메뉴 건너뛰기




Volumn 11, Issue 10, 2008, Pages 1136-1139

Syntheses, characterizations and topology analyses of two 3D copper-organic frameworks from Cu(pyzca)2 (pyzca = pyrazine-2-carboxylate) building block

Author keywords

Coordination polymers; Cyanide bridging; Solvothermal synthesis; Topology analyses; Triply bridged SCN ligand

Indexed keywords


EID: 53149130539     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2008.06.021     Document Type: Article
Times cited : (10)

References (91)
  • 59
    • 53149152323 scopus 로고    scopus 로고
    • 2 (38.8 mg, 0.125 mmol) were placed in a thick-walled Pyrex tube (ca. 15 cm long). After DMF (2 mL) was added, the mixture was evacuated and the tube was flame-sealed. The tube was heated at 160 C for 48 h. Upon cooling to room temperature over 48 h, red crystals of 1 suitable for X-ray diffraction were formed, yielded: 34.5 mg, about 25% based on CuCN. Yellow crystals of 2 were obtained via a similar manner as for 1 except that CuSCN was used instead of CuCN, Yield: 41.5 mg, about 30% based on CuSCN.
    • 2 (38.8 mg, 0.125 mmol) were placed in a thick-walled Pyrex tube (ca. 15 cm long). After DMF (2 mL) was added, the mixture was evacuated and the tube was flame-sealed. The tube was heated at 160 C for 48 h. Upon cooling to room temperature over 48 h, red crystals of 1 suitable for X-ray diffraction were formed, yielded: 34.5 mg, about 25% based on CuCN. Yellow crystals of 2 were obtained via a similar manner as for 1 except that CuSCN was used instead of CuCN, Yield: 41.5 mg, about 30% based on CuSCN.
  • 60
    • 53149109820 scopus 로고    scopus 로고
    • Crystal data for compound 1
    • 2 using all data with SHELXL programs.
  • 61
    • 53149149538 scopus 로고    scopus 로고
    • 2S: C, 26.06%; H, 1.09%; N, 15.20%. Found: C, 26.15%; H, 1.16%; N, 15.28%.
    • 2S: C, 26.06%; H, 1.09%; N, 15.20%. Found: C, 26.15%; H, 1.16%; N, 15.28%.
  • 78
    • 53149142199 scopus 로고    scopus 로고
    • O'Keeffe, See website: .
    • O'Keeffe, See website: .
  • 79
    • 33745212431 scopus 로고    scopus 로고
    • EPINET, S.T. Hyde, O.D. Friedrichs, S.J. Ramsden, V. Robins, Solid State Sci. 8 (2006) 740. .
    • EPINET, S.T. Hyde, O.D. Friedrichs, S.J. Ramsden, V. Robins, Solid State Sci. 8 (2006) 740. .
  • 81
  • 82
    • 0013054850 scopus 로고    scopus 로고
    • and the website therein
    • Batten S.R. CrystEngComm 3 (2001) 67 and the website therein
    • (2001) CrystEngComm , vol.3 , pp. 67
    • Batten, S.R.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.