Solvothermal synthesis of a stable coordination polymer with copper-I copper-II dimer units: [Cu4{1,4- C6H4(COO)2}3(4,4'-bipy)2](n)

Journal of the American Chemical Society

Volumn 122, Issue 26, 2000, Pages 6293-6294

  Lo, Samuel M F ^a   Chui, Stephen S Y ^a   Shek, Lai Yung ^a   Lin, Zhenyang ^a   Zhang, Xi Xiang ^a   Wen, Ge Hei ^a   Williams, Ian D ^a  

^a HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; POLYMER;

CHEMICAL REACTION KINETICS; CRYSTAL STRUCTURE; LETTER; METAL BINDING; ORGANIC CHEMISTRY; OXIDATION REDUCTION REACTION; POLYMERIZATION; SYNTHESIS; THERMAL ANALYSIS;

EID: 0034608964     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja000416c     Document Type: Letter

References (35)

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9. 4, 4′-bipyridine is used as a rigid linker to assist formation of open coordination polymers. Recent work with this includes. MacGillivray, L. R.; Groeneman, R. H.; Atwood, J. L. J. Am. Chem. Soc. 1998, 120, 2676-2677. Noro, S.; Kondo, M.; Kitagara, S.; Ishii, T.; Matsuzaka, H. Chem. Lett. 1999, 727-728. Zheng, L. M.; Fang, X.; Lii, K. H.; Song, H. H.; Xin, X. Q.; Fun, H. K.; Chinnakali, K.; Razak, I. A. J. Chem. Soc., Dalton Trans. 1999, 2311- 2316. Pan, L.; Zheng, N. W.; Wu, Y. G.; Jin, X. L.; Huang, X. Y. J. Coord. Chem. 1999, 47, 269-277. Wang, Q. M.; Wu, X. T.; Zhang, W. J.; Sheng, T. L.; Lin, P.; Li, J. M. Inorg. Chem. 1999, 38, 2223-2226. Lightfoot, P.; Snedden, A. J. Chem. Soc. Dalton Trans. 1999, 3549-3551.
10. 4, 4′-bipyridine is used as a rigid linker to assist formation of open coordination polymers. Recent work with this includes. MacGillivray, L. R.; Groeneman, R. H.; Atwood, J. L. J. Am. Chem. Soc. 1998, 120, 2676-2677. Noro, S.; Kondo, M.; Kitagara, S.; Ishii, T.; Matsuzaka, H. Chem. Lett. 1999, 727-728. Zheng, L. M.; Fang, X.; Lii, K. H.; Song, H. H.; Xin, X. Q.; Fun, H. K.; Chinnakali, K.; Razak, I. A. J. Chem. Soc., Dalton Trans. 1999, 2311-2316. Pan, L.; Zheng, N. W.; Wu, Y. G.; Jin, X. L.; Huang, X. Y. J. Coord. Chem. 1999, 47, 269-277. Wang, Q. M.; Wu, X. T.; Zhang, W. J.; Sheng, T. L.; Lin, P.; Li, J. M. Inorg. Chem. 1999, 38, 2223-2226. Lightfoot, P.; Snedden, A. J. Chem. Soc. Dalton Trans. 1999, 3549-3551.
11. 4, 4′-bipyridine is used as a rigid linker to assist formation of open coordination polymers. Recent work with this includes. MacGillivray, L. R.; Groeneman, R. H.; Atwood, J. L. J. Am. Chem. Soc. 1998, 120, 2676-2677. Noro, S.; Kondo, M.; Kitagara, S.; Ishii, T.; Matsuzaka, H. Chem. Lett. 1999, 727-728. Zheng, L. M.; Fang, X.; Lii, K. H.; Song, H. H.; Xin, X. Q.; Fun, H. K.; Chinnakali, K.; Razak, I. A. J. Chem. Soc., Dalton Trans. 1999, 2311- 2316. Pan, L.; Zheng, N. W.; Wu, Y. G.; Jin, X. L.; Huang, X. Y. J. Coord. Chem. 1999, 47, 269-277. Wang, Q. M.; Wu, X. T.; Zhang, W. J.; Sheng, T. L.; Lin, P.; Li, J. M. Inorg. Chem. 1999, 38, 2223-2226. Lightfoot, P.; Snedden, A. J. Chem. Soc. Dalton Trans. 1999, 3549-3551.
12. 4, 4′-bipyridine is used as a rigid linker to assist formation of open coordination polymers. Recent work with this includes. MacGillivray, L. R.; Groeneman, R. H.; Atwood, J. L. J. Am. Chem. Soc. 1998, 120, 2676-2677. Noro, S.; Kondo, M.; Kitagara, S.; Ishii, T.; Matsuzaka, H. Chem. Lett. 1999, 727-728. Zheng, L. M.; Fang, X.; Lii, K. H.; Song, H. H.; Xin, X. Q.; Fun, H. K.; Chinnakali, K.; Razak, I. A. J. Chem. Soc., Dalton Trans. 1999, 2311- 2316. Pan, L.; Zheng, N. W.; Wu, Y. G.; Jin, X. L.; Huang, X. Y. J. Coord. Chem. 1999, 47, 269-277. Wang, Q. M.; Wu, X. T.; Zhang, W. J.; Sheng, T. L.; Lin, P.; Li, J. M. Inorg. Chem. 1999, 38, 2223-2226. Lightfoot, P.; Snedden, A. J. Chem. Soc. Dalton Trans. 1999, 3549-3551.
13. 4, 4′-bipyridine is used as a rigid linker to assist formation of open coordination polymers. Recent work with this includes. MacGillivray, L. R.; Groeneman, R. H.; Atwood, J. L. J. Am. Chem. Soc. 1998, 120, 2676-2677. Noro, S.; Kondo, M.; Kitagara, S.; Ishii, T.; Matsuzaka, H. Chem. Lett. 1999, 727-728. Zheng, L. M.; Fang, X.; Lii, K. H.; Song, H. H.; Xin, X. Q.; Fun, H. K.; Chinnakali, K.; Razak, I. A. J. Chem. Soc., Dalton Trans. 1999, 2311- 2316. Pan, L.; Zheng, N. W.; Wu, Y. G.; Jin, X. L.; Huang, X. Y. J. Coord. Chem. 1999, 47, 269-277. Wang, Q. M.; Wu, X. T.; Zhang, W. J.; Sheng, T. L.; Lin, P.; Li, J. M. Inorg. Chem. 1999, 38, 2223-2226. Lightfoot, P.; Snedden, A. J. Chem. Soc. Dalton Trans. 1999, 3549-3551.
14. 6C, 49.91; H, 2.65; N, 5.29 Found C, 49.19; H, 2.65; N, 5.48%.
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23. EHMO studies have been carried out on a model complex of 2. These are in general agreement with those in refs 10a and 11.
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29. Temperature-dependent magnetic susceptibilities were measured on a Quantum Design MPMS-5 SQUID magnetometer from 4 to 300 K at fields of 0.1 to 2.0 T.
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33. 4+species through completion of the coordination sphere with carboxylate or hydroxide ions.
34. Fine control of mixed-valence species is desirable since it has major influence on magnetic properties, as in ref 2 and in the related Mo-cyanides: Sra, A. K.; Andruh, M.; Kahn, O. Golhen, S.; Ouahab, L.; Yakhmi, J. V. Angew. Chem., Int. Ed. 1999, 38, 2606-2609. Larionova, J.; Kahn, O.; Golhen, S.; Ouahab, L.; Clerac, R. J. Am. Chem. Soc. 1999, 121, 3349-3356.
35. Fine control of mixed-valence species is desirable since it has major influence on magnetic properties, as in ref 2 and in the related Mo-cyanides: Sra, A. K.; Andruh, M.; Kahn, O. Golhen, S.; Ouahab, L.; Yakhmi, J. V. Angew. Chem., Int. Ed. 1999, 38, 2606-2609. Larionova, J.; Kahn, O.; Golhen, S.; Ouahab, L.; Clerac, R. J. Am. Chem. Soc. 1999, 121, 3349-3356.