A chemically functionalizable nanoporous material [Cu3(TMA)2 (H2O)3](n)

Science

Volumn 283, Issue 5405, 1999, Pages 1148-1150

  Chui, Stephen S Y ^a   Lo, Samuel M F ^a   Charmant, Jonathan P H ^b   Orpen, A Guy ^b   Williams, Ian D ^a  

^a HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^b UNIVERSITY OF BRISTOL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

NANOPARTICLE; POLYMER; ZEOLITE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; MOLECULAR STABILITY; POROSITY; PRIORITY JOURNAL; STRUCTURE ANALYSIS;

EID: 0033582733     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.283.5405.1148     Document Type: Article

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40. 2, and others).
41. 3) was formed with large 48-membered rings of six individual Cu atoms and six TMA groups.
42. 2 loss). Variable-temperature single-crystal studies of the DMSO derivative showed no bound DMSO at RT; heating up to 200°C produced intensity changes due to solvent loss (reflection 222 increases in intensity and reflection 400 decreases). Cooling to RT resulted in a general reversal of these trends.
43. 2 produced Δw = <-1% from 25° to 500°C and Δw = -45.7% from 500° to 650°C, corresponding to decarboxylation.
44. We are grateful to the Research Grants Council of Hong Kong (RGC grants 6148-97P and 6061-98P) and the Advanced Materials Research Institute (AMRI-HKUST) for financial support and to J. Zheng and A. Siu for technical assistance.