Water-induced rearrangement of a platinacyclic carbene produces a platinacyclic carbaphosphazene with an intraannular Pt-C bond in a Pt-N-P-N-P-C ring

Angewandte Chemie - International Edition

Volumn 44, Issue 13, 2005, Pages 2005-2008

  Fang, Min ^a   Jones, Nathan D ^a   Ferguson, Michael J ^a   McDonald, Robert ^a   Cavell, Ronald G ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

Author keywords

Carbenes; Metallacycles; Phosphorus; Platinum; Rearrangement

Indexed keywords

ISOMERS; METHANOL; ORGANIC ACIDS; SYNTHESIS (CHEMICAL); WATER;

CARBENE; CHEMICAL EQUATION; METHYLATION; PLATINACYCLIC CARBENES;

NITROGEN COMPOUNDS;

EID: 16844366045     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461525     Document Type: Article

References (26)

1. A. R. McWilliams, H. Dorn, I. Manners, Top. Curr. Chem. 2002, 220, 141-167, and references therein.
2. V. Chandrasekhar, K. R. J. Thomas, Struct. Bonding (Berlin) 1993, 81, 42-113, and references therein.
3. V. Chandrasekhar, K. R. J. Thomas, Appl. Organomet. Chem. 1993, 7, 1-31, and references therein.
4. V. Chandrasekhar, S. Nagendran, Chem. Soc. Rev. 2001, 30, 193-203, and references therein.
5. K. Brandt, I. Porwolik, T. Kupka, A. Olejnik, R. A. Shaw, D. B. Davies, J. Org. Chem. 1995, 60, 7433-7438.
6. C. Diaz, M. Barbosa, Z. Godoy, Polyhedron 2004, 23, 1027-1035.
7. H. R. Allcock, F. H. Allen, J. P. O'Brien, J. Am. Chem. Soc. 1977, 99, 3984-3987.
8. M. Witt, H. W. Roesky, Chem. Rev. 1994, 94, 1163-1181, and references therein.
9. H. W. Roesky, K. V. Katti, U. Seseke, M. Witt, E. Egert, R. Herbst, G. M. Sheldrick, Angew. Chem. 1986, 98, 447-449; Angew. Chem. Int. Ed. Engl. 1986, 25, 477-478.
10. H. W. Roesky, K. V. Katti, U. Seseke, M. Witt, E. Egert, R. Herbst, G. M. Sheldrick, Angew. Chem. 1986, 98, 447-449; Angew. Chem. Int. Ed. Engl. 1986, 25, 477-478.
11. N. D. Jones, G. Lin, R. A. Gossage, R. McDonald, R. G. Cavell, Organometallics 2003, 22, 2832-2841; N. D. Jones, G. Lin, R. A. Gossage, R. McDonald, R. G. Cavell, Organometallics 2003, 22, 5378.
12. N. D. Jones, G. Lin, R. A. Gossage, R. McDonald, R. G. Cavell, Organometallics 2003, 22, 2832-2841; N. D. Jones, G. Lin, R. A. Gossage, R. McDonald, R. G. Cavell, Organometallics 2003, 22, 5378.
13. G. Lin, N. D. Jones, R. A. Gossage, R. McDonald, R. G. Cavell, Angew. Chem. 2003, 115, 4188-4191; Angew. Chem. Int. Ed. 2003, 42, 4054-4057.
14. G. Lin, N. D. Jones, R. A. Gossage, R. McDonald, R. G. Cavell, Angew. Chem. 2003, 115, 4188-4191; Angew. Chem. Int. Ed. 2003, 42, 4054-4057.
15. 1J(C,Pt) not observed). Complete synthetic and characterization data are given in the Supporting Information.
16. CCDC-242499 ([2][OTf], monoclinic form), CCDC-2425001 ([2][OTf], triclinic form), and CCDC-242451 ([3][OTf]) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_ request/cif. The full crystal data and their completely labeled diagrams are included in the Supporting Information.
17. A. Müller, M. Möhlen, B. Neumüller, N. Faza, W. Massa, K. Dehnicke, Z. Anorg. Allg. Chem. 1999, 625, 1748-1751.
18. H. R. Allcock in Phosphorus-Nitrogen Compounds (Ed.: H. R. Allcock), Academic Press, New York, 1972, pp. 36-93.
19. K. V. Katti, A. A. Pinkerton, R. G. Cavell, Inorg. Chem. 1991, 30, 2631-2633.
20. A. G. Orpen, L. Brammer, F. H. Allen, O. Kennard, D. G. Watson, R. Taylor, J. Chem. Soc. Perkin Trans. 2 1989, S1-S83.
21. R. Appel, I. Ruppert, Z. Anorg. Allg. Chem. 1974, 406, 131-144.
22. NH). Complete synthetic and characterization data are given in the Supporting Information.
23. P. Foley, R. DiCosimo, G. M. Whitesides, J. Am. Chem. Soc. 1980, 102, 6713-6725.
24. M. W. Avis, K. Vrieze, J. M. Ernsting, C. J. Elsevier, N. Veldman, A. L. Spek, K. V. Katti, C L. Barnes, Organometallics 1996, 15, 2376-2392.
25. M. L. Illingsworth, J. A. Teagle, J. L. Burmeister, W. C. Fultz, A. L. Rheingold, Organometallics 1983, 2, 1364-1369.
26. G. Facchin, L. Zanotto, R. Bertani, G. Nardin, Inorg. Chim. Acta 1996, 245, 157-166.