Crystal structures and magnetic properties of the squarate-O1,On-bridged dinuclear copper(II) complexes [Cu2(phen)4(C4O4)](CF 3SO3)2· 3H2O (n=2) and [Cu2(bipy)4(C4O4)](CF 3SO3)2· 6H2O.

Inorganica Chimica Acta

Volumn 287, Issue 2, 1999, Pages 173-180

  Castro, Isabel ^a   Luisa Calatayud, María ^a   Sletten, Jorunn ^b   Lloret, Francesc ^a   Julve, Miguel ^a  

^a UNIVERSITY OF VALENCIA   (Spain)

^b UNIVERSITY OF BERGEN   (Norway)

Author keywords

Copper complexes; Crystal structures; Magnetic properties; Polynuclear compounds; Squarate complexes

Indexed keywords

ANTIFERROELECTRICITY; ANTIFERROMAGNETISM; ATOMS; COORDINATION REACTIONS; CRYSTAL STRUCTURE; MAGNETIC PROPERTIES; MAGNETIC SUSCEPTIBILITY; MOLECULES; NITROGEN; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL);

ANTIFERROMAGNETIC COUPLING; COPPER COMPLEXES; COPPER-COPPER SEPARATION; DINUCLEAR COPPER COMPLEXES; MAGNETIC SUSCEPTIBILITY MEASUREMENTS; POLYNUCLEAR COMPOUNDS; SINGLE CRYSTAL X-RAY DIFFRACTION; SQUARATE COMPLEXES;

COPPER COMPOUNDS;

EID: 0001038608     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(99)00011-0     Document Type: Article

References (63)

1. Cohen S., Lacher J.R., Park J.D. J. Am. Chem. Soc. 81:1959;3480.
2. (a) C. Robl, A. Weiss, Mater. Res. Bull. 22 (198) 373.
3. (b) C. Robl, V. Gnutzman, A. Weiss, Z. Anorg. Allg. Chem. 549 (1987) 187.
4. (c) C. Robl, D. Kinkeldey, Z. Naturforsch., Teil B: Chem. Sci. 45 (1990) 931.
5. Narinesingh D., Ramcharitar N., Hall L.A. Polyhedron. 13:1994;45.
6. (a) J.C. Trombe, A. Gleizes, J. Galy, C.R. Acad. Sci., Ser. 2 304 (1987) 1117.
7. (b) J.C. Trombe, J.F. Petit, A. Gleizes, New J. Chem. 12 (1988) 197.
8. (c) J.F. Petit, A. Gleizes, J.C. Trombe, Inorg. Chim. Acta 167 (1990) 51.
9. (d) J.C. Trombe, J.F. Petit, A. Gleizes, Inorg. Chim. Acta 167 (1990) 69.
10. (e) J.C. Trombe, J.F. Petit, A. Gleizes, Eur. J. Solid State Inorg. Chem. 28 (1991) 669.
11. (f) A. Bouayad, C. Brouca-Cabarrecq, J.C. Trombe, A. Gleizes, Inorg. Chim. Acta 195 (1992) 193.
12. (a) R. Soules, A. Mosset, J.P. Laurent, P. Castan, G. Bernardelli, M. Delamar, Inorg. Chim. Acta 155 (1989) 105.
13. (b) P. Castan, D. Deguenon, P.L. Fabre, G. Bernardelli, Polyhedron 11 (1992) 901.
14. (a) Q. Chen, S. Liu, J. Zubieta, Inorg. Chim. Acta 164 (1989) 115.
15. (b) Q. Chen, L. Ma, S. Liu, J. Zubieta, J. Am. Chem. Soc. 111 (1989) 5944.
16. (c) Q. Chen, S. Liu, J. Zubieta, Angew. Chem., Int. Ed. Engl. 29 (1990) 70.
17. Robl C., Weiss A. Z. Anorg. Allg. Chem. 546:1987;161.
18. (a) A. Müller, R. Rohlfing, E. Krickemeyer, H. Bögge, Angew. Chem., Int. Ed. Engl. 32 (1993) 909.
19. (b) M.I. Khan, Y.D. Chang, Q. Chen, J. Salta, Y.S. Lee, C.J. O'Connor, J. Zubieta, Inorg. Chem. 33 (1994) 6340.
20. Bang E., Michelsen K., Margrethe K., Pedersen E. Acta Chem. Scand. 43:1989;748.
21. (a) F. Lloret, M. Julve, J. Faus, X. Solans, Y. Journaux, I. Morgenstern-Badarau, Inorg. Chem. 29 (1990) 2232.
22. (b) G.M. Frankenbach, M.A. Beno, A.M. Kini, J.M. Williams, U. Welp, J.E. Thompson, M.H. Whangbo, Inorg. Chim. Acta 192 (1992) 195.
23. (c) J. Sletten, H. Daraghmeh, F. Lloret, M. Julve, Inorg. Chim. Acta 279 (1998) 127.
24. (a) I. Brach, J. Rosière, B. Anselment, K. Peters, Acta Crystallogr., Sect. C 43 (1987) 458.
25. (b) S.O.H. Gutschke, M. Molinier, A.K. Powell, P.T. Wood, Angew. Chem., Int. Ed. Engl. 36 (1997) 991.
26. (a) R. Soules, F. Dahan, J.P. Laurent, P. Castan, J. Chem. Soc., Dalton Trans. (1988) 587.
27. (b) A. Bencini, A. Bianchi, E. García-España, Y. Jeannin, M. Julve, V. Marcelino, M. Philoche-Levisalles, Inorg. Chem. 29 (1990) 263.
28. (c) I. Castro, M.L. Calatayud, J. Sletten, F. Lloret, M. Julve, J. Chem. Soc., Dalton Trans. (1997) 811.
29. (a) G. Bernardelli, D. Deguenon, R. Soules, P. Castan, Can. J. Chem. 67 (1989) 1158.
30. (b) I. Castro, J. Faus, M. Julve, M. Mollar, A. Monge, E. Gutiérrez-Puebla, Inorg. Chim. Acta 161 (1989) 97.
31. (c) X. Solans, M. Aguiló, A. Gleizes, J. Faus, M. Julve, M. Verdaguer, Inorg. Chem. 29 (1990) 775.
32. (d) M. Benetó, J. García-Lozano, E. Escrivá, J.P. Legros, F. Dahan, J. Chem. Soc., Dalton Trans. (1991) 1057.
33. (e) C.E. Xanthopoulos, M.P. Sigalas, G.A. Katsoulos, C.A. Tsipis, C.C. Hadjikostas, A. Terzis, M. Mentzafos, Inorg. Chem. 32 (1993) 3743.
34. (f) I. Castro, J. Sletten, L.K. Glærum, J. Cano, F. Lloret, J. Faus, M. Julve, J. Chem. Soc., Dalton Trans. (1995) 3207.
35. (g) I. Castro, J. Sletten, M.L. Calatayud, M. Julve, J. Cano, F. Lloret, A. Caneschi, Inorg. Chem. 34 (1995) 4903.
36. Tedesco H.P., Walton H.F. Inorg. Chem. 8:1969;932.
37. Cilindro L.G., Stadlbauer E., Keller C. J. Inorg. Nucl. Chem. 34:1972;2577.
38. Alexandersson D., Vannerberg N.G. Acta Chem. Scand. 27:1973;3499.
39. Alexandersson D., Vannerberg N.G. Acta Chem. Scand. 28:1974;423.
40. Castro I., Faus J., Julve M. Transition Met. Chem. 13:1988;455.
41. I. Castro, J. Faus, M. Julve, Y. Journaux, J. Sletten, J. Chem. Soc., Dalton Trans. (1991) 2533.
42. Sisley M.J., Jordan R.B. Inorg. Chem. 30:1991;2190.
43. Habenchuss M., Gerstein B.C. J. Chem. Phys. 61:1974;852.
44. van Ooijen J.A.C., Reedijk J., Spek A.L. Inorg. Chem. 18:1979;1184.
45. Reinprecht J.T., Miller J.G., Vogel G.C., Haddad M.S., Hendrickson D.N. Inorg. Chem. 19:1980;927.
46. Earnshaw A. Introduction to Magnetochemistry. 1968;Academic Press, London.
47. North A.C.T., Phillips D.C., Mathews F.S. Acta Crystallogr., Sect. A. 24:1968;351.
48. Kopfman G., Huber R. Acta Crystallogr., Sect. A. 24:1968;348.
49. K. Harms, Philipps-Universität Marburg, Fachbereich Chemie, Germany.
50. Sheldrick G.M. Acta Crystallogr., Sect. A. 46:1990;467.
51. G.M. Sheldrick, SHELXL-93, Sheldrick, University of Göttingen, Germany, 1993.
52. G.M. Sheldrick, SHELXL-PLUS, Version 4.21, Siemens Analytical X-Ray Instruments Inc., Madison, WI, 1990.
53. G. Murphy, P. Nagle, B. Murphy, B. Hathaway, J. Chem. Soc., Dalton Trans. (1997) 2645.
54. G. Murphy, P. Nagle, B. Murphy, B. Hathaway, J. Chem. Soc., Dalton Trans. (1997) 2653.
55. I.M. Procter, B.J. Hathaway, P. Nicholls, J. Chem. Soc. (1968) 1678.
56. W.D. Harrison, D.M. Kennedy, M. Power, R. Sheahan, B.J. Hathaway, J. Chem. Soc., Dalton Trans. (1981) 1556.
57. P. Nagle, E. O'Sullivan, B.J. Hathaway, E. Muller, J. Chem. Soc., Dalton Trans. (1990) 3399.
58. Merrit L.L., Schroeder E.D. Acta Crystallogr. 9:1956;801.
59. Lawrance G.A. Chem. Rev. 86:1986;17.
60. Ito M., West B. J. Am. Chem. Soc. 85:1963;2580.
61. Baglin F.G., Rose C.B. Spectrochim. Acta. 26:1970;2293.
62. Kahn O., Charlot M.F. Nouv. J. Chim. 4:1980;567.
63. Román P., Guzmán-Miralles C., Luque A., Beitia J.I., Cano J., Lloret F., Julve M., Alvarez S. Inorg. Chem. 35:1996;3741.