Trapping tetramethoxyzincate and -cobaltate(II) between Mo24+ units

Inorganic Chemistry

Volumn 42, Issue 15, 2003, Pages 4619-4623

  Cotton, F Albert ^a   Liu, Chun Y ^a   Murillo, Carlos A ^a   Wang, Xiaoping ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT; COBALT DERIVATIVE; LIGAND; MOLYBDENUM; SULFUR; TETRAMETHOXYCOBALTATE; TETRAMETHOXYZINCATE; TUNGSTEN; UNCLASSIFIED DRUG; ZINC; ZINC DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; MAGNETISM; OXIDATION REDUCTION REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS;

EID: 0038637364     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034167f     Document Type: Article

References (42)

1. See for example: (a) Lippard, S. J.; Berg, J. M. Principles of Bioinorganic Chemistry; University Science Books: Mill Valley, CA, 1994.
2. (b) Schuster, G. B. Acc. Chem. Res. 2000, 33, 253.
3. (c) Endicott, J. F.; Kumar, K.; Ramasami, T.; Rotzinger, F. P. Prog. Inorg. Chem. 1983, 30, 141.
4. (d) Barigelletti, F.; Flamigni, L. Chem. Soc. Rev. 2000. 29, 12.
5. (e) Pletneva, E. V.; Crnogorac, M. M.; Kostic, N. M. J. Am. Chem. Soc. 2002, 124, 14342.
6. See for example: (a) Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
7. (b) Brunschwig, B. S.; Creutz, C.; Sutin, N. Chem. Soc. Rev. 2002, 31, 168.
8. (c) Demadis, K. D.; Hartshorn, C. M.; Meyer, T. J. Chem. Rev. 2001, 101, 2655.
9. (d) Chen, P.; Meyer, T. J. Chem. Rev. 1998, 98, 1439.
10. (e) Kaim, W.; Klein, A.; Gloeckle, M. Acc. Chem. Res. 2000, 33, 755.
11. (f) Ferretti, A.; Lami, A.; Murga, L. F.; Shehadi, I. A.; Ondrechen, M. J.; Villani, G. J. Am. Chem. Soc. 1999, 121, 2594.
12. Cotton, F. A.; Nocera, D. G. Acc. Chem. Res. 2000, 33, 483.
13. (a) Chisholm, M. H. J. Organomet. Chem. 2002, 641, 15.
14. (b) Bursten, B. E.; Chisholm, M. H.; Hadad, C. M.; Li, J.; Wilson, P. J. Chem. Commun. 2001, 2382.
15. (c) Bursten, B. E.; Chisholm, M. H.; Clark, R. J. H.; Firth, S.; Hadad, C. M.; MacIntosh, A. M.; Wilson, P. J.; Woodward, P. M.; Zaleski, J. M. J. Am. Chem. Soc. 2002, 124, 3050.
16. (d) Bursten, B. E.; Chisholm, M. H.; Clark, R. J. H.; Firth, S.; Hadad, C. M.; Wilson, P. J.; Woodward, P. M.; Zaleski, J. M. J. Am. Chem. Soc. 2002. 124, 12244.
17. (a) Cotton, F. A.; Lin, C.; Murillo, C. A. Acc. Chem. Res. 2001, 34, 759.
18. (b) Cotton, F. A.; Lin, C.; Murillo, C. A. Proc. Natl. Acad. Sci. U.S.A. 2002, 99, 4810.
19. Cotton, F. A.; Donahue, J. P.; Murillo, C. A. Inorg. Chem. 2001, 40, 2229.
20. Cotton, F. A.; Daniels, L. M.; Donahue, J. P.; Liu, C. Y.; Murillo, C. A. Inorg. Chem. 2002, 41, 1354.
21. Bradley, D. C.; Mehrotra, R. C.; Rothwell, I. P.; Singh, A. Alkoxo and Aryloxo Derivatives of Metals; Academic Press: New York, 2001.
22. Sheldrick, G. M. SHELXS-97. Program for crystal structure solution. Acta Crystallogr. 1990, A46, 467.
23. Sheldrick, G. M. SHELXL-97. Program for Crystal Structure Analysis; University of Göttingen: Göttingen Gerrnany, 1997.
24. Soderberg, R. H. Ph.D. Thesis, Massachusetts Institute of Technology, 1962.
25. Cotton, F. A.; Donahue, J. P.; Lin, C.; Murillo, C. A. Inorg. Chem. 2001, 40, 1234.
26. () Cotton, F. A.; Donahue, J. P.; Murillo, C. A. J. Am. Chem. Soc. 2003, 125, 5436.
27. An attempt has been made to prepare the ethoxide analogue of 1 but without complete success. The compound obtained (by method A similar to that used for 1) had a structure similar to that of 1, but it appeared that some hydrolysis had occurred so that some μ-OEt groups were replaced by μ-OH groups. This compound also had electrochemistry very similar to that of 1 with reversible oxidation processes at -192 and +42 mV versus Ag/AgCl. Satisfactory refinement of the structure was not achieved, and no further work has been done on this compound.
28. (a) Richardson, D. E.; Taube, H. Inorg. Chem. 1981, 20. 1278.
29. (b) Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
30. (a) Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry, 6th ed.; John Wiley & Sons: New York, 1999; p 814.
31. (b) Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon Press: Oxford, England, 1987; Vol. 1, p 254.
32. (a) Holm, R. H.; Cotton, F. A. J. Chem. Phys. 1959, 31, 788.
33. (b) Holm, R. H.; Cotton, F. A. J. Chem. Phys. 1960, 32, 1168.
34. (c) Cotton, F. A.; Goodgame, D. M. L.; Goodgame, M.; Sacco. A. J. Am. Chem. Soc. 1961, 83, 4157.
35. (d) Cotton, F. A.; Goodgame, D. M. L.; Goodgame, M. J. Am. Chem. Soc. 1961, 83, 4690.
36. (e) Cotton, F. A.; Soderberg, R. H. J. Am. Chem. Soc. 1962, 84, 872.
37. (a) Maret, W.; Vallee, B. L. Methods Enzymol. 1993, 226, 52.
38. (b) Landro, J. A.; Schimmel, P. Proc. Natl. Acad. Sci. U.S.A. 1993, 90, 2261.
39. (c) Auld, D. S. Method Enzymol. 1993, 226, 553.
40. (d) Brown, D. C.; Collins, K. D. J. Biol. Chem. 1991, 266, 1597.
41. (e) Schimmel, P.; Landro, J. A.; Schmidt, E. J. Biomol. Struct. Dyn. 1993, 11, 571.
42. Cotton, F. A.; Wood, J. S. Inorg. Chem. 1964, 3, 245.