[Cp*(η2-bipy)(MeCN)RuII][PF6] Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic [Cp*(η2-bipy)-(η3-allyl)Ru IV][PF6]2 Intermediates

Angewandte Chemie - International Edition

Volumn 42, Issue 41, 2003, Pages 5066-5068

  Mbaye, Mbaye D ^a   Demerseman, Bernard ^a   Renaud, Jean Luc ^a   Toupet, Loïc ^a   Bruneau, Christian ^a  

^a UNIVERSITÉ DE RENNES 1   (France)

Author keywords

Allyl complexes; Homogeneous catalysis; Ligand effects; N ligands; Ruthenium

Indexed keywords

COMPLEXATION; COORDINATION REACTIONS; DERIVATIVES; SUBSTITUTION REACTIONS;

REGIOSELECTIVITY;

CATALYST SELECTIVITY;

ALLYL COMPOUND; CATION; LIGAND; RUTHENIUM DERIVATIVE; ORGANOMETALLIC COMPOUND; RUTHENIUM;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; COLOR; COMPLEX FORMATION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY;

ALLYL COMPOUNDS; CATALYSIS; LIGANDS; MODELS, CHEMICAL; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; RUTHENIUM;

EID: 0242354877     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200352257     Document Type: Article

References (12)

1. a) Y. Morisaki, T. Kondo, T. Mitsudo. Organometallics 1999, 18, 4742-4746;
2. b) T. Kondo, Y. Morisaki, S. Uenoyama, K. Wada, T. Mitsudo, J. Am. Chem. Soc. 1999, 121, 8657-8658;
3. c) T. Kondo, H. Ono, N. Satabe, T. Mitsudo, Y. Watanabe, Organometallics 1995, 14, 1945-1953.
4. B. M. Trost, P. L. Fraisse, Z. T. Ball, Angew. Chem. 2002, 114, 1101-1103; Angew. Chem. Int. Ed. 2002, 41, 1059-1061.
5. B. M. Trost, P. L. Fraisse, Z. T. Ball, Angew. Chem. 2002, 114, 1101-1103; Angew. Chem. Int. Ed. 2002, 41, 1059-1061.
6. a) H. Kondo, Y. Yamaguchi, H. Nagashima, Chem. Commun. 2000, 1075-1076;
7. b) E. Rüba, W. Simanko, K. Mauthner, K. M. Soldouzi, C. Slugovc, K. Mereiter, R. Schmid, K. Kirchner, Organometallics 1999, 18, 3843-3850.
8. J.-L. Renaud, C. Bruneau, B. Demerseman, Synlett 2003, 408-410.
9. J. Tsuji in Transition Metal Reagents and Catalysts. Innovations in Organic Synthesis, Wiley, Chichester, 2000, pp. 109-168.
10. 2=1.011. CCDC-213659 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
11. G. A. Balavoine, T. Boyer, C. Livage, Organometallics 1992, 11, 456-459.
12. An example was recently reported in reference [3a].