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38349158894
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N̂N, 1-Me-imidazol-2-yl)2CH2 (1a, mim)2CH2, 1-Me-imidazol-2-yl)2CH(C 6H13, 1b, mim)2CH(n-hexyl, 1,1'-di(triphenylmethyl)-4,4'-biimidazole (1c, biTim, 5-Me-pyridin-2-yl)2CH2 (1d, 5-Mepy) 2CH2, pyrazol-1-yl)2CH2 (1e, pz)2CH2, 3,5-Me2-pyrazol-1-yl) 2CH2 (1f, 3,5-Me2-Pz) 2CH2, 4-Me-C6H4)N=CMeCMe=N(4-Me- C6H4, 1g, p-tolyldiimine, and (2,6- iPr2-C6H3)N=CMeCMe=N(2,6- iPr2-C6H3, 1 h, 2,6- iPr2-diimine, 1-Me-imidazol-2-yl)2CH(CH(4- MeC6H4)2, 1i, mim)2CHCH
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24
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0031011962
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2O): Mock, C.; Puscasu, I.; Rauterkus, M. J.; Geshe, T.; Wolff, J. E. A.; Krebs, B. Inorg. Chim. Acta 2001, 319, 109.
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31
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0348133576
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2Pd(salicylaldehydate): Sánchez, G.; Serrano, J. L.; Pérez, J.; Ramirez de Arellano, M. C.; Lopez, G.; Molins, E. Inorg. Chim. Acta 1999, 295, 136.
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32
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38349141768
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For 1i,n,o,q, complexes 4i,n,o,q; this work.
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(d) For 1i,n,o,q, complexes 4i,n,o,q; this work.
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33
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38349151135
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MMFF. Titan, version 1.0.5; Wavefunction, Inc, San Diego, 2000
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MMFF. Titan, version 1.0.5; Wavefunction, Inc.: San Diego, 2000.
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34
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38349137621
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n,A).
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n,A).
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35
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4544385181
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(a) Camacho, D. H.; Salo, E. V.; Ziller, J. W.; Guan, Z. Angew. Chem., Int. Ed. 2004, 43, 1821.
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Camacho, D.H.1
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39
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33751385318
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Rülke, R. E.; Ernsting, J. M.; Spek, A. L.; Elsevier, C. J.; van Leeuwen, P. W. N. M.; Vrieze, K. Inorg. Chem. 1993, 32, 5769.
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44
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38349084928
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Data for free NMe2Ph: 1H NMR (CD 2Cl2, δ 7.20 (m, 2H, o-Ph, 6.72 (m, 2H, m-Ph, 6.67 (t, J, 7, 1H, p-Ph, 3.03 (s, 6H, Me, 13C{1H) NMR (CD2Cl2, δ 151.1 (C1, 129.3 (C2, 116.6 (C4, 112.8 (C3, 40.7 (Me, 1H NMR (CD 2Cl2, 60 °C, δ 7.18 (m, 2H, o-Ph, 6.67 (m, 2H, m-Ph, 6.63 (t, J, 7, 1H, p-Ph, 2.88 (s, 6H, Me, 13C{ 1H} NMR (CD2Cl2, 60 °C, δ 150.2 (C1, 128.7 (C2, 115.8 (C4, 111.9 (C3, 40.3 (Me, b) If excess [HNMe 2Ph][B(C6F5)4] is used in the generation of 5i and 5j, and the NMe2Ph is then displaced from 5i and 5j by another ligand, the excess HNMe 2Ph+ undergoes fast H+ exchange with NMe 2Ph and a single set of NMe2Ph
-
+ resonances at the weighted average of the chemical shifts of these species is observed.
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