Two faces of a biomimetic non-heme HO-FeV=O oxidant: Olefin epoxidation versus cis-dihydroxylation

Angewandte Chemie - International Edition

Volumn 44, Issue 19, 2005, Pages 2939-2941

  Bassan, Arianna ^a   Blomberg, Margareta R A ^a   Siegbahn, Per E M ^a   Que Jr , Lawrence ^b  

^a STOCKHOLM UNIVERSITY   (Sweden)

^b University of Minnesota   (United States)

Author keywords

Density functional calculations; Dihydroxylation; Enzyme models; Epoxidation; Iron

Indexed keywords

HYBRID DENSITY FUNCTIONAL THEORY; HYDROXO LIGANDS; OLEFIN EPOXIDATION; OXIDANTS;

ACTIVATION ENERGY; AMINES; CARBON; CATALYSIS; OLEFINS; OXIDATION; PROBABILITY DENSITY FUNCTION;

BIOMIMETIC MATERIALS;

ALKENE; EPOXIDE; FE(II)TRIS(2 PYRIDYLMETHYL)AMINE; FE(II)TRIS(2-PYRIDYLMETHYL)AMINE; FERROUS ION; HEME; IRON; LIGAND; ORGANOMETALLIC COMPOUND; PYRIDINE DERIVATIVE;

ARTICLE; BIOMIMETICS; CHEMISTRY; CONFORMATION; HYDROXYLATION; OXIDATION REDUCTION REACTION; QUANTUM THEORY;

ALKENES; BIOMIMETICS; EPOXY COMPOUNDS; FERROUS COMPOUNDS; HEME; HYDROXYLATION; IRON; LIGANDS; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; PYRIDINES; QUANTUM THEORY;

EID: 18844377203     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200463072     Document Type: Article

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