Spontaneous vertical ordering and pyrolytic formation of nanoscopic ceramic patterns from poly(styrene-b-ferrocenylsilane)

Advanced Materials

Volumn 15, Issue 4, 2003, Pages 297-300

  Temple, Karen ^a   Kulbaba, Kevin ^a   Power Billard, K Nicole ^a   Manners, Ian ^a   Leach, K Amanda ^b   Xu, Ting ^b   Russell, Thomas P ^b   Hawker, Craig J ^c  

^a UNIVERSITY OF TORONTO   (Canada)

^b UNIVERSITY OF MASSACHUSETTS   (United States)

^c IBM ALMADEN RESEARCH CENTER   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANNEALING; ATOMIC FORCE MICROSCOPY; BLOCK COPOLYMERS; CERAMIC MATERIALS; FUNCTIONAL POLYMERS; NANOSTRUCTURED MATERIALS; PYROLYSIS; RING OPENING POLYMERIZATION; SPIN COATING; THICKNESS MEASUREMENT; TRANSMISSION ELECTRON MICROSCOPY; X RAY ANALYSIS;

POLYFERROCENE; POLYSTYRENE FERROCENYLSILANE; SEQUENTIAL ANIONIC RING OPENING POLYMERIZATION; SMALL ANGLE X RAY SCATTERING; VERTICAL ORDERING;

POLYSTYRENES;

EID: 0037450280     PISSN: 09359648     EISSN: None     Source Type: Journal    
DOI: 10.1002/adma.200390071     Document Type: Article

References (42)

1. a) M. Park, C. Harrison, P. M. Chaikin, R. Register, D.H. Adamson, Science 1997, 276, 1401.
2. b) C. Harrison, M. Park, P. Chaikin, R. Register, D. H. Adamson, N. Yao, Macromolecules 1998, 31, 2185.
3. a) M. Muthukumar, C. K. Ober, E. L. Thomas, Science 1997, 277, 1225.
4. b) A. Urbas, R. Sharp, Y. Fink, E. L. Thomas, M. Xeindou, L. J. Fetters, Adv. Mater. 2000, 12, 812.
5. L. Bronstein, E. Krämer, B. Berton, C. Burger, S. Förster, M. Antonietti, Chem. Mater. 1999, 11, 1402.
6. a) H. Shen, A. Eisenberg, Angew. Chem. Int. Ed. 2000, 39, 3310
7. b) L. Zhang, K. Kui, A. Eisenberg, Science, 1996, 272, 1777
8. c) G. Liu, J. Ding, Adv. Mater. 1998, 10, 69.
9. V. Z.-H. Chan, J. Hoffman, V. Y. Lee, H. Iatrou, A. Avgeropoulos, N. Hadjichristidis, R. D. Miller, E. L. Thomas, Science 1999, 286, 1716.
10. F. S. Bates, Science 1991, 251, 898.
11. a) H.-C. Kim, X. Jia, C. M. Stafford, D. H. Kim, T. J. McCarthy, C. J. Tuominen, C. J. Hawker, T. P. Russell, Adv. Mater. 2001, 13, 795.
12. b) T. Thurn-Albrecht, R. Steiner, J. DeRouchey, C. M. Stafford, E. Huang, M. Bal, M. Tuominen, C. J. Hawker, T. P. Russell Adv. Mater. 2000, 12, 787.
13. K. Shin, M. H. Rafailovich, J. Sokolov, D. M. Chang, J. K. Cox, R. B. Lennox, A. Eisenberg, A. Gibaud, J. Huang, S. L. Hsu, S. K. Satija, Langmuir 2001, 17, 4955.
14. M. Templin, A. Franck, A. Du Chesne, H. Leist, Y. Zhang, R. Ulrich, V. Schäler, U. Wiesner, Science 1997, 278, 1795.
15. M. Antonietti, C. Göltner, Angew. Chem. Int. Ed. Engl. 1997, 36, 911.
16. a) D. G. Walton, G. J. Kellogg, A. M. Mayers, P. Lambooy, T. P. Russell, Macromolecules 1994, 27, 6225.
17. b) M. J. Fasolka, P. Banerjee, A. M. Mayers, G. Pickett, A. C. Balazs, Macromolecules 2000, 33, 5702.
18. L. Rockford, S. G. J. Mochrie, T. P. Russell, Macromolecules 2001, 34, 1487.
19. T. L. Morkved, M. Lu, A. M. Urbas, E. E. Ehrichs, H. M. Jaeger, P. Mansky, T. P. Russell, Science 1996, 273, 931.
20. a) E. Huang, T. P. Russell, C. Harrison, P. M. Chaikin, R. Register, C. J. Hawker, J. Mays, Macromolecules 1998, 31, 7641.
21. b) X. M. Yang, R. D. Peters, P. F. Nealey, H. H. Solak, F. Cerrina, Macromolecules 2000, 33, 9575.
22. I. Manners, Science 2001, 294, 1664.
23. a) J. A. Massey, K. N. Power, M. A. Winnik, I. Manners, Adv. Mater. 1998, 10, 1559.
24. b) J. Y. Cheng, C. A. Ross, V. Z.-H. Chan, E. L. Thomas, R. G. H. Lammertink, G. J. Vancso, Adv. Mater. 2001, 13, 1174.
25. c) J. A. Massey, M. A. Winnik, I. Manners, V. Z.-H. Chan, J. M. Ostermann, R. Enchelmaier, J. P. Spatz, M. Möller, J. Am. Chem. Soc. 2001, 123, 3147.
26. d) C. Park, J. E. McAlvin, C. Fraser, E. L. Thomas, Chem. Mater. 2002, 14, 1225.
27. e) J. F. Gohy, B. G. G. Lohmeijer, S. K. Varshney, U. S. Schubert, Macromolecules 2002, 35, 7427.
28. Y. Ni, R. Rulkens, I. Manners, J. Am. Chem. Soc. 1996, 118, 4102.
29. K. Temple, J. A. Massey, Z. Chen, N. Vaidya, A. Berenbaum, M. D. Foster, I. Manners, J. Inorg. Organomet. Polym. 1999, 9, 189.
30. W. Li, N. Sheller, M. D. Foster, D. Balaishis, I. Manners, I. Annis, J. S. Lin, Polymer 2000, 41, 719.
31. J. A. Massey, K. Temple, L. Cao, Y. Rharbi, J. Raez, M. A. Winnik, I. Manners, J. Am. Chem. Soc. 2000, 122, 11577.
32. R. G. H. Lammertink, M. A. Hempenius, G. J. Vancso, K. Shin, M. H. Rafailovich, J. Sokolov, Macromolecules 2001, 34, 942.
33. R. L. Jones, S. K. Kumar, D. L. Ho, R. M. Briber, T. P. Russell, Macromolecules 2001, 34, 559.
34. The hydroxy terminated PS was prepared by living nitroxide-mediated radical polymerization, see D. Benoit, V. Chaplinski, R. Braslau, C. J. Hawker, J. Am. Chem. Soc. 1999, 121, 3904.
35. P. Mansky, Y. Liu, E. Huang, T. P. Russel, C. J. Hawker, Science 1997, 275, 1458.
36. y nanoparticles from pyrolysis of PFS homopolymers see a) R. Petersen, D. A. Foucher, B.-Z. Tang, A. Lough, N. P. Raju, J. E. Greedan, I. Manners, Chem. Mater. 1995, 2045.
37. b) M. J. McLachlan, M. Ginzburg, N. Coombs, T. W. Coyle, N. P. Raju, J. E. Greedan, G. A. Ozin, I. Manners, Science 2000, 287, 1460.
38. c) M. Ginzburg, M. J. MacLachlan, S. M. Yang, N. Coombs, T. W. Coyle, N. P. Raju, J. E. Greedan, R. H. Herber, G. A. Ozin, I. Manners, J. Am. Chem. Soc. 2002, 124, 2625.
39. Q. Sun, J. W. Y. Lam, K. Xu, H. Xu, J. A. K. Cha, P. C. L. Wong, G. Wen, X. Zhang, X. Jing, F. Wang, B. Z. Tang, Chem. Mater. 2000, 12, 2617.
40. For recent work on patterning with magnetic materials, see. S. Palacin, P. C. Hidber, J.-P. Bourgoin, C. Miramond, C. Fermon, G. M. Whitesides, Chem. Mater. 1996, 8, 1316.
41. F. R. Mayo, J. Am. Chem. Soc. 1968, 90, 1289.
42. After this manuscript was submitted, work on the formation of well-organized nanostructured carbon materials based on the carbonization of a phase separated film of a block copolymer of polyacrylonitrile and poly (n-butyl acrylate) was described, see T. Kowalewski, N. V. Tsarevsky, K. Matyjaszewski, J. Am. Chem. Soc. 2002, 124, 10 632.