[Ph2P(NSiMe3)]2LCLi2: A dilithium dianionic methanide salt with an unusual Li4C2 cluster structure

Angewandte Chemie - International Edition

Volumn 38, Issue 10, 1999, Pages 1483-1484

  Kasani, Aparna ^a   Kamalesh Babu, Ruppa P ^a   McDonald, Robert ^a   Cavell, Ronald G ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

Author keywords

Cluster compounds; Lithium; N ligands; Phosphanimines; Phosphoranimines

Indexed keywords

LITHIUM DERIVATIVE; LITHIUM SALT;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; PH; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; REACTION ANALYSIS; STRUCTURE ACTIVITY RELATION; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0033577907     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19990517)38:10<1483::aid-anie1483>3.0.co;2-d     Document Type: Article

References (33)

1. F. A. Cotton, B. Hong, Prog. Inorg. Chem. 1992, 40, 179-289.
2. R. J. Puddephatt, Chem. Soc. Rev. 1983, 12, 99-127.
3. M. W. Avis, K. Vrieze, J. M. Ernsting, C. J. Elsevier, N. Veldman, A. L. Spek, K. V. Katti, C. L. Barnes, Organometallics 1996, 15, 2376-2392.
4. H. H. Karsch, G. Grauvogl, M. Kawecki, P. Bissinger, O. Kumberger, A. Schier, G. Müller, Organometallics 1994, 13, 610-618.
5. S. Hao, J.-I. Song, H. Aghabozorg, S. Gambarotta, J. Chem. Soc. Chem. Commun. 1994, 157-158.
6. P. Imhoff, R. van Asselt, J. M. Ernsting, K. Vrieze, C. J. Elsevier, W. J. J. Smeets, A. L. Spek, A. P. M. Kentgens, Organometallics 1993, 12, 1523-1536.
7. I. G. Phillips, R. G. Ball, R. G. Cavell, Inorg. Chem. 1988, 27, 4038-4045.
8. D. J. Brauer, S. Hietkamp, O. Stelzer, J. Organomet. Chem. 1986, 299, 137-142.
9. H. Schmidbaur, E. Weiss, B. Zimmer-Gasser, Angew. Chem. 1979, 91, 848-850;
10. Angew. Chem. Int. Ed. Engl. 1979, 18, 782-784.
11. S. I. Al-Resayes, P. B. Hitchcock, S. F. Nixon, J. Chem. Soc. Chem. Commun. 1986, 1710-1711.
12. J. Browning, K. R. Dixon, R. W. Hills, Organometallics 1989, 8, 552.
13. G. H. Robinson, B. Lee, W. T. Pennington, S. A. Sangokoya, J. Am. Chem. Soc. 1988, 110, 6260-6261.
14. B. Lee, S. A. Sangokoya, W. T. Pennington, G. H. Robinson, J. Coord. Chem. 1990, 21, 99-105.
15. G. H. Robinson, M. F. Self, W. T. Pennington, S. A. Sangokoya, Organometallics 1988, 7, 2424-2426.
16. 2: C 65.25, H 6.71, N 4.91; found: C 65.27, H 6.69, N 4.60.
17. 2) and all data, respectively. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-114415. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
18. C. K. Johnson, ORTEP, Report ORNL No. 5138, Oak Ridge National Labs, Oak Ridge, TN, USA, 1976.
19. A. Müller, B. Neumüller, K. Dehnicke, Chem. Ber. 1996, 129, 253-257.
20. H. Hope, P. P. Power, J. Am. Chem. Soc. 1983, 105, 5320-5324.
21. A. Müller, B. Neumüller, K. Dehnicke, Angew. Chem. 1997, 109, 2447-2449;
22. Angew. Chem. Int. Ed. Engl. 1997, 36, 2350-2352.
23. A. Steiner, D. Stalke, Angew. Chem. 1995, 107, 1908-1910;
24. Angew. Chem. Int. Ed. Engl. 1995, 34, 1752-1755.
25. H. Dietrich, J. Organomet. Chem. 1981, 205, 291-299.
26. E. Weiss, T. Lambertsen, B. Schubert, J. K. Cockcroft, A. Wiedenmann, Chem. Ber. 1990, 123, 79-81.
27. T. Kottke, D. Stalke, Angew. Chem. 1993, 105, 619-621;
28. Angew. Chem. Int. Ed. Engl. 1993, 32, 580-582.
29. H. H. Karsch, G. Müller, J. Chem. Soc. Chem. Commun. 1984, 569.
30. H. H. Karsch, G. Grauvogl, P. Mikulcik, P. Bissinger, G. Müller, J. Organomet. Chem. 1994, 465, 65-71.
31. M. W. Avis, C. J. Elsevier, N. Veldman, H. Kooijman, A. L. Spek, Inorg. Chem. 1996, 35, 1518-1528.
32. 2 (R. G. Cavell, R. P. Kamalesh Babu, R. McDonald, University of Alberta Structure Report RGC9802) will be published elsewhere.
33. Editorial note: The structure of 2 was recently published: C M. Ong, D. W. Stephan, J. Am. Chem. Soc. 1999, 121, 2939-2940.