The first linear multiphosphazene having five different types of side groups and its use as the core of a dendrimeric species

Chemistry - A European Journal

Volumn 9, Issue 10, 2003, Pages 2151-2159

  Magro, Germinal ^a   Donnadieu, Bruno ^a   Caminade, Anne Marie ^a   Majoral, Jean Pierre ^a  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

Alkylation; Azides; Chain structures; Dendrimers; Phosphazenes

Indexed keywords

ELECTRONIC STRUCTURE; MATHEMATICAL MODELS; SYNTHESIS (CHEMICAL);

FUNCTIONAL SIDE GROUPS;

DENDRIMERS;

AZIDE; DENDRIMER; OLIGOPHOSPHAZENE; PHOSPHORUS DERIVATIVE; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; ELECTRONICS; INORGANIC CHEMISTRY; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0038547864     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200204630     Document Type: Article

References (39)

1. a) I. Manners, Angew. Chem. 1996, 108, 1712; Angew. Chem. Int. Ed. Engl. 1996, 35, 1602;
2. a) I. Manners, Angew. Chem. 1996, 108, 1712; Angew. Chem. Int. Ed. Engl. 1996, 35, 1602;
3. b) A. R. Mc Williams, H. Dorn, I. Manners, Top. Curr. Chem., 2001, 220, 141.
4. a) R. Schwesinger, H. Schlemper, Angew. Chem. 1987, 99, 1212; Angew. Chem. Int. Ed. Engl. 1987, 26, 1167;
5. a) R. Schwesinger, H. Schlemper, Angew. Chem. 1987, 99, 1212; Angew. Chem. Int. Ed. Engl. 1987, 26, 1167;
6. b) R. Schwesinger, C. Hasenfratz, H. Schlemper, L. Walz, E. M. Peters, K. Peters, H. G. von Schnering, Angew. Chem. 1993, 105, 1420; Angew. Chem. Int. Ed. Engl. 1993, 32, 1361.
7. b) R. Schwesinger, C. Hasenfratz, H. Schlemper, L. Walz, E. M. Peters, K. Peters, H. G. von Schnering, Angew. Chem. 1993, 105, 1420; Angew. Chem. Int. Ed. Engl. 1993, 32, 1361.
8. J. E. Mark, H. R. Allcock, R. West, Inorganic Polymers, Prentice Hall, Englewood Cliffs, New Jersey, 1992.
9. a) H. R. Allcock, Angew. Chem. 1977, 89, 153; Angew. Chem. Int. Ed. Engl. 1977, 16, 147;
10. a) H. R. Allcock, Angew. Chem. 1977, 89, 153; Angew. Chem. Int. Ed. Engl. 1977, 16, 147;
11. b) R. H. Neilson, P. Wisian-Neilson, Chem. Rev. 1988, 88, 541;
12. c) H. R. Allcock, Appl. Organomet. Chem. 1998, 12, 659.
13. H. W. Roesky, W. Grosse Böwing, E. Niecke, Chem. Ber. 1971, 104, 653.
14. a) J. M. J. Fréchet, Science, 1994, 263, 1710;
15. b) J. C. M. van Hest, D. A. P. Delnoye, M. W. P. L. Baars, M. H. P. van Genderen, E. W. Meijer, Science, 1995, 268, 1592;
16. c) M. R. Leduc, C. J. Hawker, J. Dao, J. M. J. Fréchet, J. Am. Chem. Soc. 1996, 118, 11111.
17. I. Gitsov, K. L. Wooley, J. M. J. Fréchet, Angew. Chem. 1992, 104, 1282; Angew. Chem. Int. Ed. Engl. 1992, 31, 1200.
18. I. Gitsov, K. L. Wooley, J. M. J. Fréchet, Angew. Chem. 1992, 104, 1282; Angew. Chem. Int. Ed. Engl. 1992, 31, 1200.
19. For a review, see: A. D. Schlüter, J. P. Rabe, Angew. Chem. 2000, 112, 860; Angew. Chem. Int. Ed. 2000, 39, 864.
20. For a review, see: A. D. Schlüter, J. P. Rabe, Angew. Chem. 2000, 112, 860; Angew. Chem. Int. Ed. 2000, 39, 864.
21. a) C. Larré, A. M. Caminade, J. P. Majoral, Angew. Chem. 1997, 109, 614; Angew. Chem. Int. Ed. Engl. 1997, 36, 596;
22. a) C. Larré, A. M. Caminade, J. P. Majoral, Angew. Chem. 1997, 109, 614; Angew. Chem. Int. Ed. Engl. 1997, 36, 596;
23. b) C. Galliot, C. Larré, A. M. Caminade, J. P. Majoral, Science 1997, 277, 1981;
24. c) C. Larré, B. Donnadieu, A. M. Caminade, J. P. Majoral, J. Am. Chem. Soc. 1998, 120, 4029;
25. d) C. Larré, D. Bressolles, C. Turrin, B. Donnadieu, A. M. Caminade, J. P. Majoral, J. Am. Chem. Soc. 1998, 120, 13 070;
26. e) J. P. Majoral, C. Larré, R. Laurent, A. M. Caminade, Coord. Chem. Rev. 1999, 190-192, 3.
27. 1) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44) 1223-336033; or deposit@ccdc.cam.uk).
28. Starting from this step, all the experiments must be carried out in the dark on account of the facile isomerization (E → Z) of the azobenzene linkage: R. M. Sebastian, J. C. Blais, A. M. Caminade, J. P. Majoral, Chem. Eur. J. 2002, 8, 2172.
29. H. Sun, J. Am. Chem. Soc. 1997, 119, 3611.
30. H. R. Allcock, Chem. Rev. 1972, 72, 315.
31. a) E. Fluck, Z. Anorg. Allg. Chem. 1962, 315, 191;
32. b) H. R. Allcock, N. M. Tollefson, R. A. Arcus, R. R. Whittle, J. Am. Chem. Soc. 1985, 107, 5166.
33. a) V. Maraval, R. Laurent, B. Donnadieu, M. Mauzac, A. M. Caminade, J. P. Majoral, J. Am Chem. Soc. 2000, 122, 2499;
34. b) V. Maraval, R. Laurent, S. Merino, A. M. Caminade, J. P. Majoral, Eur. J. Org. Chem. 2000, 3555.
35. J. Mitjaville, A. M. Caminade, J. C. Daran, B. Donnadieu, J. P. Majoral, J. Am. Chem. Soc. 1995, 117, 1712.
36. N. Walker, D. Stuart, DIFABS Acta Crystallogr., Sect A 1983, 39, 158.
37. A. Altomare, G. Cascarano, G. Giacovazzo, A. Guagliardi, M. C. Burla, G. Polidori, M. Camalli, SIR 92 program for automatic solution of crystal structures by direct methods. J. Appl. Crystallogr. 1994, 27, 435.
38. G. M. Sheldrick, (1997) SHELXL97. Program for the refinement of Crystal Structures. University of Göttingen (Germany).
39. L. J. Farrugia, ORTEP3 for Windows J. Appl. Crystallogr. 1997, 30, 565.