Poly(ferrocenylsilanes): Novel organometallic plastics

Chemical Communications

Volumn , Issue 10, 1999, Pages 857-865

  Manners, Ian ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

COPOLYMER; FERROCENE; ORGANOMETALLIC COMPOUND; PLASTIC; SILANE DERIVATIVE; SILICON;

ARCHITECTURE; CHEMICAL STRUCTURE; ENVIRONMENTAL TEMPERATURE; MACROMOLECULE; METHODOLOGY; MOLECULAR WEIGHT; OXIDATION REDUCTION REACTION; POLYMERIZATION; REVIEW;

EID: 0033591237     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a810043h     Document Type: Review

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31. A few months prior to the publication of ref. 10, Rauchfuss and coworkers reported an atom-abstraction ROP route to poly(ferrocenes) with disulfido spacers. See: P. F. Brandt and T. B. Rauchfuss, J. Am. Chem. Soc., 1992, 114, 1926. For other, recent ROP routes to poly(ferrocenes) see, C. E. Stanton, T. R. Lee, R. H. Grubbs, N. S. Lewis, J. K. Pudelski, M. R. Callstrom, M. S. Erickson and M. L. McLaughlin, Macromolecules, 1995, 28, 8713; R. W. Heo, F. B. Somoza and T. R. Lee, J. Am. Chem. Soc., 1998, 120, 1621; M. A. Buretea and T. D. Tilley, Organometallics, 1997, 16, 1507.
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34. A few months prior to the publication of ref. 10, Rauchfuss and coworkers reported an atom-abstraction ROP route to poly(ferrocenes) with disulfido spacers. See: P. F. Brandt and T. B. Rauchfuss, J. Am. Chem. Soc., 1992, 114, 1926. For other, recent ROP routes to poly(ferrocenes) see, C. E. Stanton, T. R. Lee, R. H. Grubbs, N. S. Lewis, J. K. Pudelski, M. R. Callstrom, M. S. Erickson and M. L. McLaughlin, Macromolecules, 1995, 28, 8713; R. W. Heo, F. B. Somoza and T. R. Lee, J. Am. Chem. Soc., 1998, 120, 1621; M. A. Buretea and T. D. Tilley, Organometallics, 1997, 16, 1507.
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37. n < 7000) poly(ferrocenylsilanes) see: H. Rosenberg, M. D. Rausch, US Pat., 3 060 215, 1962; H. Rosenberg, US Pat., 3 426 053, 1969; for a discussion of related work including an unsuccessful attempt to induce the anionic ROP of a phosphorus-bridged [1]ferrocenophane in 1982, see ref. 11.
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56. S. Barlow, A. L. Rohl, S. Shi, C. M. Freeman and D. O'Hare, J. Am. Chem. Soc., 1996, 118, 7578.
57. R. Rulkens, A. J. Lough, I. Manners, S. R. Lovelace, C. Grant, and W. E. Geiger, J. Am. Chem. Soc., 1996, 118, 12 683.
58. D. H. Reneker and I. Chun, Nanotechnology, 1996, 7, 216.
59. F. Jäkle, R. Rulkens, G. Zech, D. A. Foucher, A. J. Lough and I. Manners, Chem. Eur. J., 1998, 4, 2117.
60. R. Rulkens, R. Resendes, A. Verma, I. Manners, K. Murti, E. Fossum, P. Miller and K. Matyjaszewski, Macromolecules, 1997, 30, 8165.
61. D. A. Foucher, R. Ziembinski, R. Rulkens, J. M. Nelson and I. Manners, in Inorganic and Organometallic Polymers II, ed. P. Wisian-Neilson, H. R. Allcock and K. J. Wynne, American Chemical Society, Washington, DC, 1994, ACS Symposium Series 572.
62. H. Yim, M. D. Foster, D. Balaishis and I. Manners, Langmuir, 1998, 14, 3921.
63. M. T. Nguyen, A. F. Diaz, V. V. Dement'ev and K. H. Pannell, Chem. Mater., 1994, 6, 952.
64. K. H. Pannell and J. Robillard, US Pat., 308856, 1994.
65. B.-Z. Tang, R. Petersen, D. A. Foucher, A. J. Lough, N. Coombs, R. Sodhi and I. Manners, J. Chem. Soc., Chem. Commun., 1993, 6, 523; R. Petersen, D. A. Foucher, B.-Z. Tang, A. J. Lough, N. P. Raju, J. E. Greedan and I. Manners, Chem. Mater., 1995, 7, 2045.
66. B.-Z. Tang, R. Petersen, D. A. Foucher, A. J. Lough, N. Coombs, R. Sodhi and I. Manners, J. Chem. Soc., Chem. Commun., 1993, 6, 523; R. Petersen, D. A. Foucher, B.-Z. Tang, A. J. Lough, N. P. Raju, J. E. Greedan and I. Manners, Chem. Mater., 1995, 7, 2045.
67. M. Hmyene, A. Yasser, M. Escorne, A. Percheron-Guegan and F. Garnier, Adv. Mater., 1994, 6, 564.
68. J. M. Nelson, P. Nguyen, R. Petersen, H. Rengel, P. M. Macdonald, A. J. Lough, I. Manners, N. P. Raju, J. E. Greedan, S. Barlow and D. O'Hare, Chem. Eur. J., 1997, 3, 573.
69. X.-H. Liu, D. W. Bruce and I. Manners, Chem. Commun., 1997, 289.
70. K. C. Hultzsch, J. M. Nelson, A. J. Lough and I. Manners, Organometallics, 1995, 14, 5496.
71. R. Rulkens, Y. Ni and I. Manners, J. Am. Chem. Soc., 1994, 116, 12 121.
72. Y. Ni, R. Rulkens and I. Manners, J. Am. Chem. Soc., 1996, 118, 4102.
73. Y. Ni, R. Rulkens, J. K. Pudelski and I. Manners, Macromol. Rapid Commun., 1995, 16, 637.
74. N. P. Reddy, H. Yamashita and M. Tanaka, J. Chem. Soc., Chem. Commun., 1995, 2263.
75. J. B. Sheridan, K. Temple, A. J. Lough and I. Manners, J. Chem. Soc., Dalton Trans., 1997, 711.
76. P. Gómez-Elipe, P. M. Macdonald and I. Manners, Angew. Chem., Int. Ed. Engl., 1997, 36, 762.
77. P. Gómez-Elipe, R. Resendes, P. M. Macdonald and I. Manners, J. Am. Chem. Soc., 1998, 120, 8348.
78. M. J. MacLachlan, P. Aroca, N. Coombs, I. Manners and G. A. Ozin, Adv. Mater., 1998, 10, 144.
79. F. S. Bates, Science, 1991, 251, 898; S. F̈orster and M. Antonietti, Adv. Mater., 1998, 10, 195.
80. F. S. Bates, Science, 1991, 251, 898; S. F̈orster and M. Antonietti, Adv. Mater., 1998, 10, 195.
81. J. Massey, K. N. Power, M. A. Winnik and I. Manners, Adv. Mater., 1998, 10, 1559.
82. I. Manners, Can. J. Chem., 1998, 76, 378.
83. R. G. H. Lammertink, D. J. Versteeg, M. A. Hempenius and G. J. Vancso, J. Polym. Sci. Part A: Polym. Chem., 1998, 36, 2147.
84. For recent work on non-spherical micellar aggregates of organic block copolymers in solution see, for example, C. Price, Pure Appl. Chem., 1983, 55, 1563; M. Antonietti, S. Heinz, M. Schimdt and C. Rosenauer, Macromolecules, 1994, 27, 3276; L. Zhang and A. Eisenberg, Science, 1995, 268, 1728; L. Zhang, K. Yu and A. Eisenberg, Science, 1996, 272, 1777; J. P. Spatz, S. Mößmer and M. Möller, Angew. Chem., Int. Ed. Engl., 1996, 35, 1510.
85. For recent work on non-spherical micellar aggregates of organic block copolymers in solution see, for example, C. Price, Pure Appl. Chem., 1983, 55, 1563; M. Antonietti, S. Heinz, M. Schimdt and C. Rosenauer, Macromolecules, 1994, 27, 3276; L. Zhang and A. Eisenberg, Science, 1995, 268, 1728; L. Zhang, K. Yu and A. Eisenberg, Science, 1996, 272, 1777; J. P. Spatz, S. Mößmer and M. Möller, Angew. Chem., Int. Ed. Engl., 1996, 35, 1510.
86. For recent work on non-spherical micellar aggregates of organic block copolymers in solution see, for example, C. Price, Pure Appl. Chem., 1983, 55, 1563; M. Antonietti, S. Heinz, M. Schimdt and C. Rosenauer, Macromolecules, 1994, 27, 3276; L. Zhang and A. Eisenberg, Science, 1995, 268, 1728; L. Zhang, K. Yu and A. Eisenberg, Science, 1996, 272, 1777; J. P. Spatz, S. Mößmer and M. Möller, Angew. Chem., Int. Ed. Engl., 1996, 35, 1510.
87. For recent work on non-spherical micellar aggregates of organic block copolymers in solution see, for example, C. Price, Pure Appl. Chem., 1983, 55, 1563; M. Antonietti, S. Heinz, M. Schimdt and C. Rosenauer, Macromolecules, 1994, 27, 3276; L. Zhang and A. Eisenberg, Science, 1995, 268, 1728; L. Zhang, K. Yu and A. Eisenberg, Science, 1996, 272, 1777; J. P. Spatz, S. Mößmer and M. Möller, Angew. Chem., Int. Ed. Engl., 1996, 35, 1510.
88. For recent work on non-spherical micellar aggregates of organic block copolymers in solution see, for example, C. Price, Pure Appl. Chem., 1983, 55, 1563; M. Antonietti, S. Heinz, M. Schimdt and C. Rosenauer, Macromolecules, 1994, 27, 3276; L. Zhang and A. Eisenberg, Science, 1995, 268, 1728; L. Zhang, K. Yu and A. Eisenberg, Science, 1996, 272, 1777; J. P. Spatz, S. Mößmer and M. Möller, Angew. Chem., Int. Ed. Engl., 1996, 35, 1510.
89. J. Massey, K. N. Power, I. Manners and M. A. Winnik, J. Am. Chem. Soc., 1998, 120, 9533.
90. J. P. Spatz, S. Mößmer, M. Möller, T. Herzog, A. Plettl and P. Ziemann, J. Luminesc., 1998, 76/77, 168.