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Another motivation for this work comes from the fact that many technologically important inorganic NLO crystals such as lithium borate and β-barium borate are of octupolar nature. See: (a) Xia, Y. Adv. Mater. 1994, 6, 510-511. (b) Chen, C.; Wang, Y.; Wu, B.; Wu, K.; Zng, W.; Yu, L. Nature 1995, 373, 322-324.
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2d,e Also see: Voigt-Martin, I. G.; Li, G.; Yakimanski, A.; Schulz, G.; Wolff, J. J. J. Am. Chem. Soc. 1996, 118, 12830-12831.
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0032561806
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25
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13044310385
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note
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3: C, 50.9; H, 3.62; N, 7.41. Found: C, 50.4; H, 3.57; N, 7.33.
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26
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13044310592
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note
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3-O group, the EA, TGA, and density results would have been significantly different owing to the presence of only one perchlorate anion.
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27
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13044307843
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note
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3, T = 293 K, Mo Kα radiation (λ = 0.71073 Å). Least-squares refinements based on 2674 [1984 with I > 2σ(I)] reflections, 254 parameters, and 21 restraints led to convergence, with a final value of R1 = 0.049 (0.027) and wR2 = 0.065 (0.060). The crystal is enantiomerically twinned with a BASF value of 0.57.
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28
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0000169484
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3 plane. Also see: (a) Konno, T.; Kageyama, Y.; Okamoto, K.-i. Bull. Chem. Soc. Jpn. 1994, 67, 1957-1960. (b) Weidenbruch, M.; Herrndorf, M.; Schäfer, A.; Pohl, S.; Saak, W. J. Organomet. Chem. 1989, 361, 139-145.
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Konno, T.1
Kageyama, Y.2
Okamoto, K.-I.3
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29
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0001556935
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3 plane. Also see: (a) Konno, T.; Kageyama, Y.; Okamoto, K.-i. Bull. Chem. Soc. Jpn. 1994, 67, 1957-1960. (b) Weidenbruch, M.; Herrndorf, M.; Schäfer, A.; Pohl, S.; Saak, W. J. Organomet. Chem. 1989, 361, 139-145.
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Weidenbruch, M.1
Herrndorf, M.2
Schäfer, A.3
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Saak, W.5
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30
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13044314283
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note
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Pillared 2D sheets based on hydrogen-bonded systems have recently been used to crystal engineer novel clathrate materials.
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31
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1842378076
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(a) Russell, V. A.; Evans, C. C.; Li, W.; Ward, M. D. Science 1997, 276, 575-579.
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0031780159
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(b) Swift, J. A.; Pivovar, A. M.; Reynolds, A. M.; Ward, M. D. J. Am. Chem. Soc. 1998, 120, 5887-5894.
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34
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13044314517
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note
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2ω of ca. 10 vs. α-quartz.
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35
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13044301400
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note
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We believe that charge transfer from the carboxylate end to the pyridine end in L is the origin of second-order optical nonlinearity in 1 since the replacement of L in 1 with isonicotinate groups results in the diminishment of SHG efficiency. Unpublished results.
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