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Trnka, T. M.; Morgan, J. P.; Sanford, M. S.; Wilhelm, T. E.; Scholl, M.; Choi, T. L.; Ding, S.; Day, M. W.; Grubbs, R. H. J. Am. Chem. Soc. 2003, 125, 2546-2558.
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34347218289
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See Supporting Information for kinetic plots and 31P spectra after catalyst decomposition
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31P spectra after catalyst decomposition.
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25
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34347237676
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Ulman, M. Ph.D. Dissertation, California Institute of Technology, 2000.
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Ulman, M. Ph.D. Dissertation, California Institute of Technology, 2000.
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30
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34347228224
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Steady-state appromimation was applied to eq 1
-
Steady-state appromimation was applied to eq 1.
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31
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34347209473
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3.
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3.
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32
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14744269446
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2IPr ligands and the geometry is not favorable for the internal attack. For the electronic properties of N-heterocyclic carbene ligands, see: Dorta, R.; Stevens, E. D.; Scott, N. M.; Costabile, C.; Cavallo, L.; Hoff, C. D.; Nolan, S. P. J. Am. Chem. Soc. 2005, 127, 2485-2495.
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2IPr ligands and the geometry is not favorable for the internal attack. For the electronic properties of N-heterocyclic carbene ligands, see: Dorta, R.; Stevens, E. D.; Scott, N. M.; Costabile, C.; Cavallo, L.; Hoff, C. D.; Nolan, S. P. J. Am. Chem. Soc. 2005, 127, 2485-2495.
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Sanford, M. S.; Love, J. A.; Grubbs, R. H. Organometallics 2001, 20, 5314-5318.
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Sanford, M.S.1
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35
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34347268863
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Values correspond to NMR yields utilizing anthracene (0.014 M) as an internal reaction standard. Alkylidene assumed to be methylidene-derived (2H); conversion based on Ru is 66% if it is assumed that the complex is the bis-ruthenium complex 11.
-
Values correspond to NMR yields utilizing anthracene (0.014 M) as an internal reaction standard. Alkylidene assumed to be methylidene-derived (2H); conversion based on Ru is 66% if it is assumed that the complex is the bis-ruthenium complex 11.
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40
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17444414248
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Streitwieser, A.; McKeown, A. E.; Hasanayn, F.; Davis, N. R. Org. Lett. 2005, 7, 1259-1262.
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41
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34347230573
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For a mechanistic investigation on the influence of phosphine on the rate of initiation of 2, 5, and 18, see ref 23
-
For a mechanistic investigation on the influence of phosphine on the rate of initiation of 2, 5, and 18, see ref 23.
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42
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0034734340
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Garber, S. B.; Kingsbury, J. S.; Gray, B. L.; Hoveyda, A. H. J. Am. Chem. Soc. 2000, 122, 8168-8179.
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85034336744
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Love, J. A.; Morgan, J. P.; Trnka, T. M.; Grubbs, R. H. Anqew. Chem., Int. Ed. 2002, 41, 4035-4037.
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Love, J. A.; Morgan, J. P.; Trnka, T. M.; Grubbs, R. H. Anqew. Chem., Int. Ed. 2002, 41, 4035-4037.
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45
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34347264935
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California Institute of Technology, Pasadena, CA
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Unpublished work
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Hejl, A.; Grubbs, R. H. California Institute of Technology, Pasadena, CA. Unpublished work, 2006.
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Hejl, A.1
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Williams, J. E.; Harner, M. J.; Sponsler, M. B. Organometallics 2005, 24, 2013-2015.
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85152998637
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2(py)(CO) (Cl)(H)Ru. See: Werner, H.; Stüer, W.; Weberndörfer, B.; Wolf, J. Eur. J. Inorg. Chem. 1999, 1707-1713.
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2(py)(CO) (Cl)(H)Ru. See: Werner, H.; Stüer, W.; Weberndörfer, B.; Wolf, J. Eur. J. Inorg. Chem. 1999, 1707-1713.
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Schwab, P.; Grubbs, R. H.; Ziller, J. W. J. Am. Chem. Soc. 1996, 118, 100-110.
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Ziller, J.W.3
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49
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34347206066
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The alkylidene was assumed to be methylidene-derived (2H); values should be doubled when calculating conversion to 11 relative to ruthenium because it is a bimetallic species.
-
The alkylidene was assumed to be methylidene-derived (2H); values should be doubled when calculating conversion to 11 relative to ruthenium because it is a bimetallic species.
-
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50
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34347255788
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The presence of 11 has also been observed via mass spectrometry in the reaction of the bispyridyl catalyst 4 with ethylene.
-
The presence of 11 has also been observed via mass spectrometry in the reaction of the bispyridyl catalyst 4 with ethylene.
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