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3543008554
-
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note
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2] is more resistant toward ligand substitution.
-
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41
-
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0039420077
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(b) Benn, R.; Cibura, K.; Hofmann, P.; Jonas, K.; Rufinska, A. Organometallics 1985, 4, 2214-2221.
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42
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0031069002
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Lenges, C.P.1
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Grant, B.E.3
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0011438965
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Brookhart, M.; Grant, B.; Volpe, A. Organometallics 1992, 11, 3920-3922.
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0000952986
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84981893981
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Koelle, U.1
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-
46
-
-
3543012784
-
-
For complete structural data see the Supporting Information
-
For complete structural data see the Supporting Information.
-
-
-
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47
-
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84989446802
-
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27544448971
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49
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84985667676
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0031116062
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-
51
-
-
3542999493
-
-
Unpublished results
-
2], several isomers are observed in which the substituent on the olefin is directed either toward the other olefin substituent or toward the Cp* ligand. Brookhart, M.; Lenges, C. P. Unpublished results.
-
-
-
Brookhart, M.1
Lenges, C.P.2
-
52
-
-
3543004330
-
-
note
-
3 resonance at -0.21; several olefinic resonances in the region of 2.5-0.3 ppm support this assignment.
-
-
-
-
53
-
-
3543017563
-
-
note
-
Addition of trimethylvinylsilane to a reaction mixture prepared in this fashion allows entry into a typical catalytic hydroacylation cycle and regeneration of the equilibrium mixture of 1 and 4.
-
-
-
-
55
-
-
3543031819
-
-
note
-
1/2 ≃ 45 Hz) which corresponds to a Co-CO.
-
-
-
-
56
-
-
3543030660
-
-
note
-
3] was not observed in this reaction, vide infra.
-
-
-
-
57
-
-
0006820287
-
-
Sarkar, T. K.; Gosh, S. K.; Satapathi, T. K. Tetrahedron 1990, 46, 1885-1898.
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Sarkar, T.K.1
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Satapathi, T.K.3
-
58
-
-
0030039487
-
-
The stability of aldehydes with β-silyl substituents has been discussed. See: Hoveyda, A. H.; Young, D. G. J.; Hale, M. R. Tetrahedron Lett. 1996, 37, 827-830.
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Hoveyda, A.H.1
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Hale, M.R.3
-
59
-
-
0000699784
-
-
In comparison to other Co(III)-CO complexes the series of complexes of type 4 show relatively low CO bands. See for example: Dahl, L. F.; Nagaki, D. A.; Olson, W. L. Organometallics 1986, 5, 630-634.
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Dahl, L.F.1
Nagaki, D.A.2
Olson, W.L.3
-
60
-
-
3543008553
-
-
note
-
2] is observed.
-
-
-
-
61
-
-
0040487438
-
-
Werner, H.; Heiser, B.; Klingert, B.; Doefel, R. J. Organomet. Chem. 1982, 240, 179-190.
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-
62
-
-
3543046362
-
-
note
-
-1, 56 equiv.
-
-
-
-
63
-
-
3543043338
-
-
note
-
Kinetics are consistent with either rapid preequilibrium between 41 and 12 favoring 41 followed by reductive elimination or rate-determining trapping of 51 followed by rapid reductive elimination.
-
-
-
-
64
-
-
3543027649
-
-
note
-
5).
-
-
-
-
65
-
-
3543018121
-
-
note
-
Repeated attempts to isolate 13 were not successful; decomposition to ketone 31 and unassigned organometallic products are observed.
-
-
-
-
66
-
-
0010321461
-
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3543022911
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Bergman, R. G.; Bryndza, H. E.; Evitt, E. R. J. Am. Chem. Soc. 1980, 102, 4948-4951.
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-
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0039650913
-
-
In a subsequent study Bergman et al. investigated a similar Co(III)-metallacyclopentanone system. Even at high temperatures the formation of cyclobutanone was not observed. See: (a) Bergman, R. G.; Theopold, K. H. Organometallics 1982, 1, 1571-1579. (b) Bergman, R. G.; Theopold, K. H.; Becker, P. N. J. Am. Chem. Soc. 1982, 104, 5250-5252.
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Bergman, R.G.1
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0037545891
-
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In a subsequent study Bergman et al. investigated a similar Co(III)-metallacyclopentanone system. Even at high temperatures the formation of cyclobutanone was not observed. See: (a) Bergman, R. G.; Theopold, K. H. Organometallics 1982, 1, 1571-1579. (b) Bergman, R. G.; Theopold, K. H.; Becker, P. N. J. Am. Chem. Soc. 1982, 104, 5250-5252.
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Bergman, R.G.1
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72
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3543010967
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Maitlis, P. M.; Saez, I. M., Fanizzi, F. P.; Sunley, G. J. J. Organomet. Chem. 1987, 330, C27-C30.
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0000348083
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Suggs, J. W.; Wovkulich, M. J.; Cox, S. D. Organometallics 1985, 4, 1101-1107.
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Suggs, J.W.1
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Cox, S.D.3
-
74
-
-
3543007362
-
-
note
-
3); other products are not observed. During catalysis the formation of isomeric hexanals is observed as well.
-
-
-
-
77
-
-
0001467488
-
-
Takegami, Y.; Watanabe, Y.; Mitsudo, T.; Yamashita, M. Bull. Chem. Soc. Jpn. 1976, 49, 3597-3600.
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Takegami, Y.1
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78
-
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3543017562
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Yamamoto, A.; Koshiro, Y.; Horino, H.; Ito, T. Bull. Chem. Soc. Jpn. 1982, 55, 504-512.
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Yamamoto, A.1
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79
-
-
3542994702
-
-
note
-
This reaction is observed with substrates without acidic α-protons to avoid competitive enolate-type transformations. The Tishenko analogue reaction reported here is curiously exclusive for alkyl aldehydes. Aromatic aldehydes show regular decarbonylation chemistry to 14 and 15 in the presence of excess aldehyde.
-
-
-
-
80
-
-
3543023518
-
-
note
-
Turnover numbers on the order of 50-100 are observed for aldehydes such as isobutyraldehyde or cyclohexanecarbaldehyde at 10 °C with turnover frequencies of ∼4 TO/h under these conditions. 4 persists to 90% conversion of aldehyde to ester; then deactivation is observed, and besides decarbonylation product 15 further unassigned organometallic complexes were observed.
-
-
-
-
81
-
-
3543028272
-
-
(a) Puddephatt, R. J.; Brown, M. P.; Upton, C. E. E.; Lavington, S. W. J. Chem. Soc., Dalton Trans. 1974, 1613-1618.
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Puddephatt, R.J.1
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0000716713
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Wadepohl, H.; Borchert, T.; Buechner, H.; Pritzkow, H. Chem. Ber. 1993, 126, 1615-1618.
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37049083577
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Wadepohl, H.; Borchert, T.; Pritzkow, H. J Chem. Soc., Chem. Commun. 1995, 1447-1448.
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0030039487
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