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Recently, bi- and polycyclic cyclobutenes have been isolated using metal-catalyzed reactions from 1,6 and 1,7-enynes and allenynes: (a) Trost, B. M.; Yanai, M.; Hoogsteen, K. J. Am. Chem. Soc. 1993, 115, 5294-5295.
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Monocyclic cyclobutenes have also been obtained from the rearrangement of methylenecyclopropanes: (j) Fürstner, A.; Aissa, C. J. Am. Chem. Soc. 2006, 128, 6306-6307.
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