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Volumn 27, Issue 8, 2008, Pages 1809-1822

(η6-arene)-ruthenium(II) complexes containing methanide and methandiide anions of Ph2P(=S)CH2P(=NR)Ph2: Unprecedented insertion of isocyanide into a ruthenium-carbene bond

Author keywords

[No Author keywords available]

Indexed keywords

BOND STRENGTH (CHEMICAL); MOLECULAR STRUCTURE; REACTION KINETICS; RUTHENIUM COMPOUNDS; X RAY CRYSTALLOGRAPHY;

EID: 43249126799     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om701228a     Document Type: Article
Times cited : (28)

References (115)
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    • 2 was found to be stable enough to be crystallographically characterized: (a) Kasani, A.; Kamalesh Babu, R. P.; McDonald, R.; Cavell, R. G. Angew. Chem., Int. Ed. 1999, 38, 1483.
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    • 2 dimers have also been described recently: Hull, K. L.; Noll, B. C.; Henderson, K. W. Organometallics 2006, 25, 4072.
    • 2 dimers have also been described recently: Hull, K. L.; Noll, B. C.; Henderson, K. W. Organometallics 2006, 25, 4072.
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    • Two accounts dealing with this topic are available: (a) Cavell, R. G.; Kamalesh Babu, R. P.; Aparna, K. J. Organomet. Chem. 2001, 617-618, 158.
    • Two accounts dealing with this topic are available: (a) Cavell, R. G.; Kamalesh Babu, R. P.; Aparna, K. J. Organomet. Chem. 2001, 617-618, 158.
  • 33
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    • 6-p- cymene)-Ru(II) and Cp*Ru(II) fragments has been reported by K. G. Caulton and co-workers: (a) Bibal, C.; Pink, M.; Smurnyy, Y. D.; Tomaszewski, J.; Caulton, K. G. J. Am. Chem. Soc. 2004, 126, 2312.
    • 6-p- cymene)-Ru(II) and Cp*Ru(II) fragments has been reported by K. G. Caulton and co-workers: (a) Bibal, C.; Pink, M.; Smurnyy, Y. D.; Tomaszewski, J.; Caulton, K. G. J. Am. Chem. Soc. 2004, 126, 2312.
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    • An account on this chemistry is available: (a) Doux, M, Piechaczyk, O, Cantat, T, Mézailles, N, Le Hoch, P. C. R. Chim. 2007, 10, 573
    • An account on this chemistry is available: (a) Doux, M.; Piechaczyk, O.; Cantat, T.; Mézailles, N.; Le Hoch, P. C. R. Chim. 2007, 10, 573.
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    • Extensive electronic delocalization is a classical feature of N-phosphorylated or thiophosphorylated iminophophorane units -Ph 2P=N-P(=X)(OR)2 (X, O, S, See for example: (a) Larré, C, Donnadieu, B, Caminade, A. M, Majoral, J. P. Eur. J. Inorg. Chem. 1999, 601
    • 2 (X = O, S). See for example: (a) Larré, C.; Donnadieu, B.; Caminade, A. M.; Majoral, J. P. Eur. J. Inorg. Chem. 1999, 601.
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    • Magro, G.; Donnadieu, B.; Caminade, A.-M.; Majoral, J.-P. Chem. Eur. J. 2003, 9, 2151 See also refs 15 and 26.
    • (f) Magro, G.; Donnadieu, B.; Caminade, A.-M.; Majoral, J.-P. Chem. Eur. J. 2003, 9, 2151 See also refs 15 and 26.
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    • 2P=N(P- Tolyl)}] has also been reported: Grim, S. O.; Kettler, P. B. J. Chem. Soc., Chem. Commun. 1991, 979.
    • 2P=N(P- Tolyl)}] has also been reported: Grim, S. O.; Kettler, P. B. J. Chem. Soc., Chem. Commun. 1991, 979.
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    • Maraval, A.; Magro, G.; Maraval, V.; Vendier, L.; Caminade, A.-M.; Majoral, J.-P. J. Organomet. Chem. 2006, 691, 1333. See also ref 26i.
    • (d) Maraval, A.; Magro, G.; Maraval, V.; Vendier, L.; Caminade, A.-M.; Majoral, J.-P. J. Organomet. Chem. 2006, 691, 1333. See also ref 26i.
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    • As shown in Figures 1 and 2 (structures E and H, while studying the coordination to ruthenium of the methanide and methandiide anions derived from CH2[P{=NP(=S)(OR)2)Ph2]2 R, Et, Ph, some complexes showing the N-coordination of the P=N-P=S framework could be isolated: see ref 15b
    • 2 (R = Et, Ph), some complexes showing the N-coordination of the P=N-P=S framework could be isolated: see ref 15b.
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    • All attempts to obtain crystals suitable for X-ray diffraction analysis of the chloride salts of complexes 3f and 4g failed. The corresponding hexafluoroantimonate salts, which readily crystallize by slow diffusion of n-pentane into a saturated dichloromethane solution, were obtained by chloride metathesis, using 1 equiv of AgSbF6 in methanol at room temperature
    • 6 in methanol at room temperature.
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    • 3) is one of the most popular methods to generate ketenimine complexes, (a) See for example: Aumann, R.; Fischer, E. O. Chem. Ber. 1968, 101, 954.
    • 3) is one of the most popular methods to generate ketenimine complexes, (a) See for example: Aumann, R.; Fischer, E. O. Chem. Ber. 1968, 101, 954.
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    • Both the C=C and C=N π-bonds of ketenimines R1R 2C=C=NR3 can complexate transition-metal fragments (see ref 40, For examples involving the C=C bond, see: (a) Strecker, B, Hörlin, G, Schulz, M, Werner, H. Chem. Ber. 1991, 124, 285
    • 3 can complexate transition-metal fragments (see ref 40). For examples involving the C=C bond, see: (a) Strecker, B.; Hörlin, G.; Schulz, M.; Werner, H. Chem. Ber. 1991, 124, 285.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.