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The precipitation polymerization techniques described in this paper have been extended to the synthesis of PFSMSs from fcSiMePh and the spirocyclic cross-linker 4. The resulting spherical particles had an average diameter of 1.84 μm and a PDI of 1.17 (see the Supporting Information). The fcSiMePh monomer was synthesized according to literature procedures (see ref 29).
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See the Supporting Information for solid-state NMR, reflectance UV-vis/near-IR, XPS, and PXRD data as well as SEM and TEM images for PFSMSs formed under these conditions.
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