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There have been suggestions that this ligand may potentially bind to transition metal ions as a bis-bidentate linker, and at least a magnetic study has been reported on a nickel species that has been claimed to be a dinuclear species. However, it should be noted that this compound has not been structurally characterized. See: Duggan, D. M, Barefield, E. K, Hendrickson, D. N. Inorg. Chem. 1973, 12, 985
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There have been suggestions that this ligand may potentially bind to transition metal ions as a bis-bidentate linker, and at least a magnetic study has been reported on a nickel species that has been claimed to be a dinuclear species. However, it should be noted that this compound has not been structurally characterized. See: Duggan, D. M.; Barefield, E. K.; Hendrickson, D. N. Inorg. Chem. 1973, 12, 985.
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Crystal data for [Mo2(DAniF)3]2(C 4O4)·2{[Mo2(DAniF)3] 2(C4O4, TFPB, triclinic, space group P1, a, 18.383(2) Å, b, 19.175(2) Å, c, 30.077(4) Å, α, 106.233(6)°, β, 96.206(7)°, γ, 109.366-(7)°, V, 9365(2) Å3, Z, 1, R value [I > 2σ] R1, 0.138. In the asymmetric unit, there is a half moiety of the neutral compound 1 and an entire molecule of the singly oxidized compound, Mo2(DAniF)3] 2C4O4, TFPB, The quality of the diffraction data for this crystal was insufficient for a detailed structural analysis. However, in the singly oxidized species, the analysis unambiguously shows the existence of molecular pairs composed of two [Mo2] units and a squarate dianion. The
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2] unit in the timescale of X-ray analysis.
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It should be noted that caution should be used especially when non-innocent linkers are present in the compounds under study. This is why interpretation should always be accompanied by analysis of additional data such as those from structural, spectroscopic, or magnetic studies
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It should be noted that caution should be used especially when non-innocent linkers are present in the compounds under study. This is why interpretation should always be accompanied by analysis of additional data such as those from structural, spectroscopic, or magnetic studies.
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