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Transition temperatures: s-18b: c 182 i; i 181 N; s-19b: c 199 i; i 188 N; m-18b: c 132 N 177 i; m-19b: c 111 N 160 i; 1-18b: c 71 SmC 79 SmA 95 n 109 i; 1-19b: c 73 SmC 80 SmA 99 n 114 i.
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[74a] The material was obtained through aqueous extractive work up; i.e., fractionation was avoided to obtain a representative sample of the polymerisation experiment.
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149
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13C NMR spectroscopy.
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The signals of the olefinic unit appear well-separated from the signals of the other parts of the molecule. In the case of the polyester formations described, the signals of the end groups are comparatively difficult to detect because they are close to the signals of both the product and the potential by-products.
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[78c] Karagounis has investigated a similar approach, but using inappropriate ring sizes. A discussion of this work, including references, can be found in ref.[47a]
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