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2-hybridized nitrogen atoms, especially when the N atom is part of an aromatic system, have an extensive coordination chemistry, in particular when they are multidentate ligands. In contrast to the phosphorous atom, the nitrogen atom has no low-lying d orbitals available, so that nitrogen-containing ligands have only σ-donor (and no π-acceptor) properties. Therefore, the metal-nitrogen bond has a more pronounced ionic character than the metalphosphorous bond. Furthermore, as M-N bonds are more affected by steric effects than M-P bonds, stable complexes with nitrogen-containing ligands can be expected for multidentate ligands making use of the chelating effect.
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