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In spite of the inert nitrogen atmosphere purge, the mass composition is observed to increase by ∼2% during the heating from 415 to 600 °C. This effect is reproducible and is only observed in PS-b-PFEMS samples.
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In spite of the inert nitrogen atmosphere purge, the mass composition is observed to increase by ∼2% during the heating from 415 to 600 °C. This effect is reproducible and is only observed in PS-b-PFEMS samples.
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50
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On the basis of carbon nanotube (CNT) growth studies, we assume that the iron nanoparticle diameter is similar to that of the CNTs and therefore <1 nm. Please see: Lastella, S.; Mallick, G.; Woo, R.; Karna, S. P.; Rider, D. A.; Manners, I.; Jung, Y. J.; Ryu, C. Y.; Ajayan, P. M. Influences of Organometallic Polymer-Derived Catalyst Dispersion on SWNT Growth. J. Polym. Sci. B: Polym. Phys. 2007, 45, 758-765.
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On the basis of carbon nanotube (CNT) growth studies, we assume that the iron nanoparticle diameter is similar to that of the CNTs and therefore <1 nm. Please see: Lastella, S.; Mallick, G.; Woo, R.; Karna, S. P.; Rider, D. A.; Manners, I.; Jung, Y. J.; Ryu, C. Y.; Ajayan, P. M. Influences of Organometallic Polymer-Derived Catalyst Dispersion on SWNT Growth. J. Polym. Sci. B: Polym. Phys. 2007, 45, 758-765.
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Polystyrene is known to undergo both chain scission and cross-linking pathways when exposed to UV light. In our case, the dominant pathway was determined to be the latter, as the UV-exposed PS-b-PFEMS films were found to be stable to dissolution in various solvents. See: Rånby, B, Rabek, J. F. Photodegradation, Photo-oxidation and Photostabilization of Polymers; Wiley: New York NY, 1975
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Polystyrene is known to undergo both chain scission and cross-linking pathways when exposed to UV light. In our case, the dominant pathway was determined to be the latter, as the UV-exposed PS-b-PFEMS films were found to be stable to dissolution in various solvents. See: Rånby, B.; Rabek, J. F. Photodegradation, Photo-oxidation and Photostabilization of Polymers; Wiley: New York NY, 1975.
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Wang, X.; Liu, K.; Arsenault, A. C.; Rider, D. A.; Ozin, G. A.; Winnik, M. A.; Manners, I. Shell-Cross-Linked Cylindrical Polyisoprene-b-Polyferrocenylsilane (PI-b-PFS) Block Copolymer Micelles: One-Dimensional (1D) Organometallic Nanocylinders. J. Am. Chem. Soc. 2007, 129, 5630-5639.
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