note
    • The synthesis of siloxantphos (A) and siloxPNP (C) will be published elsewhere.
  • 17
    • 0344488408 scopus 로고    scopus 로고
    • note
    • P-Rh = 121 Hz).
  • 18
    • 0344919544 scopus 로고    scopus 로고
    • note
    • The stretch frequency of the carbonyl group is slightly influenced by the nature of the counterion of the complexes.
  • 21
    • 0344919542 scopus 로고    scopus 로고
    • note
    • 2. R values [I > 2σ(I)]: R1 = 0.0538, wR2 = 0.1337. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-128890. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
  • 23
    • 0345350778 scopus 로고    scopus 로고
    • note
    • The bite angles of the ligands were calculated on [Rh(ligand)] as reported in ref. [12].
  • 24
    • 0344919543 scopus 로고    scopus 로고
    • note
    • See the Supporting Information for the determination of the rate equation.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.