Periodic organic-organometallic microdomain structures in poly(styrene-block-ferrocenyldimethylsilane) copolymers and blends with corresponding homopolymers

Journal of Polymer Science, Part B: Polymer Physics

Volumn 37, Issue 10, 1999, Pages 1009-1021

  Lammertink, Rob G H ^a   Hempenius, Mark A ^a   Thomas, Edwin L ^b   Vancso, G Julius ^a  

^a UNIVERSITY OF TWENTE   (Netherlands)

^b Massachusetts Institute of Technology Cambridge   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANIONIC POLYMERIZATION; METALLORGANIC POLYMERS; MORPHOLOGY; PHASE DIAGRAMS; PHASE SEPARATION; POLYMER BLENDS; POLYSTYRENES; RHEOLOGY; TRANSMISSION ELECTRON MICROSCOPY; X RAY SCATTERING;

POLYSTYRENE BLOCK FERROCENYLDIMETHYLSILANE COPOLYMERS; SMALL ANGLE X RAY SCATTERING (SAXS);

BLOCK COPOLYMERS;

EID: 0032653471     PISSN: 08876266     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0488(19990515)37:10<1009::AID-POLB6>3.0.CO;2-W     Document Type: Article

References (55)

1. Foucher, D. A.; Tang, B. Z.; Manners, I. J Am Chem Soc 1992, 114, 6246.
2. (a) Foucher, D. A.; Ziembinski, R.; Tang, B. Z.; Macdonald, P. M.; Massey, J.; Jaeger, C. R.; Vancso, G. J.; Manners, I. Macromolecules 1993, 26, 2878
3. (b) Foucher, D. A.; Edwards, M.; Burrow, R. A.; Lough, A. J.; Manners, I. Organometallics 1994, 13, 4959
4. Nelson, J. M.; Lough, A. J.; Manners, I. Angew Chem Int Ed Engl 1994, 33, 989
5. Pudelski, J. K.; Rulkens, R.; Foucher, D. A.; Lough, A. J.; Macdonald, P. M.; Manners, I. Macromolecules 1995, 28, 7301.
6. Foucher, D. A.; Honeyman, C. H.; Nelson, J. M.; Tang, B. Z.; Manners, I. Angew Chem Int Ed Engl 1993, 32, 1709.
7. Tang, B. Z.; Petersen, R.; Foucher, D. A.; Lough, A.; Coombs, N.; Sodhi, R.; Manners, I. J Chem Soc Chem Commun 1993, 523.
8. Rasburn, J.; Petersen, R.; Jahr, T.; Rulkens, R.; Manners, I.; Vancso, G. J. Chem Mater 1995, 7, 871.
9. (a) Rulkens, R.; Ni, Y.; Manners, I. J Am Chem Soc 1994, 116, 12121
10. (b) Rulkens, R.; Lough, A. J.; Manners, I. J Am Chem Soc 1994, 116, 797.
11. (a) Ni, Y.; Rulkens, R.; Pudelski, J. K.; Manners, I. Macromol Rapid Commun 1995, 16, 637;
12. (b) Gómez-Elipe, P.; Macdonald, P. M.; Manners, I. Angew Chem Int Ed Engl 1997, 36, 762.
13. Ni, Y.; Rulkens, R.; Manners, I. J Am Chem Soc 1996, 118, 4102.
14. Lammertink, R. G. H.; Versteeg, D. H.; Hempenius, M. A.; Vancso, G. J. J Polym Sci Part A Polym Chem 1998, 36, 2147.
15. Bates, F. S.; Rosedale, J. H.; Fredrickson, G. H. J Chem Phys 1990, 92, 6255.
16. Almdal, K.; Koppi, K. A.; Bates, F. S.; Mortensen, K. Macromolecules 1992, 25, 1743.
17. Hajduk, D. A.; Harper, P. E.; Grüner, S. M.; Honeker, C. C.; Kim, G.; Thomas, E. L.; Fetters, L. J. Macromolecules 1994, 27, 4063.
18. Förster, S.; Khandpur, A. K.; Zhao, J.; Bates, F. S.; Hamley, I. W.; Ryan, A. J.; Bras, W. Macromolecules 1994, 27, 6922.
19. Khandpur, A. K.; Förster, S.; Bates, F. S.; Hamley, I. W.; Ryan, A. J.; Bras, W.; Almdal, K.; Mortensen, K. Macromolecules 1995, 28, 8796.
20. Schulz, M. F.; Khandpur, A. K; Bates, F. S.; Almdal, K.; Mortensen, K.; Hajduk, D. A.; Grüner, S. M. Macromolecules 1996, 29, 2857.
21. Hajduk, D. A.; Takenouchi, H.; Hillmyer, M. A.; Bates, F. S.; Vigild, M. E.; Almdal, K. Macromolecules 1997, 30, 3788.
22. Helfand, E. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science: New York, 1982, vol. 1.
23. Vavasour, J. D.; Whitmore, M. D. Macromolecules 1993, 26, 7070.
24. Matsen, M. W.; Schick, M. Macromolecules 1994, 27, 4014.
25. Hasegawa, H.; Tanaka, H.; Yamasaki, K.; Hashimoto, T. Macromolecules 1987, 20, 1651.
26. Pochan, D. J.; Gido, S. P.; Zhou, J.; Mays, J. W.; Whitmore, M.; Ryan, A. J. J Polym Sci Part B Polym Phys 1997, 35, 2629.
27. Whitmore, M. D.; Noolandi, J. Macromolecules 1985, 18, 2486.
28. Matsen, M. W. Macromolecules 1995, 28, 5765.
29. Xi, H.; Milner, S. T. Macromolecules 1996, 29, 2404.
30. 25.' Likhtman, A. E.; Semenov, A. N. Macromolecules 1997, 30, 7273.
31. Janert, P. K.; Schick, M. Macromolecules 1998, 31, 1109; note that the definition of a by these authors (AT^/A^) is half the value it would have according to our definition (NAihomJNAd-Mock) because a symmetric diblock (f = 0.5) was assumed. We prefer to use our definition because asymmetric diblocks are used in the blends in our study.
32. Roe, R. J.; Zin, W. C. Macromolecules 1984, 17, 189.
33. Kinning, D. J.; Winey, K. I.; Thomas, E. L. Macromolecules 1988, 21, 3502.
34. Hashimoto, T.; Tanaka, H.; Hasegawa, H. Macromolecules 1990, 23, 4378.
35. Tanaka, H.; Hasegawa, H.; Hashimoto, T. Macromolecules 1991, 24, 240.
36. Tanaka, H.; Hashimoto, T. Macromolecules 1991, 24, 5398.
37. Winey, K. I.; Thomas, E. L.; Fetters, L. J. J Chem Phys 1991, 95, 9367.
38. Winey, K. L; Thomas, E. L.; Fetters, L. J. Macromolecules 1991, 24, 6182.
39. Winey, K. I.; Thomas, E. L.; Fetters, L. J. Macromolecules 1992, 25, 422.
40. Winey, K. L; Thomas, E. L.; Fetters, L. J. Macromolecules 1992, 25, 2645.
41. Spontak, R. J.; Smith, S. D.; Ashraf, A. Macromolecules 1993, 26, 956.
42. Disko, M. M.; Liang, K. S.; Behal, S. K.; Roe, R. J.; Jeon, K. J. Macromolecules 1993, 26, 2983.
43. Jeon, K. J.; Roe, R. J. Macromolecules 1994, 27, 2439.
44. Lammertink, R. G. H.; Hempenius, M. A.; Mariners, L; Vancso, G. J. Macromolecules 1998, 31, 795.
45. Lammertink, R. G. H.; Hempenius, M. A.; Vancso, G. J. Macromol Chem Phys 1998, 199, 2141.
46. Ficher, A. B.; Kinney, J. B.; Staley, R. H.; Wrighton, M. S. J Am Chem Soc 1979, 101, 6501.
47. Classe, M. D. Prog Polym Sci 1983, 9, 133.
48. Ferry, J. D. Viscoelastic Properties of Polymers; Wiley: New York, 1980, 3rd éd.
49. Chung, G. I.; Gale, J. C. J Polym Sci Part B Polym Phys 1976, 14, 1149.
50. Gouinlock, E. V.; Porter, R. S. Polym Eng Sci 1977, 17, 535.
51. Chung, C. I.; Lin, M. I. J Polym Sci Part B Polym Phys 1978, 16, 545.
52. Chung, C. I.; Griesbach, H. L.; Young, L. J Polym Sci Part B Polym Phys 1980, 18, 1237.
53. Bâtes, F. S. Macromolecules 1984, 17, 2607.
54. Winey, K. I.; Gobran, D. A.; Xu, Z.; Fetters, L. J.; Thomas, E. L. Macromolecules 1994, 27, 2392.
55. Ohta, T.; Kawasaki, K. Macromolecules 1986, 19, 2621.