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Volumn 121, Issue 48, 1999, Pages 11249-11250

A novel octupolar metal-organic NLO material based on a chiral 2D coordination network [14]

Author keywords

[No Author keywords available]

Indexed keywords

CADMIUM DERIVATIVE; COORDINATION COMPOUND; METAL COMPLEX; ORGANIC COMPOUND; POLYMER;

EID: 0033537055     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9928327     Document Type: Letter
Times cited : (493)

References (35)
  • 10
    • 0028445980 scopus 로고
    • Another motivation for this work comes from the fact that many technologically important inorganic NLO crystals such as lithium borate and β-barium borate are of octupolar nature. See: (a) Xia, Y. Adv. Mater. 1994, 6, 510-511. (b) Chen, C.; Wang, Y.; Wu, B.; Wu, K.; Zng, W.; Yu, L. Nature 1995, 373, 322-324.
    • (1994) Adv. Mater. , vol.6 , pp. 510-511
    • Xia, Y.1
  • 11
    • 0028872940 scopus 로고
    • Another motivation for this work comes from the fact that many technologically important inorganic NLO crystals such as lithium borate and β-barium borate are of octupolar nature. See: (a) Xia, Y. Adv. Mater. 1994, 6, 510-511. (b) Chen, C.; Wang, Y.; Wu, B.; Wu, K.; Zng, W.; Yu, L. Nature 1995, 373, 322-324.
    • (1995) Nature , vol.373 , pp. 322-324
    • Chen, C.1    Wang, Y.2    Wu, B.3    Wu, K.4    Zng, W.5    Yu, L.6
  • 25
    • 13044310385 scopus 로고    scopus 로고
    • note
    • 3: C, 50.9; H, 3.62; N, 7.41. Found: C, 50.4; H, 3.57; N, 7.33.
  • 26
    • 13044310592 scopus 로고    scopus 로고
    • note
    • 3-O group, the EA, TGA, and density results would have been significantly different owing to the presence of only one perchlorate anion.
  • 27
    • 13044307843 scopus 로고    scopus 로고
    • note
    • 3, T = 293 K, Mo Kα radiation (λ = 0.71073 Å). Least-squares refinements based on 2674 [1984 with I > 2σ(I)] reflections, 254 parameters, and 21 restraints led to convergence, with a final value of R1 = 0.049 (0.027) and wR2 = 0.065 (0.060). The crystal is enantiomerically twinned with a BASF value of 0.57.
  • 28
    • 0000169484 scopus 로고
    • 3 plane. Also see: (a) Konno, T.; Kageyama, Y.; Okamoto, K.-i. Bull. Chem. Soc. Jpn. 1994, 67, 1957-1960. (b) Weidenbruch, M.; Herrndorf, M.; Schäfer, A.; Pohl, S.; Saak, W. J. Organomet. Chem. 1989, 361, 139-145.
    • (1994) Bull. Chem. Soc. Jpn. , vol.67 , pp. 1957-1960
    • Konno, T.1    Kageyama, Y.2    Okamoto, K.-I.3
  • 30
    • 13044314283 scopus 로고    scopus 로고
    • note
    • Pillared 2D sheets based on hydrogen-bonded systems have recently been used to crystal engineer novel clathrate materials.
  • 34
    • 13044314517 scopus 로고    scopus 로고
    • note
    • 2ω of ca. 10 vs. α-quartz.
  • 35
    • 13044301400 scopus 로고    scopus 로고
    • note
    • We believe that charge transfer from the carboxylate end to the pyridine end in L is the origin of second-order optical nonlinearity in 1 since the replacement of L in 1 with isonicotinate groups results in the diminishment of SHG efficiency. Unpublished results.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.